Facile preparation of stable palygorskite/cationic red X-GRL@SiO2“Maya Red” pigments

RSC Advances ◽  
2014 ◽  
Vol 4 (108) ◽  
pp. 63485-63493 ◽  
Author(s):  
Ling Fan ◽  
Yujie Zhang ◽  
Junping Zhang ◽  
Aiqin Wang

We report the fabrication of stable “Maya Red” pigments with a purple-red hue by adsorption of cationic red X-GRL (CR-XGRL) onto palygorskite, which is followed by hydrolysis and polycondensation of tetraethoxysilaneviaa modified Stöber method to form a layer of SiO2.

Nanomaterials ◽  
2018 ◽  
Vol 8 (6) ◽  
pp. 362 ◽  
Author(s):  
Qian Chen ◽  
Yanling Ge ◽  
Henrika Granbohm ◽  
Simo-Pekka Hannula

2019 ◽  
Vol 13 (2) ◽  
pp. 156-164
Author(s):  
Meng Liu ◽  
Lei Liu ◽  
Yifeng Yu ◽  
Haijun Lv ◽  
Aibing Chen ◽  
...  

2018 ◽  
Vol 18 (10) ◽  
pp. 6867-6872 ◽  
Author(s):  
Van Thi Thanh Ho ◽  
Nguyen Vu Hoa Hong ◽  
At Van Nguyen ◽  
Long Giang Bach ◽  
Tuan Phan Dinh

2014 ◽  
Vol 67 (1) ◽  
pp. 134 ◽  
Author(s):  
Yiheng Wang ◽  
Mengge Xia ◽  
Yongtao Wu ◽  
Meifang Zhu

Functionalized magnetic microspheres were prepared by anchoring cross-linked core–shell poly(N-isopropylacrylamide-co-acrylic acid) (P(NIPAM-co-AA)) nanoparticles onto silica-coated magnetic microspheres (Fe3O4@SiO2). First, the smaller polystyrene/P(NIPAM-co-AA) core–shell nanoparticles were synthesized through seed emulsion polymerization and adhered to the surface of amino-modified Fe3O4@SiO2 micorspheres, which were made using the modified Stöber method through electrostatic interaction under appropriate preparation conditions. An amidation reaction between the carboxylic and amino groups on the respective surfaces was then catalyzed. Finally, the novel architecture magnetic microspheres with multiresponsive functionalities were obtained, and their polymerization conditions, environmental sensitivity, and magnetic properties were discussed and optimized. The superparamagnetism and temperature/pH dual responsivity and excellent dispersibility of the P(NIPAM-co-AA) functionalized magnetic microspheres provide them with high potential to be used in the fields of controlled drug delivery, bioseparation, and catalysis.


RSC Advances ◽  
2016 ◽  
Vol 6 (44) ◽  
pp. 37535-37543 ◽  
Author(s):  
Fen Wang ◽  
Xin Zhang ◽  
Jianfeng Zhu ◽  
Ying Lin

Polystyrene@silica (PS@SiO2) core–shell nanospheres were synthesized using a surfactant free method followed by a modified Stöber method in the research reported in this paper.


2008 ◽  
Vol 24 (4) ◽  
pp. 248-252 ◽  
Author(s):  
Y. Kobayashi ◽  
N. Shimizu ◽  
K. Misawa ◽  
M. Takeda ◽  
N. Ohuchi ◽  
...  

2016 ◽  
Vol 301 ◽  
pp. 486-492 ◽  
Author(s):  
Eliana Galland Barrera ◽  
Paolo R. Livotto ◽  
João H.Z. dos Santos

2011 ◽  
Vol 695 ◽  
pp. 449-452 ◽  
Author(s):  
Juha Larismaa ◽  
Toni Honkanen ◽  
Yan Ling Ge ◽  
Outi Söderberg ◽  
Michael Friman ◽  
...  

Antibacterial silver can be used against such micro-organisms as bacteria and molds. When Ag nanoparticles are attached to an inorganic carrier, e.g., silica long-term antimicrobial functionality can be gained. Such Ag-SiO2particles are potential for water purification or bactericidal applications. In this work, submicron sized silica particles doped with Ag were prepared by the modified Stöber method. The as-prepared powder was air-dried and annealed for 75 minutes at 573, 673, 773, 873, 973, 1073, 1173, or 1273 K in air. The powders were studied by DSC/TGA, XRD, SEM, TEM and UV-vis methods. The as-prepared powder consisted of round silica particles having size around several hundred nanometers. XRD and SEM studies confirmed that the powder consisted of metallic silver nanoparticles on the submicron silica surface after annealing at 873 K or higher. According to the SEM study the silver particles had an average particle size between 19-400 nm depending on the annealing temperature. DSC was used to determine the phase transformation temperatures. After annealing the Ag-SiO2powder at 873 K the TEM study suggested that the silver had crystalline structure. The XRD studies confirmed that silver appeared as a FCC crystal structure. The UV-vis measurements of Ag-SiO2powder annealed at and below 773 K showed a steady increase in absorption with decreasing wavelength without absorption peaks. Annealing at 873 K and above resulted in a strong peak in between 404 nm and 416 nm. This peak can be attributed to the surface plasmon resonance of silver nanoparticles.


2014 ◽  
Vol 154 (1) ◽  
pp. 142-146 ◽  
Author(s):  
Xue Lei ◽  
Bing Yu ◽  
Hai-Lin Cong ◽  
Chao Tian ◽  
Yue-Zhong Wang ◽  
...  

2008 ◽  
Vol 8 (3) ◽  
pp. 1464-1467 ◽  
Author(s):  
Weiping Qin ◽  
Dan Zhao ◽  
Jisen Zhang ◽  
Jishuang Zhang ◽  
Yan Wang ◽  
...  

The core–shell titania (TiO2) hybrid spheres embedded with tris(dibenzoylmethanato)phenanthroline [Eu-(DBM)3phen] complex clusters were fabricated by a modified Stöber method. Under ultraviolet excitation (355 nm), the hybrid spheres exhibit the characteristic luminescence of the Eu3+ ions. The experimental results indicate that the titanic shell has different influences on the two fluorescent centers of Eu3+ ions. The emission from the centers on the complex surfaces was greatly enhanced when incorporated into titania spheres.


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