Synthesis of 2-substituted pyrimidines and benzoxazoles via a visible-light-driven organocatalytic aerobic oxidation: enhancement of the reaction rate and selectivity by a base

2014 ◽  
Vol 16 (8) ◽  
pp. 3752 ◽  
Author(s):  
Lin Wang ◽  
Zhi-Gang Ma ◽  
Xiao-Jing Wei ◽  
Qing-Yuan Meng ◽  
Deng-Tao Yang ◽  
...  
Keyword(s):  
Visible Light ◽  
Reaction Rate ◽  
Aerobic Oxidation ◽  
Visible Light Driven

scholarly journals Recent advances in visible-light-driven organic reactions

2017 ◽  
Vol 4 (3) ◽  
pp. 359-380 ◽  
Author(s):  
Qiang Liu ◽  
Li-Zhu Wu
Keyword(s):  
Visible Light ◽  
Aerobic Oxidation ◽  
Environmental Benefits ◽  
Organic Reactions ◽  
Light Sources ◽  
Recent Advances ◽  
Visible Light Driven ◽  
Hydrogen Evolution Reactions ◽  
Green Chemical Synthesis ◽  
Powerful Strategy

Abstract In recent years, visible-light-driven organic reactions have been experiencing a significant renaissance in response to topical interest in environmentally friendly green chemical synthesis. The transformations using inexpensive, readily available visible-light sources have come to the forefront in organic chemistry as a powerful strategy for the activation of small molecules. In this review, we focus on recent advances in the development of visible-light-driven organic reactions, including aerobic oxidation, hydrogen-evolution reactions, energy-transfer reactions and asymmetric reactions. These key research topics represent a promising strategy towards the development of practical, scalable industrial processes with great environmental benefits.

Visible light-driven aerobic oxidation catalyzed by a diiron(IV) μ-oxo biscorrole complex

2013 ◽  
Vol 464-465 ◽  
pp. 95-100 ◽  
Author(s):  
Rui Zhang ◽  
Eric Vanover ◽  
Tse-Hong Chen ◽  
Helen Thompson
Keyword(s):  
Visible Light ◽  
Aerobic Oxidation ◽  
Visible Light Driven

A self-assembled perylene diimide nanobelt for efficient visible-light-driven photocatalytic H2 evolution

2019 ◽  
Vol 55 (56) ◽  
pp. 8090-8093 ◽  
Author(s):  
Kangyi Kong ◽  
Shicong Zhang ◽  
Yanmeng Chu ◽  
Yue Hu ◽  
Fengtao Yu ◽  
...  
Keyword(s):  
Visible Light ◽  
Hydrogen Evolution ◽  
Hydrogen Evolution Reaction ◽  
Reaction Rate ◽  
Perylene Diimide ◽  
Supramolecular System ◽  
H2 Evolution ◽  
Photocatalytic Hydrogen Evolution ◽  
Visible Light Driven ◽  
Photocatalytic H2 Evolution

In this paper, a supramolecular system (P-PMPDI) has been successfully developed for highly efficient photocatalytic hydrogen evolution. P-PMPDI showed a superior hydrogen evolution reaction rate of 11.7 mmol g−1 h−1 and a recorded AQY of 2.96% at 550 nm.

Highly efficient visible-light-driven photoelectro-catalytic selective aerobic oxidation of biomass alcohols to aldehydes

2014 ◽  
Vol 16 (8) ◽  
pp. 3860-3869 ◽  
Author(s):  
Yajun Zhang ◽  
Guohua Zhao ◽  
Yanan Zhang ◽  
Xiaofeng Huang
Keyword(s):  
Visible Light ◽  
Aerobic Oxidation ◽  
Mild Conditions ◽  
Highly Efficient ◽  
Visible Light Driven ◽  
Selective Aerobic Oxidation

Highly efficient visible-light driven synergistic photoelectrocatalytic aerobic oxidation of biomass alcohols to aldehydes using Au/CeO2–TIO2 NT photocathodes under the mild conditions.

scholarly journals Cu(ii) vitamin C tunes photocatalytic activity of TiO2 nanoparticles for visible light-driven aerobic oxidation of benzylic alcohols

RSC Advances ◽  
2020 ◽  
Vol 10 (20) ◽  
pp. 12053-12059
Author(s):  
Narges Pourmorteza ◽  
Maasoumeh Jafarpour ◽  
Fahimeh Feizpour ◽  
Abdolreza Rezaeifard
Keyword(s):  
Photocatalytic Activity ◽  
Vitamin C ◽  
Visible Light ◽  
Tio2 Nanoparticles ◽  
Molecular Oxygen ◽  
Aerobic Oxidation ◽  
Free Condition ◽  
Benzylic Alcohols ◽  
Solvent Free Condition ◽  
Visible Light Driven

The combination of TiO2-AA-Cu(ii) nanoparticles with TEMPO and molecular oxygen (air) afforded an active catalytic system for the selective oxidation of diverse set of benzylic alcohols under solvent-free condition.

Visible-light-mediated aerobic selenation of (hetero)arenes with diselenides

2017 ◽  
Vol 19 (23) ◽  
pp. 5559-5563 ◽  
Author(s):  
Qing-Bao Zhang ◽  
Yong-Liang Ban ◽  
Pan-Feng Yuan ◽  
Shou-Jiao Peng ◽  
Jian-Guo Fang ◽  
...  
Keyword(s):  
Visible Light ◽  
Room Temperature ◽  
Aerobic Oxidation ◽  
Visible Light Driven

The first visible-light driven aerobic oxidation for the direct selenation of (hetero)arenes has been developed at room temperature, providing an eco-friendly, atom-economical protocol to prepare unsymmetrical selenides from easily accessible diselenides.

Bi2WO6: A highly chemoselective visible light photocatalyst toward aerobic oxidation of benzylic alcohols in water

RSC Advances ◽  
2014 ◽  
Vol 4 (6) ◽  
pp. 2904-2910 ◽  
Author(s):  
Yanhui Zhang ◽  
Yi-Jun Xu
Keyword(s):  
Sustainable Development ◽  
Green Chemistry ◽  
Visible Light ◽  
Aerobic Oxidation ◽  
Organic Transformations ◽  
Visible Light Photocatalyst ◽  
Benzylic Alcohols ◽  
Visible Light Driven

The visible-light-driven flower-like Bi2WO6 photocatalyst toward “green” chemistry oriented selective organic transformations in water is an essential pathway to sustainable development.

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