Kinetically asymmetric charge and discharge behavior of LiNi0.5Mn1.5O4 at low temperature observed by in situ X-ray diffraction

2014 ◽  
Vol 2 (37) ◽  
pp. 15414-15419 ◽  
Author(s):  
Ikuma Takahashi ◽  
Haruno Murayama ◽  
Kenji Sato ◽  
Takahiro Naka ◽  
Koji Kitada ◽  
...  
Keyword(s):  
Low Temperature ◽  
Low Temperatures ◽  
X Ray Diffraction ◽  
X Ray ◽  
Discharge Behavior

Thermodynamically reversible LiNi0.5Mn1.5O4 electrodes kinetically behave asymmetrically during charging and discharging at low temperatures.

In situ characterization of strain-induced crystallization of natural rubber by synchrotron radiation wide-angle X-ray diffraction: construction of a crystal network at low temperatures

Soft Matter ◽  
2019 ◽  
Vol 15 (4) ◽  
pp. 734-743 ◽  
Author(s):  
Pinzhang Chen ◽  
Jingyun Zhao ◽  
Yuanfei Lin ◽  
Jiarui Chang ◽  
Lingpu Meng ◽  
...  
Keyword(s):  
Low Temperatures ◽  
Structural Evolution ◽  
X Ray Diffraction ◽  
In Situ Characterization ◽  
X Ray ◽  
Crystal Network ◽  
Strain Induced Crystallization ◽  
Induced Crystallization

The structural evolution of NR during stretching at −40 °C and in the strain–temperature space.

scholarly journals The Stability of Icosahedral Cd-Yb

2003 ◽  
Vol 805 ◽  
Author(s):  
Günter Krauss ◽  
Sofia Deloudi ◽  
Andrea Steiner ◽  
Walter Steurer ◽  
Amy R. Ross ◽  
...  
Keyword(s):  
Low Temperature ◽  
Ambient Temperature ◽  
Mechanical Stress ◽  
Single Crystals ◽  
High Temperatures ◽  
Low Temperatures ◽  
Ambient Pressure ◽  
X Ray Diffraction ◽  
X Ray ◽  
The Stability

ABSTRACTThe stability of single-crystalline icosahedral Cd-Yb was investigated using X-ray diffraction methods in the temperature range 20 K ≤ T ≤ 900 K at ambient pressure and from ambient temperature to 873 K at about 9 GPa. Single-crystals remain stable at low temperatures and in the investigated HP-HT-regime. At high temperatures and ambient pressure, the quasicrystal decomposes. The application of mechanical stress at low temperatures yields to the same decomposition, the formation of Cd. A reaction of icosahedral Cd-Yb with traces of oxygen or water causing the decomposition seems reasonable, but a low-temperature instability of this binary quasi-crystal cannot be ruled out totally.

Dimethyl-, Disilyl- and Digermylsulfide: Different Intermolecular Contacts in the Solid State

2004 ◽  
Vol 59 (6) ◽  
pp. 635-638 ◽  
Author(s):  
Norbert W. Mitzel ◽  
Udo Losehand
Keyword(s):  
Solid State ◽  
Low Temperature ◽  
Crystal Structures ◽  
X Ray Diffraction ◽  
X Ray ◽  
Intermolecular Contacts

The compounds (H3C)2S, (H3Si)2S and (H3Ge)2S have been crystallised in situ on a diffractometer and their crystal structures determined by low-temperature X-ray diffraction. The molecules are present as monomers in the crystals. The aggregation of the molecules through secondary intermolecular contacts in the crystal is different: (H3C)2S is weakly associated into dimers by S···S contacts, whereas (H3Si)2S and (H3Ge)2S form Si···S and Ge···S contacts in an ice-analogous aggregation motif. Important geometry parameters are (H3C)2S: C-S 1.794(av) Å , C-S-C 99.2(1)°; (H3Si)2S: Si- S 2.143(1) Å , Si-S-Si 98.4°; (H3Ge)2S Ge-S 2.223(2) and 2.230(2) Å , Ge-S-Ge 98.2(1)◦.

Low-Temperature (<300°C) Phosphate Ceramics from Reactive Aluminas

1989 ◽  
Vol 179 ◽  
Author(s):  
M. R. Silsbee ◽  
R. A. Steinke ◽  
D. M. Roy ◽  
D. K. Agrawal ◽  
R. Roy
Keyword(s):  
Mechanical Properties ◽  
Low Temperature ◽  
Low Temperatures ◽  
Ceramic Materials ◽  
X Ray Diffraction ◽  
X Ray ◽  
Characterization Techniques ◽  
Exciting Potential

AbstractReactive aluminas, including rapidly calcined gibbsites, offer exciting potential for forming ceramic materials at low temperatures. New x-ray amorphous aluminas will react with water at room temperatures to form compacts with 10–50 MPa tensile strengths, via viscous slurries. The cementious behavior of these materials has been examined. The results of TGA, x-ray diffraction, SEM, mechanical properties, and other characterization techniques, as applied to these systems, will be discussed.

scholarly journals In situlaser irradiation setup for a Bruker three-circle goniometer

2017 ◽  
Vol 50 (5) ◽  
pp. 1556-1558
Author(s):  
Dmitry S. Yufit
Keyword(s):  
Low Temperature ◽  
Single Crystals ◽  
Laser Irradiation ◽  
Diffraction Experiment ◽  
X Ray Diffraction ◽  
X Ray

A new design of a setup forin situlaser irradiation of single crystals during an X-ray diffraction experiment is presented. The system is designed for use with a Bruker three-circle goniometer in combination with a Helix ultra-low-temperature cryostat and consists of a laser mount and a set of three adjustable mirrors. The main advantages of the presented system include a stationary laser mount, the ability to irradiate a sample inside the Be nozzle and no impediments to the goniometer movements.

scholarly journals Facile Low Temperature Hydrothermal Synthesis of BaTiO3 Nanoparticles Studied by In Situ X-ray Diffraction

Crystals ◽  
2018 ◽  
Vol 8 (6) ◽  
pp. 253 ◽  
Author(s):  
Ola Grendal ◽  
Anders Blichfeld ◽  
Susanne Skjærvø ◽  
Wouter van Beek ◽  
Sverre Selbach ◽  
...  
Keyword(s):  
Hydrothermal Synthesis ◽  
Low Temperature ◽  
X Ray Diffraction ◽  
X Ray ◽  
Batio3 Nanoparticles

Ni/GeSn solid-state reaction monitored by combined X-ray diffraction analyses: focus on the Ni-rich phase

2018 ◽  
Vol 51 (4) ◽  
pp. 1133-1140 ◽  
Author(s):  
Andrea Quintero ◽  
Patrice Gergaud ◽  
Joris Aubin ◽  
Jean-Michel Hartmann ◽  
Vincent Reboud ◽  
...  
Keyword(s):  
Solid State ◽  
Low Temperature ◽  
Solid State Reaction ◽  
Metastable Phase ◽  
Hexagonal Structure ◽  
X Ray Diffraction ◽  
Rich Phase ◽  
X Ray ◽  
Pole Figures

The Ni/Ge0.9Sn0.1 solid-state reaction was monitored by combining in situ X-ray diffraction, in-plane reciprocal space map measurements and in-plane pole figures. A sequential growth was shown, in which the first phase formed was an Ni-rich phase. Then, at 518 K, the mono-stanogermanide phase Ni(Ge0.9Sn0.1) was observed. This phase was stable up to 873 K. Special attention has been given to the nature and the crystallographic orientation of the Ni-rich phase obtained at low temperature. It is demonstrated, with in-plane pole figure measurements and simulation, that it was the ∊-Ni5(Ge0.9Sn0.1)3 metastable phase with a hexagonal structure.

Sign in / Sign up

Export Citation Format

Share Document