Liquid phase stepwise growth of surface mounted metal–organic frameworks for exploratory research and development of applications

2014 ◽  
Vol 1 (6) ◽  
pp. 442 ◽  
Author(s):  
Min Tu ◽  
Suttipong Wannapaiboon ◽  
Roland A. Fischer
Keyword(s):  
Liquid Phase ◽  
Research And Development ◽  
Metal Organic Frameworks ◽  
Exploratory Research ◽  
Metal Organic

scholarly journals Metal-Organic Frameworks in Oxidation Catalysis with Hydrogen Peroxide

Catalysts ◽  
2021 ◽  
Vol 11 (2) ◽  
pp. 283
Author(s):  
Oxana Kholdeeva ◽  
Nataliya Maksimchuk
Keyword(s):  
Hydrogen Peroxide ◽  
Liquid Phase ◽  
Selective Oxidation ◽  
Metal Organic Frameworks ◽  
Short Review ◽  
Catalytic Performance ◽  
Oxidation Catalysis ◽  
Catalyst Stability ◽  
Aqueous Hydrogen Peroxide ◽  
Metal Organic

In recent years, metal–organic frameworks (MOFs) have received increasing attention as selective oxidation catalysts and supports for their construction. In this short review paper, we survey recent findings concerning use of MOFs in heterogeneous liquid-phase selective oxidation catalysis with the green oxidant–aqueous hydrogen peroxide. MOFs having outstanding thermal and chemical stability, such as Cr(III)-based MIL-101, Ti(IV)-based MIL-125, Zr(IV)-based UiO-66(67), Zn(II)-based ZIF-8, and some others, will be in the main focus of this work. The effects of the metal nature and MOF structure on catalytic activity and oxidation selectivity are analyzed and the mechanisms of hydrogen peroxide activation are discussed. In some cases, we also make an attempt to analyze relationships between liquid-phase adsorption properties of MOFs and peculiarities of their catalytic performance. Attempts of using MOFs as supports for construction of single-site catalysts through their modification with heterometals will be also addressed in relation to the use of such catalysts for activation of H2O2. Special attention is given to the critical issues of catalyst stability and reusability. The scope and limitations of MOF catalysts in H2O2-based selective oxidation are discussed.

Toward Liquid Phase Processable Metal Organic Frameworks: Dream or Reality?

2021 ◽  
Author(s):  
Daria Poloneeva ◽  
Shuvo Jit Datta ◽  
Luis Garzon-Tovar ◽  
Sara Durini ◽  
Magnus Rueping ◽  
...  
Keyword(s):  
Liquid Phase ◽  
Metal Organic Frameworks ◽  
Metal Organic

Fabrication of free-standing ultrathin films of porous metal-organic frameworks by liquid-phase epitaxy and subsequent delamination

2010 ◽  
Vol 4 (8-9) ◽  
pp. 197-199 ◽  
Author(s):  
Masih Darbandi ◽  
Hasan K. Arslan ◽  
Osama Shekhah ◽  
Asif Bashir ◽  
Alexander Birkner ◽  
...  
Keyword(s):  
Liquid Phase ◽  
Liquid Phase Epitaxy ◽  
Ultrathin Films ◽  
Metal Organic Frameworks ◽  
Porous Metal ◽  
Free Standing ◽  
Metal Organic

Mixed-Metal Metal–Organic Frameworks as Catalysts for Liquid-Phase Oxidation of Toluene and Cycloalkanes

2017 ◽  
Vol 42 (10) ◽  
pp. 4383-4390 ◽  
Author(s):  
Abdul Malik P. Peedikakkal ◽  
Abiola Azeez Jimoh ◽  
M. Nasiruzzaman Shaikh ◽  
Bassam El Ali
Keyword(s):  
Liquid Phase ◽  
Metal Organic Frameworks ◽  
Liquid Phase Oxidation ◽  
Mixed Metal ◽  
Metal Metal ◽  
Phase Oxidation ◽  
Metal Organic
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