Metal-catalyst-free growth of carbon nanotubes/carbon nanofibers on carbon blacks using chemical vapor deposition

RSC Advances ◽  
2014 ◽  
Vol 4 (76) ◽  
pp. 40251-40258 ◽  
Author(s):  
Zhi-Yan Zeng ◽  
Jarrn-Horng Lin

Carbon black can act as catalysts to grow carbon nanotubes or carbon nanofibers through a metal-catalyst-free thermal chemical vapor deposition.

RSC Advances ◽  
2017 ◽  
Vol 7 (53) ◽  
pp. 33185-33193 ◽  
Author(s):  
Shan Zheng ◽  
Guofang Zhong ◽  
Xingyi Wu ◽  
Lorenzo D'Arsiè ◽  
John Robertson

We study the metal-catalyst-free growth of uniform and continuous graphene on different insulating substrates by microwave plasma-enhanced chemical vapor deposition (PECVD) with a gas mixture of C2H2, NH3, and H2 at a temperature of 700–750 °C.


2008 ◽  
Vol 39 (1) ◽  
pp. 1766
Author(s):  
Jian-Min Jeng ◽  
Wen-Ching Shih ◽  
Ming-hong Tsai ◽  
Chi-Tsung Lo ◽  
Tzung-Han Yang ◽  
...  

2010 ◽  
Vol 133 (3) ◽  
Author(s):  
Myung Gwan Hahm ◽  
Young-Kyun Kwon ◽  
Ahmed Busnaina ◽  
Yung Joon Jung

Due to their unique one-dimensional nanostructure along with excellent mechanical, electrical, and optical properties, carbon nanotubes (CNTs) become a promising material for diverse nanotechnology applications. However, large-scale and structure controlled synthesis of CNTs still have many difficulties due to the lack of understanding of the fundamental growth mechanism of CNTs, as well as the difficulty of controlling atomic-scale physical and chemical reactions during the nanotube growth process. Especially, controlling the number of graphene wall, diameter, and chirality of CNTs are the most important issues that need to be solved to harness the full potential of CNTs. Here we report the large-scale selective synthesis of vertically aligned single walled carbon nanotubes (SWNTs) and double walled carbon nanotubes (DWNTs) by controlling the size of catalyst nanoparticles in the highly effective oxygen assisted thermal chemical vapor deposition (CVD) process. We also demonstrate a simple but powerful strategy for synthesizing ultrahigh density and diameter selected vertically aligned SWNTs through the precise control of carbon flow during a thermal CVD process.


Carbon ◽  
2014 ◽  
Vol 68 ◽  
pp. 399-405 ◽  
Author(s):  
Yun Liu ◽  
Minghan Xu ◽  
Xingzhong Zhu ◽  
Minmin Xie ◽  
Yanjie Su ◽  
...  

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