3D hierarchical honeycomb structured MWCNTs coupled with CoMnAl–LDO: fabrication and application for ultrafast catalytic degradation of bisphenol A

RSC Advances ◽  
2015 ◽  
Vol 5 (12) ◽  
pp. 8859-8867 ◽  
Author(s):  
Wen Li ◽  
Pingxiao Wu ◽  
Shanshan Yang ◽  
Yajie Zhu ◽  
Chunxi Kang ◽  
...  
Keyword(s):  
Surface Modification ◽  
Bisphenol A ◽  
Metal Ions ◽  
Catalytic Degradation ◽  
Nano Structure ◽  
Adsorption Of Metal Ions

Schematic illustration for the synthesis of CNTs–LDH. (I): The surface modification of MWCNTs. (II): The adsorption of metal ions. (III): The formation of 2D CNTs–LDH nanosheets. (IV): The formation of 3D hierarchical honeycomb nano-structure.

Synthesis and Surface Modification of Mesoporous Silicate SBA‐15 for the Adsorption of Metal Ions

2006 ◽  
Vol 41 (9) ◽  
pp. 1829-1840 ◽  
Author(s):  
Kathy Northcott ◽  
Hisao Kokusen ◽  
Yu Komatsu ◽  
Geoff Stevens
Keyword(s):  
Surface Modification ◽  
Metal Ions ◽  
Mesoporous Silicate ◽  
Adsorption Of Metal Ions

scholarly journals UV Stimulated Manganese Dioxide for the Persulfate Catalytic Degradation of Bisphenol A

Catalysts ◽  
2021 ◽  
Vol 11 (4) ◽  
pp. 502
Author(s):  
Guihua Dong ◽  
Bing Chen ◽  
Bo Liu ◽  
Stanislav R. Stoyanov ◽  
Yiqi Cao ◽  
...  
Keyword(s):  
Bisphenol A ◽  
Reaction Mechanisms ◽  
Reduction Rate ◽  
Catalytic Degradation ◽  
Gas Chromatography Mass Spectrometry ◽  
Degradation Pathways ◽  
Industrial Chemicals ◽  
Oh Groups ◽  
Long Term Adverse Effects

One of the most commonly produced industrial chemicals worldwide, bisphenol A (BPA), is used as a precursor in plastics, resins, paints, and many other materials. It has been proved that BPA can cause long-term adverse effects on ecosystems and human health due to its toxicity as an endocrine disruptor. In this study, we developed an integrated MnO2/UV/persulfate (PS) process for use in BPA photocatalytic degradation from water and examined the reaction mechanisms, degradation pathways, and toxicity reduction. Comparative tests using MnO2, PS, UV, UV/MnO2, MnO2/PS, and UV/PS processes were conducted under the same conditions to investigate the mechanism of BPA catalytic degradation by the proposed MnO2/UV/PS process. The best performance was observed in the MnO2/UV/PS process in which BPA was completely removed in 30 min with a reduction rate of over 90% for total organic carbon after 2 h. This process also showed a stable removal efficiency with a large variation of pH levels (3.6 to 10.0). Kinetic analysis suggested that 1O2 and SO4•− played more critical roles than •OH for BPA degradation. Infrared spectra showed that UV irradiation could stimulate the generation of –OH groups on the MnO2 photocatalyst surface, facilitating the PS catalytic degradation of BPA in this process. The degradation pathways were further proposed in five steps, and thirteen intermediates were identified by gas chromatography-mass spectrometry. The acute toxicity was analyzed during the treatment, showing a slight increase (by 3.3%) in the first 30 min and then a decrease by four-fold over 2 h. These findings help elucidate the mechanism and pathways of BPA degradation and provide an effective PS catalytic strategy.

A comparative study on selective adsorption of metal ions using aminated adsorbents

2013 ◽  
Vol 395 ◽  
pp. 230-240 ◽  
Author(s):  
Len Foong Koong ◽  
Koon Fung Lam ◽  
John Barford ◽  
Gordon McKay
Keyword(s):  
Comparative Study ◽  
Metal Ions ◽  
Selective Adsorption ◽  
Adsorption Of Metal Ions

scholarly journals Impact of exogenous metal ions on peri-implant bone metabolism: a review

RSC Advances ◽  
2021 ◽  
Vol 11 (22) ◽  
pp. 13152-13163
Author(s):  
Wei Chen ◽  
Wen-qing Zhu ◽  
Jing Qiu
Keyword(s):  
Surface Modification ◽  
Metal Ions ◽  
Bone Metabolism ◽  
Dental Implants ◽  
Materials Science ◽  
Dental Materials ◽  
Intense Research

The development of effective methods to promote the osseointegration of dental implants by surface modification is an area of intense research in dental materials science.

3D composite lithium metal with multilevel micro-nano structure combined with surface modification for stable lithium metal anodes

2021 ◽  
Vol 570 ◽  
pp. 151159
Author(s):  
Weishang Jia ◽  
Hudong Li ◽  
Zihao Wang ◽  
Yuchi Liu ◽  
Yao-Yue Yang ◽  
...  
Keyword(s):  
Surface Modification ◽  
Lithium Metal ◽  
Nano Structure ◽  
Lithium Metal Anodes ◽  
3D Composite ◽  
Metal Anodes

scholarly journals Removal of barium, cobalt, strontium and zinc from solution by natural and synthetic allophane adsorbents

2018 ◽  
Author(s):  
Andre Baldermann ◽  
Andrea Cäcilia Grießbacher ◽  
Claudia Baldermann ◽  
Bettina Purgstaller ◽  
Ilse Letofsky-Papst ◽  
...  
Keyword(s):  
Metal Ions ◽  
Metal Ion ◽  
Physical Adsorption ◽  
Ion Concentration ◽  
Pseudo First Order Reaction ◽  
Uptake Mechanism ◽  
Nano Structure ◽  
Metal Ion Removal ◽  
Ion Removal ◽  
Transmission Electron

The capacity and the mechanism of the adsorption of aqueous barium (Ba), cobalt (Co), strontium (Sr) and zinc (Zn) by Ecuadorian (NatAllo) and synthetic (SynAllo-1 and SynAllo-2) allophanes were studied as a function of contact time, pH and metal ion concentration using kinetic and equilibrium experiments. The mineralogy, nano-structure and chemical composition of the allophanes were characterized by X-ray diffraction, Fourier transform infrared spectroscopy, transmission electron microscopy and specific surface area analyses. The evolution of adsorption fitted to a pseudo-first-order reaction kinetics, where equilibrium between aqueous metal ions and allophane was reached within < 10 min. The metal ion removal efficiencies varied from 0.7 to 99.7 % at pH 4.0 to 8.5. At equilibrium, the adsorption behavior is better described by the Langmuir model than by the Dubinin-Radushkevich model, yielding sorption capacities of 10.6, 17.2 and 38.6 mg/g for Ba^(2+), 12.4, 19.3 and 29.0 mg/g for HCoO_2^-, 7.2, 15.9 and 34.4 mg/g for Sr^(2+) and 20.9, 26.9 and 36.9 mg/g for Zn^(2+), respectively, by NatAllo, SynAllo-2 and SynAllo-1. The uptake mechanism is based on a physical adsorption process. Allophane holds great potential to remove aqueous metal ions and could be used instead of zeolites, montmorillonite, carbonates and phosphates for wastewater treatment.

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