scholarly journals Geomimetics for green polymer synthesis: highly ordered polyimides via hydrothermal techniques

2014 ◽  
Vol 5 (12) ◽  
pp. 3771-3776 ◽  
Author(s):  
Bettina Baumgartner ◽  
Michael J. Bojdys ◽  
Miriam M. Unterlass

We mimic a geological ore formation mechanism, so-called hydrothermal crystallization, to obtain highly crystalline high-performance polymers. After only 1 h under hydrothermal conditions, a fully condensed polyimide depicting microflower morphologies is obtained.

Author(s):  
Sengshiu Chung ◽  
Peggy Cebe

We are studying the crystallization and annealing behavior of high performance polymers, like poly(p-pheny1ene sulfide) PPS, and poly-(etheretherketone), PEEK. Our purpose is to determine whether PPS, which is similar in many ways to PEEK, undergoes reorganization during annealing. In an effort to address the issue of reorganization, we are studying solution grown single crystals of PPS as model materials.Observation of solution grown PPS crystals has been reported. Even from dilute solution, embrionic spherulites and aggregates were formed. We observe that these morphologies result when solutions containing uncrystallized polymer are cooled. To obtain samples of uniform single crystals, we have used two-stage self seeding and solution replacement techniques.


Author(s):  
A. L. Rusanov ◽  
L. G. Komarova ◽  
M. P. Prigozhina ◽  
V. A. Tartakovsky ◽  
S. A. Shevelev ◽  
...  

2020 ◽  
Vol 27 (6) ◽  
pp. 2195-2202
Author(s):  
El Hadji Ndongo Diaw ◽  
Severine Le Roy ◽  
Gilbert Teyssedre ◽  
Eddy Aubert

2011 ◽  
Vol 217-218 ◽  
pp. 1606-1610
Author(s):  
Dong Jiang ◽  
Xiao Ran Zhang ◽  
Yan Mei Ma ◽  
Cheng You Ma

A series of random polysulfone/polyethersulfone (PSF/PES) copolymers were synthesized by the polycondensation of 4, 4'-isopropylidendiphenol, 4, 4΄-dihyolroxy diphenyl sulfone and 4, 4'-dichlorodiphenyl sulfone in the presence of K2CO3. We obtained a series of copolymers by changing the molar ratio of 4, 4΄-dihyolroxy diphenyl sulfone and 4, 4'-isopropylidendiphenol (it was marked as the ratio of S:A). The copolymers have the similar solubility with polyethersulfone. They also have high glass transition temperatures (Tg: 199°C~229°C) and 5% weight loss temperatures (4, 4'-isopropylidendiphenol: 4, 4΄-dihyolroxy diphenyl sulfone=1:1, Td5=497°C). At the same time the elongation at break is much higher than that of PES, while the tensile strength is a little lower than that of PES.


2004 ◽  
Vol 16 (3) ◽  
pp. 381-390 ◽  
Author(s):  
Meghan Spence ◽  
James A. Newell ◽  
Michael Lynch ◽  
T. J. Lee ◽  
Jenn Demetrio ◽  
...  

2008 ◽  
Vol 26 (01) ◽  
pp. 55 ◽  
Author(s):  
Guan-jun Chang ◽  
Xuan Luo ◽  
Lin Zhang ◽  
Run-xiong Lin

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