A highly selective and sensitive fluorescent chemosensor for Hg2+ based on a pyridine-appended π-conjugated ligand

RSC Advances ◽  
2014 ◽  
Vol 4 (87) ◽  
pp. 47000-47004 ◽  
Author(s):  
Yaping Yang ◽  
Xin-Long Ni ◽  
Tao Sun ◽  
Hang Cong ◽  
Gang Wei
Keyword(s):  
Aqueous Solution ◽  
Organic Synthesis ◽  
Fluorescence Enhancement ◽  
Fluorescent Chemosensor ◽  
Selective Method ◽  
Pure Aqueous Solution

A sensitive and selective method for the determination of Hg2+ cations by fluorescence enhancement in pure aqueous solution was developed and obtained by simple organic synthesis.

scholarly journals FLUORESCENCE ENHANCEMENT OF Al3+– SODIUM MORIN–5–SULFONATE COMPLEX BY IMIDAZOLIUM IONIC LIQUID AND ITS APPLICATION IN DETERMINATION OF Al3+ IONS IN AN AQUEOUS SOLUTION

2019 ◽  
Vol 81 (2) ◽  
Author(s):  
Syaza Atikah Nizar ◽  
Nurul Syamimi Abdul Satar ◽  
Shaik Azri Shaik Amar ◽  
Fatin Hazirah Abdullah ◽  
Faizatul Shimal Mehamod ◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Ionic Liquid ◽  
Acetic Acid ◽  
Ternary Complex ◽  
Fluorescence Enhancement ◽  
Calibration Graph ◽  
Fluorescence Signal ◽  
Binary Complex ◽  
Imidazolium Ionic Liquid

This study describes the preparation of sodium morin–5–sulfonate (NaMSA) as a new reagent for the determination of aluminium(III) (Al3+) ions based on the formation of a ternary complex. The complex consists of Al3+, NaMSA, and 1–Butyl–3–methylimidazolium hexafluorophosphate (BMIM–PF6). It was found that this method was sensitive compared to the binary complex of Al3+ and NaMSA. The ternary complex was excited at 420 nm, and the fluorescence signal was measured at 518 nm. Maximum fluorescence signal produced at pH 5.0 (acetic acid–acetate buffer), with 0.02% v/v BMIM–PF6 and 1.0 × 10-4 molL-1 of NaMSA. The calibration graph in linear up to 10 mgL-1 with the calculated detection limit of 0.017 mgL-1. Effect of foreign ions towards the ternary complex was also studied. Finally, the method was applied in the determination of Al3+ ions in water samples, and satisfactory results were obtained.

scholarly journals Solvent Extraction of Thorium Using 5,11,17,23-Tetra[(2-ethyl acetoethoxyphenyl)(azo)phenyl]calix[4]arene

2016 ◽  
Vol 2016 ◽  
pp. 1-6 ◽  
Author(s):  
Quang Hieu Tran ◽  
Van Tan Le ◽  
Van Cuong Nguyen
Keyword(s):  
Aqueous Solution ◽  
Solvent Extraction ◽  
Molar Absorptivity ◽  
Tolerance Limits ◽  
Acidic Aqueous Solution ◽  
Selective Method ◽  
Chloroform Layer ◽  
Effects Of Ph ◽  
Synthetic Solution

A rapid, sensitive, and selective method for determination of thorium based on the complex withortho-ester tetra-azophenylcalix[4]arene (TEAC) was described. In the presence of pH of 4–6, TEAC-Th(IV) complex is extracted from an acidic aqueous solution into chloroform layer. The absorbance intensity of complex was measured by UV-Vis spectrometer at 525 nm and the molar absorptivity was found to be 2.4 × 104. Beer’s law was obeyed in the range of 1.0 to 25 × 10−5 M thorium(IV). The effects of pH, TEAC concentration, and shaking time were also studied. The tolerance limits for several metal ions were calculated. The proposed method was applied to the determination of thorium in synthetic solution and in the monazite sand samples with good results.

scholarly journals Simple spectrofluorometric determination of p-aminobenzoic and p-aminosalicylic acids in biological fluids by use of terbium-sensitized luminescence

1996 ◽  
Vol 42 (10) ◽  
pp. 1659-1665 ◽  
Author(s):  
E S Lianidou ◽  
P C Ioannou
Keyword(s):  
Aqueous Solution ◽  
Biological Fluids ◽  
Optimum Conditions ◽  
Serum Samples ◽  
Solution Ph ◽  
Acidic Aqueous Solution ◽  
Selective Method ◽  
Spectrofluorometric Determination ◽  
Aminosalicylic Acids

Abstract A novel, sensitive, and selective method has been developed for determination of p-aminobenzoic (PABA) and p-aminosalicylic (PAS) acids in the N-benzoyl-L-tyrosyl-PABA/ PAS test. PAS is measured as a ternary complex with terbium and EDTA (lambda(ex) = 324 nm, lambda(em) = 546 nm) in alkaline aqueous solution (pH approximately 12.6), whereas both compounds (PABA and PAS) are measured as ternary complexes with terbium and tri-n-octylphosphine oxide (lambda(ex) = 292 nm, lambda(em) = 546 nm) in weakly acidic aqueous solution (pH approximately 5.5). We inve stigated and implemented optimum conditions for formation of these complexes, yielding respective detection limits for PABA and PAS of 0.07 and 0.02 micromol/L and ranges of application of 0-10 and 0-40 micromol/L (final concentration). The method has been successfully applied to determinations of PABA and PAS in urine and, after alkaline hydrolysis, to determinations of PABA in serum that has been deproteinized with acetonitrile. Within-run imprecision of the PABA determination ranges from 0.8% to 4.2 % for urine samples and from 3.9% to 8.2% for serum samples; day-to-day imprecision varies from 3.2% to 10% for serum samples.

A tetranaphthoimidazolium receptor as a fluorescent chemosensor for phytate

2014 ◽  
Vol 50 (44) ◽  
pp. 5851-5853 ◽  
Author(s):  
Minji Lee ◽  
Jong Hun Moon ◽  
Eun Jin Jun ◽  
Gyoungmi Kim ◽  
Yong-Uk Kwon ◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Fluorescence Enhancement ◽  
Fluorescent Chemosensor ◽  
Inositol Hexakisphosphate

A new tetranaphthoimidazolium receptor showed a selective fluorescence enhancement with phytate, myo-inositol hexakisphosphate (IP6), in 100% aqueous solution at pH 7.4.

scholarly journals A Highly Selective Turn-on and Reversible Fluorescent Chemosensor for Al3+ Detection Based on Novel Salicylidene Schiff Base-Terminated PEG in Pure Aqueous Solution

Polymers ◽  
2019 ◽  
Vol 11 (4) ◽  
pp. 573 ◽  
Author(s):  
Liping Bai ◽  
Yuhang Xu ◽  
Guang Li ◽  
Shuhui Tian ◽  
Leixuan Li ◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Schiff Base ◽  
Ethylenediaminetetraacetic Acid ◽  
Logic Gate ◽  
Water Soluble ◽  
Fluorescent Chemosensor ◽  
Water Soluble Polymer ◽  
Fluorescence Response ◽  
Turn On ◽  
Pure Aqueous Solution

The development of highly selective and sensitive chemosensors for Al3+ detection in pure aqueous solution is still a significant challenge. In this work, a novel water-soluble polymer PEGBAB based on salicylidene Schiff base has been designed and synthesized as a turn-on fluorescent chemosensor for the detection of Al3+ in 100% aqueous solution. PEGBAB exhibited high sensitivity and selectivity to Al3+ over other competitive metal ions with the detection limit as low as 4.05 × 10−9 M. PEGBAB displayed high selectivity to Al3+ in the pH range of 5–10. The fluorescence response of PEGBAB to Al3+ was reversible in the presence of ethylenediaminetetraacetic acid (EDTA). Based on the fluorescence response, an INHIBIT logic gate was constructed with Al3+ and EDTA as two inputs. Moreover, test strips based on PEGBAB were fabricated facilely for convenient on-site detection of Al3+.

An efficient water-soluble fluorescent chemosensor based on furan Schiff base functionalized PEG for the sensitive detection of Al3+ in pure aqueous solution

2020 ◽  
Vol 44 (26) ◽  
pp. 11148-11154 ◽  
Author(s):  
Liping Bai ◽  
Yuhang Xu ◽  
Leixuan Li ◽  
Farong Tao ◽  
Shuangshuang Wang ◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Schiff Base ◽  
Polyethylene Glycol ◽  
Water Soluble ◽  
Sensitive Detection ◽  
Fluorescent Chemosensor ◽  
Base Unit ◽  
Pure Aqueous Solution

An efficient reversible fluorescent chemosensor, PEGFB, based on polyethylene glycol bearing a furan Schiff base unit has been successfully developed to sensitively detect Al3+ in pure aqueous solution.

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