Enhanced lithium storage capacity of Co3O4hexagonal nanorings derived from Co-based metal organic frameworks

2014 ◽  
Vol 2 (41) ◽  
pp. 17408-17414 ◽  
Author(s):  
Panpan Su ◽  
Shichao Liao ◽  
Feng Rong ◽  
Fuqing Wang ◽  
Jian Chen ◽  
...  
Keyword(s):  
Storage Capacity ◽  
Metal Organic Frameworks ◽  
Lithium Storage ◽  
Metal Organic

Construction of NiCo2O4@graphene nanorods by tuning the compositional chemistry of metal–organic frameworks with enhanced lithium storage properties

2018 ◽  
Vol 6 (40) ◽  
pp. 19604-19610 ◽  
Author(s):  
Zhiqing Jia ◽  
Yingbin Tan ◽  
Zhonghui Cui ◽  
Linlin Zhang ◽  
Xiangxin Guo
Keyword(s):  
Storage Capacity ◽  
Metal Organic Frameworks ◽  
Rate Capability ◽  
Cycling Stability ◽  
Lithium Storage ◽  
Metal Organic ◽  
Storage Properties ◽  
Li Storage

NiCo2O4@graphene nanorods synthesized by tuning the compositional chemistry of metal–organic frameworks exhibit high Li-storage capacity, excellent rate capability and extraordinary cycling stability.

Achieving Large Volumetric Gas Storage Capacity in Metal–Organic Frameworks by Kinetic Trapping: A Case Study of Xenon Loading in MFU-4

2018 ◽  
Vol 140 (32) ◽  
pp. 10191-10197 ◽  
Author(s):  
Hana Bunzen ◽  
Felicitas Kolbe ◽  
Andreas Kalytta-Mewes ◽  
German Sastre ◽  
Eike Brunner ◽  
...  
Keyword(s):  
Storage Capacity ◽  
Metal Organic Frameworks ◽  
Gas Storage ◽  
Metal Organic ◽  
Kinetic Trapping

Enhanced water stability and high CO2 storage capacity of Lewis basic sites containing zirconium metal–organic framework

2021 ◽  
Author(s):  
Selcuk Demir ◽  
Nuray Bilgin ◽  
H. Merve Cepni ◽  
Hiroyasu Furukawa ◽  
Fatih Yilmaz ◽  
...  
Keyword(s):  
Metal Ions ◽  
Storage Capacity ◽  
Metal Organic Framework ◽  
Co2 Storage ◽  
Metal Organic Frameworks ◽  
Water Stability ◽  
High Co2 ◽  
Metal Organic ◽  
Zirconium Metal ◽  
Selection Of

Metal–organic frameworks (MOFs) are an emerging class of materials employed for custom-designed purposes by judicious selection of the linker and the metal ions. Among the MOFs composed of carboxylate linkers,...

scholarly journals Implementing Metal-Organic Frameworks for Natural Gas Storage

Crystals ◽  
2019 ◽  
Vol 9 (8) ◽  
pp. 406 ◽  
Author(s):  
Eyas Mahmoud ◽  
Labeeb Ali ◽  
Asmaa El Sayah ◽  
Sara Awni Alkhatib ◽  
Hend Abdulsalam ◽  
...  
Keyword(s):  
Natural Gas ◽  
Thermal Management ◽  
Active Sites ◽  
Storage Capacity ◽  
Metal Organic Frameworks ◽  
Department Of Energy ◽  
Working Capacity ◽  
Adsorbed Natural Gas ◽  
Metal Organic ◽  
Temperature And Pressure

Methane can be stored by metal-organic frameworks (MOFs). However, there remain challenges in the implementation of MOFs for adsorbed natural gas (ANG) systems. These challenges include thermal management, storage capacity losses due to MOF packing and densification, and natural gas impurities. In this review, we discuss discoveries about how MOFs can be designed to address these three challenges. For example, Fe(bdp) (bdp2− = 1,4-benzenedipyrazolate) was discovered to have intrinsic thermal management and released 41% less heat than HKUST-1 (HKUST = Hong Kong University of Science and Technology) during adsorption. Monolithic HKUST-1 was discovered to have a working capacity 259 cm3 (STP) cm−3 (STP = standard temperature and pressure equivalent volume of methane per volume of the adsorbent material: T = 273.15 K, P = 101.325 kPa), which is a 50% improvement over any other previously reported experimental value and virtually matches the 2012 Department of Energy (Department of Energy = DOE) target of 263 cm3 (STP) cm−3 after successful packing and densification. In the case of natural gas impurities, higher hydrocarbons and other molecules may poison or block active sites in MOFs, resulting in up to a 50% reduction of the deliverable energy. This reduction can be mitigated by pore engineering.

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