Au nanoparticle-loaded PDMAEMA brush grafted graphene oxide hybrid systems for thermally smart catalysis

RSC Advances ◽  
2014 ◽  
Vol 4 (84) ◽  
pp. 44480-44485 ◽  
Author(s):  
Jing Chen ◽  
Peng Xiao ◽  
Jincui Gu ◽  
Youju Huang ◽  
Jiawei Zhang ◽  
...  
Carbon ◽  
2014 ◽  
Vol 71 ◽  
pp. 238-248 ◽  
Author(s):  
Mingyi Tang ◽  
Xingrui Wang ◽  
Fei Wu ◽  
Yue Liu ◽  
Sai Zhang ◽  
...  

Author(s):  
A. Sugita ◽  
T. Makiyama ◽  
R. Aoshima ◽  
A. Ono ◽  
W. Inami ◽  
...  

The Analyst ◽  
2013 ◽  
Vol 138 (23) ◽  
pp. 7101 ◽  
Author(s):  
Yuting Yan ◽  
Qian Liu ◽  
Kun Wang ◽  
Ling Jiang ◽  
Xingwang Yang ◽  
...  

Nanomaterials ◽  
2020 ◽  
Vol 10 (12) ◽  
pp. 2376 ◽  
Author(s):  
Marco Lunardon ◽  
JiaJia Ran ◽  
Dario Mosconi ◽  
Carla Marega ◽  
Zhanhua Wang ◽  
...  

A peculiar 3D graphene-based architecture, i.e., partial reduced-Graphene Oxide Aerogel Microspheres (prGOAM), having a dandelion-like morphology with divergent microchannels to implement innovative electrocatalysts for the hydrogen evolution reaction (HER) is investigated in this paper. prGOAM was used as a scaffold to incorporate exfoliated transition metals dichalcogenide (TMDC) nanosheets, and the final hybrid materials have been tested for HER and photo-enhanced HER. The aim was to create a hybrid material where electronic contacts among the two pristine materials are established in a 3D architecture, which might increase the final HER activity while maintaining accessible the TMDC catalytic sites. The adopted bottom-up approach, based on combining electrospraying with freeze-casting techniques, successfully provides a route to prepare TMDC/prGOAM hybrid systems where the dandelion-like morphology is retained. Interestingly, the microspherical morphology is also maintained in the tested electrode and after the electrocatalytic experiments, as demonstrated by scanning electron microscopy images. Comparing the HER activity of the TMDC/prGOAM hybrid systems with that of TMDC/partially reduced-Graphene Oxide (prGO) and TMDC/Vulcan was evidenced in the role of the divergent microchannels present in the 3D architecture. HER photoelectron catalytic (PEC) tests have been carried out and demonstrated an interesting increase in HER performance.


2016 ◽  
Vol 8 (2) ◽  
pp. 401-408 ◽  
Author(s):  
Gül Kotan ◽  
Faruk Kardaş ◽  
Özlem Aktaş Yokuş ◽  
Onur Akyıldırım ◽  
Hasan Saral ◽  
...  

We report the synthesis of Ru@Au nanoparticles involved l-cysteine functionalized reduced graphene oxide (rGO) composites (NSrGO/Ru@AuNPs).


Micromachines ◽  
2021 ◽  
Vol 12 (10) ◽  
pp. 1256
Author(s):  
Pingping Xu ◽  
Wenpo Feng ◽  
Mei Wang ◽  
Ling Zhang ◽  
Gaofeng Liang ◽  
...  

The early detection of tumor markers has an effective role in the treatment of cancer. Here, a new sandwich-type electrochemical immunosensor for early label-free detection of the cancer biomarker carcinoembryonic antigen (CEA) was developed. Dendritic tri-fan blade-like PdAuCu nanoparticles (PdAuCu NPs)/amine functionalized graphene oxide (NH2-GO) were the label of secondary antibodies (Ab2), and Au nanoparticle-decorated polydopamines (Au/PDA) were immobilized on a screen-printed carbon electrode (SPCE) as the substrate materials. Dendritic tri-fan blade-like PdAuCu NPs/NH2-GO was synthesized according to a simple hydrothermal procedure and used to immobilize antibodies (Ab2) with large surfaces areas, increased catalytic properties and good adsorption to amplify the current signals. Subsequently, Ab2/PdAuCu NPs/NH2-GO catalyzed the reduction of H2O2 in the sandwich-type immunoreactions. Under optimal conditions, the immunosensor exhibited a satisfactory response to CEA with a limit detection of 0.07 pg mL−1 and a linear detection range from 0.1 pg mL−1 to 200 ng mL−1. The proposed immunosensor could be suitable enough for a real sample analysis of CEA, and has clinical value in the early diagnosis of cancer.


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