Thermal stability, swelling behavior and CO2 absorption properties of Nanoscale Ionic Materials (NIMs)

RSC Advances ◽  
2014 ◽  
Vol 4 (110) ◽  
pp. 65195-65204 ◽  
Author(s):  
Kun-Yi Andrew Lin ◽  
Youngjune Park ◽  
Camille Petit ◽  
Ah-Hyung Alissa Park

Nanoscale Ionic Materials (NIMs) consist of a nanoscale core, a corona of charged brushes tethered on the surface of the core, and a canopy of the oppositely charged species linked to the corona.

2021 ◽  
Vol 13 (2) ◽  
pp. 637
Author(s):  
Tomas Astrauskas ◽  
Tomas Januševičius ◽  
Raimondas Grubliauskas

Studies on recycled materials emerged during recent years. This paper investigates samples’ sound absorption properties for panels fabricated of a mixture of paper sludge (PS) and clay mixture. PS was the core material. The sound absorption was measured. We also consider the influence of an air gap between panels and rigid backing. Different air gaps (50, 100, 150, 200 mm) simulate existing acoustic panel systems. Finally, the PS and clay composite panel sound absorption coefficients are compared to those for a typical commercial absorptive ceiling panel. The average sound absorption coefficient of PS-clay composite panels (αavg. in the frequency range from 250 to 1600 Hz) was up to 0.55. The resulting average sound absorption coefficient of panels made of recycled (but unfinished) materials is even somewhat higher than for the finished commercial (finished) acoustic panel (αavg. = 0.51).


Polymers ◽  
2021 ◽  
Vol 13 (4) ◽  
pp. 502
Author(s):  
Karel Šindelka ◽  
Zuzana Limpouchová ◽  
Karel Procházka

Using coarse-grained dissipative particle dynamics (DPD) with explicit electrostatics, we performed (i) an extensive series of simulations of the electrostatic co-assembly of asymmetric oppositely charged copolymers composed of one (either positively or negatively charged) polyelectrolyte (PE) block A and one water-soluble block B and (ii) studied the solubilization of positively charged porphyrin derivatives (P+) in the interpolyelectrolyte complex (IPEC) cores of co-assembled nanoparticles. We studied the stoichiometric mixtures of 137 A10+B25 and 137 A10−B25 chains with moderately hydrophobic A blocks (DPD interaction parameter aAS=35) and hydrophilic B blocks (aBS=25) with 10 to 120 P+ added (aPS=39). The P+ interactions with other components were set to match literature information on their limited solubility and aggregation behavior. The study shows that the moderately soluble P+ molecules easily solubilize in IPEC cores, where they partly replace PE+ and electrostatically crosslink PE− blocks. As the large P+ rings are apt to aggregate, P+ molecules aggregate in IPEC cores. The aggregation, which starts at very low loadings, is promoted by increasing the number of P+ in the mixture. The positively charged copolymers repelled from the central part of IPEC core partially concentrate at the core-shell interface and partially escape into bulk solvent depending on the amount of P+ in the mixture and on their association number, AS. If AS is lower than the ensemble average ⟨AS⟩n, the copolymer chains released from IPEC preferentially concentrate at the core-shell interface, thus increasing AS, which approaches ⟨AS⟩n. If AS>⟨AS⟩n, they escape into the bulk solvent.


2015 ◽  
Vol 50 (13) ◽  
pp. 4698-4706 ◽  
Author(s):  
Maoqiao Xiang ◽  
Yingchun Zhang ◽  
Ming Hong ◽  
Shuyan Liu ◽  
Yun Zhang ◽  
...  

2017 ◽  
Vol 121 (40) ◽  
pp. 21877-21886 ◽  
Author(s):  
Matthew T. Dunstan ◽  
Hannah Laeverenz Schlogelhofer ◽  
John M. Griffin ◽  
Matthew S. Dyer ◽  
Michael W. Gaultois ◽  
...  

2008 ◽  
Vol 320 (6) ◽  
pp. 1106-1111 ◽  
Author(s):  
B. Lu ◽  
X.L. Dong ◽  
H. Huang ◽  
X.F. Zhang ◽  
X.G. Zhu ◽  
...  

Applied laser ◽  
2015 ◽  
Vol 35 (1) ◽  
pp. 83-87
Author(s):  
朱虹 Zhu Hong ◽  
郭亮 Guo Liang ◽  
张庆茂 Zhang Qingmao

Particuology ◽  
2016 ◽  
Vol 24 ◽  
pp. 129-137 ◽  
Author(s):  
J. Ortiz-Landeros ◽  
R. López-Juárez ◽  
I.C. Romero-Ibarra ◽  
H. Pfeiffer ◽  
H. Balmori-Ramírez ◽  
...  

2010 ◽  
Vol 52 (2) ◽  
pp. 189-192 ◽  
Author(s):  
Daisuke Kodama ◽  
Mitsuhiro Kanakubo ◽  
Masaki Kokubo ◽  
Takeshi Ono ◽  
Hajime Kawanami ◽  
...  

2012 ◽  
Vol 534 ◽  
pp. 86-88
Author(s):  
Shi Mei Yang ◽  
Shao Yun Shan ◽  
Qing Ming Jia ◽  
Ting Wei Hu ◽  
Li Hong Jiang ◽  
...  

Using urea and calcium chloride as precipitator and calcium source, fibrous CaCO3 precursors were prepared using hydrothermal method, then fibrous CaO sorbent was obtained by calcination. The influence of hydrothermal temperature on CO2 absorption properties was discussed. X-ray diffraction analysis showed that pure CaCO3 phase with aragonite and calcite crystal forms was obtained. Scanning electron microscopy analysis showed that the resultant CaO sorbent presented a fibrous microstructure, which inherited the morphologies of CaCO3. The absorption capacity of the resultant CaO sorbent reached 59.86%, being 76% of theoretical absorption capacity. In addition, compared with the CaO sorbent from analytical pure CaCO3, the obtained fibrous CaO-sorbent have the better cyclic absorption properties.


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