Achieving Large Volumetric Gas Storage Capacity in Metal–Organic Frameworks by Kinetic Trapping: A Case Study of Xenon Loading in MFU-4

2018 ◽  
Vol 140 (32) ◽  
pp. 10191-10197 ◽  
Author(s):  
Hana Bunzen ◽  
Felicitas Kolbe ◽  
Andreas Kalytta-Mewes ◽  
German Sastre ◽  
Eike Brunner ◽  
...  
Keyword(s):  
Storage Capacity ◽  
Metal Organic Frameworks ◽  
Gas Storage ◽  
Metal Organic ◽  
Kinetic Trapping

Metal organic frameworks with exceptional gas storage capacity

2010 ◽  
Author(s):  
Matthew R Hill ◽  
Aaron W. Thornton ◽  
Kate M Nairn ◽  
Kenji Sumida ◽  
Anita J Hill
Keyword(s):  
Storage Capacity ◽  
Metal Organic Frameworks ◽  
Gas Storage ◽  
Metal Organic

Adsorption of two gas molecules at a single metal site in a metal–organic framework

2016 ◽  
Vol 52 (53) ◽  
pp. 8251-8254 ◽  
Author(s):  
Tomče Runčevski ◽  
Matthew T. Kapelewski ◽  
Rodolfo M. Torres-Gavosto ◽  
Jacob D. Tarver ◽  
Craig M. Brown ◽  
...  
Keyword(s):  
Storage Capacity ◽  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
Gas Storage ◽  
Metal Centers ◽  
Metal Site ◽  
Metal Organic ◽  
Gas Molecules ◽  
Organic Framework

One strategy to markedly increase the gas storage capacity of metal–organic frameworks is to introduce coordinatively-unsaturated metal centers capable of binding multiple gas molecules.

Metal-Organic Frameworks vs. Buffers: Case Study of UiO-66 Stability

2020 ◽  
Author(s):  
Daniel Bůžek ◽  
Slavomír Adamec ◽  
Kamil Lang ◽  
Jan Demel
Keyword(s):  
Inductively Coupled Plasma ◽  
Buffer Capacity ◽  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
Analytical Techniques ◽  
Aqueous Dispersions ◽  
Inductively Coupled ◽  
Plasma Mass Spectrometry ◽  
Metal Organic

<div><p>UiO-66 is a zirconium-based metal-organic framework (MOF) that has numerous applications. Our group recently determined that UiO-66 is not as inert in aqueous dispersions as previously reported in the literature. The present work therefore assessed the behaviour of UiO-66 in buffers: 2-amino-2-(hydroxymethyl)-1,3-propanediol (TRIS), 4-(2-hydroxyethyl)piperazine-1-ethane sulfonic acid (HEPES), N-ethylmorpholine (NEM) and phosphate buffer (PB), all of which are commonly used in many UiO-66 applications. High pressure liquid chromatography and inductively coupled plasma mass spectrometry were used to monitor degradation of the MOF. In each buffer, the terephthalate linker was released to some extent, with a more pronounced leaching effect in the saline forms of these buffers. The HEPES buffer was found to be the most benign, whereas NEM and PB should be avoided at any concentration as they were shown to rapidly degrade the UiO-66 framework. Low concentration TRIS buffers are also recommended, although these offer minimal buffer capacity to adjust pH. Regardless of the buffer used, rapid terephthalate release was observed, indicating that the UiO-66 was attacked immediately after mixing with the buffer. In addition, the dissolution of zirconium, observed in some cases, intensified the UiO-66 decomposition process. These results demonstrate that sensitive analytical techniques have to be used to monitor the release of MOF components so as to quantify the stabilities of these materials in liquid environments.</p></div>

Synthesis, designing strategies and photocatalytic charge dynamics of Metal-Organic Frameworks (MOFs): A catalyzed Photo-degradation approach towards Organic Dyes

2021 ◽  
Author(s):  
Ayushi Singh ◽  
Ashish Kumar Singh ◽  
Jian-Qiang Liu ◽  
Abhinav Kumar
Keyword(s):  
Small Molecule ◽  
Coordination Polymers ◽  
Organic Dyes ◽  
Metal Organic Frameworks ◽  
Gas Storage ◽  
New Variety ◽  
Photo Degradation ◽  
Charge Dynamics ◽  
Potential Applications ◽  
Metal Organic

Metal-organic frameworks (MOFs) or coordination polymers (CPs) are regarded as new variety of materials that find potential applications in plethora of areas such as gas/small molecule absorption/separation, gas storage, membranes...

scholarly journals Recent Bio-Advances in Metal-Organic Frameworks

Molecules ◽  
2020 ◽  
Vol 25 (6) ◽  
pp. 1291 ◽  
Author(s):  
Isobel Tibbetts ◽  
George Kostakis
Keyword(s):  
Drug Delivery ◽  
Inorganic Material ◽  
Metal Organic Frameworks ◽  
Gas Storage ◽  
Industrial Applications ◽  
Biologically Relevant ◽  
Bioinspired Materials ◽  
Synthesis Properties ◽  
Metal Organic

Metal-organic frameworks (MOFs) have found uses in adsorption, catalysis, gas storage and other industrial applications. Metal Biomolecule Frameworks (bioMOFs) represent an overlap between inorganic, material and medicinal sciences, utilising the porous frameworks for biologically relevant purposes. This review details advances in bioMOFs, looking at the synthesis, properties and applications of both bioinspired materials and MOFs used for bioapplications, such as drug delivery, imaging and catalysis, with a focus on examples from the last five years.

scholarly journals Metal–Organic Framework Hybrid Materials and Their Applications

Crystals ◽  
2018 ◽  
Vol 8 (8) ◽  
pp. 325 ◽  
Author(s):  
Joshua Sosa ◽  
Timothy Bennett ◽  
Katherine Nelms ◽  
Brandon Liu ◽  
Roberto Tovar ◽  
...  
Keyword(s):  
Small Molecules ◽  
Hybrid Materials ◽  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
Gas Storage ◽  
Superior Performance ◽  
Separation Energy ◽  
New Materials ◽  
Metal Organic ◽  
Covalent Modifications

The inherent porous nature and facile tunability of metal–organic frameworks (MOFs) make them ideal candidates for use in multiple fields. MOF hybrid materials are derived from existing MOFs hybridized with other materials or small molecules using a variety of techniques. This led to superior performance of the new materials by combining the advantages of MOF components and others. In this review, we discuss several hybridization methods for the preparation of various MOF hybrids with representative examples from the literature. These methods include covalent modifications, noncovalent modifications, and using MOFs as templates or precursors. We also review the applications of the MOF hybrids in the fields of catalysis, drug delivery, gas storage and separation, energy storage, sensing, and others.

Enhanced water stability and high CO2 storage capacity of Lewis basic sites containing zirconium metal–organic framework

2021 ◽  
Author(s):  
Selcuk Demir ◽  
Nuray Bilgin ◽  
H. Merve Cepni ◽  
Hiroyasu Furukawa ◽  
Fatih Yilmaz ◽  
...  
Keyword(s):  
Metal Ions ◽  
Storage Capacity ◽  
Metal Organic Framework ◽  
Co2 Storage ◽  
Metal Organic Frameworks ◽  
Water Stability ◽  
High Co2 ◽  
Metal Organic ◽  
Zirconium Metal ◽  
Selection Of

Metal–organic frameworks (MOFs) are an emerging class of materials employed for custom-designed purposes by judicious selection of the linker and the metal ions. Among the MOFs composed of carboxylate linkers,...

scholarly journals The role of molecular modelling and simulation in the discovery and deployment of metal-organic frameworks for gas storage and separation

2019 ◽  
Vol 45 (14-15) ◽  
pp. 1082-1121 ◽  
Author(s):  
Arni Sturluson ◽  
Melanie T. Huynh ◽  
Alec R. Kaija ◽  
Caleb Laird ◽  
Sunghyun Yoon ◽  
...  
Keyword(s):  
Molecular Modelling ◽  
Metal Organic Frameworks ◽  
Gas Storage ◽  
Modelling And Simulation ◽  
Metal Organic
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