An efficient room temperature core–shell AgPd@MOF catalyst for hydrogen production from formic acid

Nanoscale ◽  
2015 ◽  
Vol 7 (18) ◽  
pp. 8321-8325 ◽  
Author(s):  
Fei Ke ◽  
Luhuan Wang ◽  
Junfa Zhu
Keyword(s):  
Hydrogen Production ◽  
Formic Acid ◽  
Room Temperature ◽  
Core Shell ◽  
One Pot ◽  
Highly Active

Novel AgPd@MIL-100(Fe) core–shell NPs were fabricated by a facile one-pot method. The NPs are highly active for the dehydrogenation of formic acid without any additives at room temperature.

Hydrogen production from formic acid decomposition at room temperature using a Ag–Pd core–shell nanocatalyst

2011 ◽  
Vol 6 (5) ◽  
pp. 302-307 ◽  
Author(s):  
Karaked Tedsree ◽  
Tong Li ◽  
Simon Jones ◽  
Chun Wong Aaron Chan ◽  
Kai Man Kerry Yu ◽  
...  
Keyword(s):  
Hydrogen Production ◽  
Formic Acid ◽  
Room Temperature ◽  
Core Shell ◽  
Acid Decomposition ◽  
Formic Acid Decomposition

scholarly journals A Process for Hydrogen Production from the Catalytic Decomposition of Formic Acid over Iridium—Palladium Nanoparticles

Materials ◽  
2021 ◽  
Vol 14 (12) ◽  
pp. 3258
Author(s):  
Hamed M. Alshammari ◽  
Mohammad Hayal Alotaibi ◽  
Obaid F. Aldosari ◽  
Abdulellah S. Alsolami ◽  
Nuha A. Alotaibi ◽  
...  
Keyword(s):  
Hydrogen Production ◽  
Formic Acid ◽  
Activated Charcoal ◽  
Palladium Nanoparticles ◽  
Room Temperature ◽  
Catalytic Decomposition ◽  
Conversion Yield ◽  
Production Of Hydrogen ◽  
Commercial Applications

The present study investigates a process for the selective production of hydrogen from the catalytic decomposition of formic acid in the presence of iridium and iridium–palladium nanoparticles under various conditions. It was found that a loading of 1 wt.% of 2% palladium in the presence of 1% iridium over activated charcoal led to a 43% conversion of formic acid to hydrogen at room temperature after 4 h. Increasing the temperature to 60 °C led to further decomposition and an improvement in conversion yield to 63%. Dilution of formic acid from 0.5 to 0.2 M improved the decomposition, reaching conversion to 81%. The reported process could potentially be used in commercial applications.

Hollow Ag@Pd core–shell nanotubes as highly active catalysts for the electro-oxidation of formic acid

2012 ◽  
Vol 23 (10) ◽  
pp. 105609 ◽  
Author(s):  
Yuanyuan Jiang ◽  
Yizhong Lu ◽  
Dongxue Han ◽  
Qixian Zhang ◽  
Li Niu
Keyword(s):  
Formic Acid ◽  
Core Shell ◽  
Highly Active ◽  
Electro Oxidation

Core–Shell Engineering of Pd–Ag Bimetallic Catalysts for Efficient Hydrogen Production from Formic Acid Decomposition

ACS Catalysis ◽  
2018 ◽  
Vol 9 (2) ◽  
pp. 819-826 ◽  
Author(s):  
Bu-Seo Choi ◽  
Jaeeun Song ◽  
Minjin Song ◽  
Bon Seung Goo ◽  
Young Wook Lee ◽  
...  
Keyword(s):  
Hydrogen Production ◽  
Formic Acid ◽  
Bimetallic Catalysts ◽  
Core Shell ◽  
Acid Decomposition ◽  
Formic Acid Decomposition

Efficient hydrogen production from formic acid using TiO2-supported AgPd@Pd nanocatalysts

2015 ◽  
Vol 3 (8) ◽  
pp. 4453-4461 ◽  
Author(s):  
Masashi Hattori ◽  
Hisahiro Einaga ◽  
Takeshi Daio ◽  
Masaharu Tsuji
Keyword(s):  
Hydrogen Production ◽  
Formic Acid ◽  
Polyol Method ◽  
Core Shell

AgPd@Pd core–shell nanocatalysts loaded on TiO2 nanoparticles were fabricated using a two-step microwave–polyol method for efficient hydrogen production from decomposition of formic acid.

One-pot synthesis of Pd–Pt@Pd core–shell nanocrystals with enhanced electrocatalytic activity for formic acid oxidation

CrystEngComm ◽  
2014 ◽  
Vol 16 (13) ◽  
pp. 2560-2564 ◽  
Author(s):  
Qiang Yuan ◽  
Da-Bing Huang ◽  
Hong-Hui Wang ◽  
Zhi-You Zhou ◽  
Qingxiao Wang
Keyword(s):  
Aqueous Solution ◽  
Formic Acid ◽  
Electrocatalytic Activity ◽  
Formic Acid Oxidation ◽  
Acid Oxidation ◽  
Core Shell ◽  
One Pot ◽  
Solution Approach ◽  
One Pot Synthesis

Pd–Pt@Pd core–shell nanocrystals were directly synthesized through an aqueous solution approach without any preformed Pd or Pt seeds.

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