Asymmetric transfer hydrogenation of imines in water/methanol co-solvent system and mechanistic investigation by DFT study

RSC Advances ◽  
2014 ◽  
Vol 4 (86) ◽  
pp. 46351-46356 ◽  
Author(s):  
Vaishali S. Shende ◽  
Savita K. Shingote ◽  
Sudhindra H. Deshpande ◽  
Nishamol Kuriakose ◽  
Kumar Vanka ◽  
...  
Keyword(s):  
Solvent System ◽  
Hydrogen Donor ◽  
Transfer Hydrogenation ◽  
Dft Study ◽  
Asymmetric Transfer Hydrogenation ◽  
Mechanistic Investigation

Asymmetric transfer hydrogenation of various cyclic imines proceeded efficiently with H2O/MeOH (1 : 1, v/v) co-solvent media in 20 min with excellent yields and enantioselectivities by using Rh–TsDPEN catalyst and HCOONa as a hydrogen donor.

ChemInform Abstract: Asymmetric Transfer Hydrogenation of Imines in Water/Methanol Co-Solvent System and Mechanistic Investigation by DFT Study.

ChemInform ◽  
2015 ◽  
Vol 46 (14) ◽  
pp. no-no
Author(s):  
Vaishali S. Shende ◽  
Savita K. Shingote ◽  
Sudhindra H. Deshpande ◽  
Nishamol Kuriakose ◽  
Kumar Vanka ◽  
...  
Keyword(s):  
Solvent System ◽  
Transfer Hydrogenation ◽  
Dft Study ◽  
Asymmetric Transfer Hydrogenation ◽  
Mechanistic Investigation

Asymmetric Transfer Hydrogenation of Acetophenone N-Benzylimine Using [RuIICl((S,S)-TsDPEN)(η6-p-cymene)]: A DFT Study

2012 ◽  
Vol 31 (17) ◽  
pp. 6496-6499 ◽  
Author(s):  
Petr Šot ◽  
Marek Kuzma ◽  
Jiří Václavík ◽  
Jan Pecháček ◽  
Jan Přech ◽  
...  
Keyword(s):  
Transfer Hydrogenation ◽  
Dft Study ◽  
Asymmetric Transfer Hydrogenation

scholarly journals Manganese Catalyzed Asymmetric Transfer Hydrogenation of Ketones Using Chiral Oxamide Ligands

Synlett ◽  
2019 ◽  
Vol 30 (04) ◽  
pp. 503-507 ◽  
Author(s):  
Jacob Schneekönig ◽  
Kathrin Junge ◽  
Matthias Beller
Keyword(s):  
Isopropyl Alcohol ◽  
Ruthenium Catalyst ◽  
Hydrogen Donor ◽  
Transfer Hydrogenation ◽  
Asymmetric Transfer Hydrogenation ◽  
Reaction Conditions ◽  
Active Systems ◽  
Manganese Catalysts

The asymmetric transfer hydrogenation of ketones using isopropyl alcohol (IPA) as hydrogen donor in the presence of novel manganese catalysts is explored. The selective and active systems are easily generated in situ from [MnBr(CO)5] and inexpensive C 2-symmeric bisoxalamide ligands. Under the optimized reaction conditions, the Mn-derived catalyst gave higher enantioselectivity compared with the related ruthenium catalyst.

Efficient asymmetric transfer hydrogenation of ketones in ethanol with chiral iridium complexes of spiroPAP ligands as catalysts

2015 ◽  
Vol 51 (28) ◽  
pp. 6123-6125 ◽  
Author(s):  
Wei-Peng Liu ◽  
Ming-Lei Yuan ◽  
Xiao-Hui Yang ◽  
Ke Li ◽  
Jian-Hua Xie ◽  
...  
Keyword(s):  
Hydrogen Donor ◽  
Transfer Hydrogenation ◽  
Chiral Alcohols ◽  
Iridium Complexes ◽  
Asymmetric Transfer Hydrogenation ◽  
Highly Efficient

Highly efficient iridium catalyzed asymmetric transfer hydrogenation of simple ketones with ethanol as a hydrogen donor has been developed, providing chiral alcohols with up to 98% ee.

Asymmetric Transfer Hydrogenation of Imines using Alcohol: Efficiency and Selectivity are Influenced by the Hydrogen Donor

2016 ◽  
Vol 128 (33) ◽  
pp. 9767-9771 ◽  
Author(s):  
Hui-Jie Pan ◽  
Yao Zhang ◽  
Chunhui Shan ◽  
Zhaoyuan Yu ◽  
Yu Lan ◽  
...  
Keyword(s):  
Hydrogen Donor ◽  
Transfer Hydrogenation ◽  
Asymmetric Transfer Hydrogenation

Asymmetric Transfer Hydrogenation of Imines using Alcohol: Efficiency and Selectivity are Influenced by the Hydrogen Donor

2016 ◽  
Vol 55 (33) ◽  
pp. 9615-9619 ◽  
Author(s):  
Hui-Jie Pan ◽  
Yao Zhang ◽  
Chunhui Shan ◽  
Zhaoyuan Yu ◽  
Yu Lan ◽  
...  
Keyword(s):  
Hydrogen Donor ◽  
Transfer Hydrogenation ◽  
Asymmetric Transfer Hydrogenation

Asymmetric Transfer Hydrogenation of Ketimines by Indoline as Recyclable Hydrogen Donor

2014 ◽  
Vol 16 (20) ◽  
pp. 5312-5315 ◽  
Author(s):  
Kodai Saito ◽  
Hiromitsu Miyashita ◽  
Takahiko Akiyama
Keyword(s):  
Hydrogen Donor ◽  
Transfer Hydrogenation ◽  
Asymmetric Transfer Hydrogenation

Rhodium-Catalyzed anti and syn Enantio- and Diastereoselective Transfer Hydrogenation of α-Amino β-Keto Ester Hydrochlorides through Dynamic Kinetic Resolution

Synthesis ◽  
2016 ◽  
Vol 48 (19) ◽  
pp. 3357-3363 ◽  
Author(s):  
Quentin Llopis ◽  
Charlène Férard ◽  
Gérard Guillamot ◽  
Phannarath Phansavath ◽  
Virginie Ratovelomanana-Vidal
Keyword(s):  
Formic Acid ◽  
Kinetic Resolution ◽  
Amino Alcohols ◽  
Hydrogen Donor ◽  
Transfer Hydrogenation ◽  
Asymmetric Transfer Hydrogenation ◽  
Dynamic Kinetic Resolution ◽  
Keto Ester ◽  
Catalytic Asymmetric ◽  
Donor Source

A mild catalytic asymmetric transfer hydrogenation of a series of α-amino β-keto ester hydrochlorides catalyzed by a rhodium(III) complex is reported. The use of the formic acid/triethylamine system as the hydrogen donor source provided the corresponding anti and syn amino alcohols with complete conversions, fair diastereoselectivities (up to 97:3 dr), and high enantioselectivities (ee up to >99%).

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