Magnetic, electrochemical and optical properties of a sulfate-bridged Co(ii) imidazole dimer

2014 ◽  
Vol 38 (12) ◽  
pp. 5856-5860 ◽  
Author(s):  
Michael J. Murphy ◽  
Pavel M. Usov ◽  
Felix J. Rizzuto ◽  
Cameron J. Kepert ◽  
Deanna M. D'Alessandro

The electrochemical, optical and magnetic properties of a sulfate-bridged high spin Co(ii) dimer, [Co2(DMIM)4(μ2-O2,O,O′-SO4)2]·2MeCN are reported. Antiferromagnetic coupling across the μ2-(O2-sulfato) bridging mode has been identified with J = −28 cm−1.

2018 ◽  
Vol 6 (39) ◽  
pp. 10502-10512 ◽  
Author(s):  
Brandon Azeredo ◽  
Anne Carton ◽  
Cédric Leuvrey ◽  
Céline Kiefer ◽  
Dris Ihawakrim ◽  
...  

A ZnO/PBA/Fe3−δO4 nanocomposite displays enhanced magnetic and optical properties as a result of dual synergy.


2014 ◽  
Vol 16 (45) ◽  
pp. 24884-24891 ◽  
Author(s):  
A. P. Yelisseyev ◽  
Xingxing Jiang ◽  
V. P. Solntsev ◽  
T. B. Bekker ◽  
Zheshuai Lin

The optical properties of Ba5(BO3)3F as a bulk single crystal are investigated experimentally and theoretically.


2021 ◽  
Vol 7 (7) ◽  
pp. 105
Author(s):  
Min Zeng ◽  
Xi Chen ◽  
Hui-Zhong Kou

Two carboxylate-bridged one-dimensional chain complexes, {[MnII(MeOH)2][FeIII(L)2]2}n (1) and {[MnII(DMF)2][MnIII(L)2]2·DMF}n (2) [H2L = ((2-carboxyphenyl)azo)-benzaldoxime], containing a low-spin [FeIII(L)2]− or [MnIII(L)2]− unit were synthesized. Magnetic measurements show that the adjacent high-spin MnII and low-spin MIII ions display weak antiferromagnetic coupling via the syn–anti carboxyl bridges, with J = −0.066(2) cm−1 for complex 1 and J = −0.274(2) cm−1 for complex 2.


1993 ◽  
Vol 328 ◽  
Author(s):  
P. Wautelet ◽  
J. Le Moigne ◽  
P. Turek

ABSTRACTA series of new stable fiinctionalised aryl ethynyl compounds bearing nitronyl-nitroxy and galvinoxyl radicals were synthesised as potential organic magnets with optical properties. Our goal is to construct biradicals in linear or broken rod molecules with the aim of probing i) the efficiency of the conjugation for the intramolecular spin exchange, and / or ii) the inter-Molecular Magnetic interaction between the neighboring radicals in the solid state Materials.We focused our attention on the preparation of phenoxy, and galvinoxyl biradicals of the conjugated phenyl and thienyl diethynyl Moieties. The synthesis of these new components will be presented. Their optical and magnetic properties will be discussed both in solution and in the solid state.


RSC Advances ◽  
2015 ◽  
Vol 5 (125) ◽  
pp. 103465-103473 ◽  
Author(s):  
R. Avinash Kumar ◽  
K. Suresh Babu ◽  
Arup Dasgupta ◽  
R. Ramaseshan

Iron and europium co-doped cerium oxide nanoparticles exhibits interesting optical and magnetic properties.


2010 ◽  
Vol 65 (10) ◽  
pp. 1191-1198 ◽  
Author(s):  
Inga Schellenberg ◽  
Hannes Lincke ◽  
Wilfried Hermes ◽  
Volker Dittrich ◽  
Robert Glaum ◽  
...  

Several REZnPnO phases of the ZrCuSiAs type (RE = rare earth element, Pn = P, As, Sb) were synthesized in X-ray-pure form in NaCl/KCl salt fluxes. The structure of PrZnSbO was refined from single-crystal diffractometer data: P4/nmm, a = 418.79(8), c = 946.7(5) pm, wR2 = 0.0349, 192 F2 values, 12 parameters. The REZnPnO pnictide oxides were studied with respect to magnetic susceptibility, 121Sb Mössbauer spectroscopy, and optical properties.


Photonics ◽  
2019 ◽  
Vol 6 (4) ◽  
pp. 107
Author(s):  
Yuriy G. Galyametdinov ◽  
Dmitriy O. Sagdeev ◽  
Andrey A. Sukhanov ◽  
Violeta K. Voronkova ◽  
Radik R. Shamilov

Synthesis of nanoparticles doped with various ions can significantly expand their functionality. The conditions of synthesis exert significant influence on the distribution nature of doped ions and therefore the physicochemical properties of nanoparticles. In this paper, a correlation between the conditions of synthesis of manganese-containing cadmium sulfide or zinc sulfide nanoparticles and their optical and magnetic properties is analyzed. Electron paramagnetic resonance was used to study the distribution of manganese ions in nanoparticles and the intensity of interaction between them depending on the conditions of synthesis of nanoparticles, the concentration of manganese, and the type of initial semiconductor. The increase of manganese concentration is shown to result in the formation of smaller CdS-based nanoparticles. Luminescent properties of nanoparticles were studied. The 580 nm peak, which is typical for manganese ions, becomes more distinguished with the increase of their concentration and the time of synthesis.


2020 ◽  
Vol 43 (1) ◽  
Author(s):  
Muhammad Yaseen ◽  
Muhammad Dilawar ◽  
Hina Ambreen ◽  
Shamsa Bibi ◽  
Shafiq Ur Rehman ◽  
...  

2017 ◽  
Vol 28 (20) ◽  
pp. 15668-15675 ◽  
Author(s):  
R. Sathish Kumar ◽  
S. Johnson Jeyakumar ◽  
M. Jothibas ◽  
I. Kartharinal Punithavathy ◽  
J. Prince Richard

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