Asymmetric synthesis of axially chiral anilides by Pd-catalyzed allylic substitutions with P/olefin ligands

2015 ◽  
Vol 13 (1) ◽  
pp. 125-132 ◽  
Author(s):  
Yilin Liu ◽  
Xiangqing Feng ◽  
Haifeng Du
Keyword(s):  
Asymmetric Synthesis ◽  
Allylic Substitutions ◽  
Axially Chiral ◽  
Palladium Catalyzed

Palladium-catalyzed allylic substitutions of ortho-substituted anilides using P/olefin ligands were achieved to afford chiral anilides with up to 84% ee.

Palladium-Catalyzed Asymmetric Synthesis of Axially Chiral Allenylsilanes and Their Application to SE2′ Chirality Transfer Reactions

2010 ◽  
Vol 12 (24) ◽  
pp. 5736-5739 ◽  
Author(s):  
Masamichi Ogasawara ◽  
Atsushi Okada ◽  
Velusamy Subbarayan ◽  
Sebastian Sörgel ◽  
Tamotsu Takahashi
Keyword(s):  
Asymmetric Synthesis ◽  
Transfer Reactions ◽  
Chirality Transfer ◽  
Axially Chiral ◽  
Palladium Catalyzed

Asymmetric Synthesis of Axially Chiral Naphthyl-C3-indoles via a Palladium-Catalyzed Cacchi Reaction

2021 ◽  
Author(s):  
Cong-Shuai Wang ◽  
Liang Wei ◽  
Cong Fu ◽  
Xin-Heng Wang ◽  
Chun-Jiang Wang
Keyword(s):  
Asymmetric Synthesis ◽  
Axially Chiral ◽  
Palladium Catalyzed

ChemInform Abstract: Palladium-Catalyzed Asymmetric Synthesis of Axially Chiral Allenylsilanes and Their Application to SE2′ Chirality Transfer Reactions.

ChemInform ◽  
2011 ◽  
Vol 42 (13) ◽  
pp. no-no
Author(s):  
Masamichi Ogasawara ◽  
Atsushi Okada ◽  
Velusamy Subbarayan ◽  
Sebastian Soergel ◽  
Tamotsu Takahashi
Keyword(s):  
Asymmetric Synthesis ◽  
Transfer Reactions ◽  
Chirality Transfer ◽  
Axially Chiral ◽  
Palladium Catalyzed

scholarly journals Palladium-Catalyzed Asymmetric Synthesis of Axially Chiral (Allenylmethyl)silanes and Chirality Transfer to Stereogenic Carbon Centers in SE′ Reactions.

ChemInform ◽  
2003 ◽  
Vol 34 (21) ◽  
Author(s):  
Masamichi Ogasawara ◽  
Kazuhito Ueyama ◽  
Takashi Nagano ◽  
Yoshiyuki Mizuhata ◽  
Tamio Hayashi
Keyword(s):  
Asymmetric Synthesis ◽  
Chirality Transfer ◽  
Carbon Centers ◽  
Axially Chiral ◽  
Palladium Catalyzed
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