Bi2WO6: A highly chemoselective visible light photocatalyst toward aerobic oxidation of benzylic alcohols in water

RSC Advances ◽  
2014 ◽  
Vol 4 (6) ◽  
pp. 2904-2910 ◽  
Author(s):  
Yanhui Zhang ◽  
Yi-Jun Xu
Keyword(s):  
Sustainable Development ◽  
Green Chemistry ◽  
Visible Light ◽  
Aerobic Oxidation ◽  
Organic Transformations ◽  
Visible Light Photocatalyst ◽  
Benzylic Alcohols ◽  
Visible Light Driven

The visible-light-driven flower-like Bi2WO6 photocatalyst toward “green” chemistry oriented selective organic transformations in water is an essential pathway to sustainable development.

scholarly journals Cu(ii) vitamin C tunes photocatalytic activity of TiO2 nanoparticles for visible light-driven aerobic oxidation of benzylic alcohols

RSC Advances ◽  
2020 ◽  
Vol 10 (20) ◽  
pp. 12053-12059
Author(s):  
Narges Pourmorteza ◽  
Maasoumeh Jafarpour ◽  
Fahimeh Feizpour ◽  
Abdolreza Rezaeifard
Keyword(s):  
Photocatalytic Activity ◽  
Vitamin C ◽  
Visible Light ◽  
Tio2 Nanoparticles ◽  
Molecular Oxygen ◽  
Aerobic Oxidation ◽  
Free Condition ◽  
Benzylic Alcohols ◽  
Solvent Free Condition ◽  
Visible Light Driven

The combination of TiO2-AA-Cu(ii) nanoparticles with TEMPO and molecular oxygen (air) afforded an active catalytic system for the selective oxidation of diverse set of benzylic alcohols under solvent-free condition.

scholarly journals Recent advances in visible-light-driven organic reactions

2017 ◽  
Vol 4 (3) ◽  
pp. 359-380 ◽  
Author(s):  
Qiang Liu ◽  
Li-Zhu Wu
Keyword(s):  
Visible Light ◽  
Aerobic Oxidation ◽  
Environmental Benefits ◽  
Organic Reactions ◽  
Light Sources ◽  
Recent Advances ◽  
Visible Light Driven ◽  
Hydrogen Evolution Reactions ◽  
Green Chemical Synthesis ◽  
Powerful Strategy

Abstract In recent years, visible-light-driven organic reactions have been experiencing a significant renaissance in response to topical interest in environmentally friendly green chemical synthesis. The transformations using inexpensive, readily available visible-light sources have come to the forefront in organic chemistry as a powerful strategy for the activation of small molecules. In this review, we focus on recent advances in the development of visible-light-driven organic reactions, including aerobic oxidation, hydrogen-evolution reactions, energy-transfer reactions and asymmetric reactions. These key research topics represent a promising strategy towards the development of practical, scalable industrial processes with great environmental benefits.

Synthesis of 2-substituted pyrimidines and benzoxazoles via a visible-light-driven organocatalytic aerobic oxidation: enhancement of the reaction rate and selectivity by a base

2014 ◽  
Vol 16 (8) ◽  
pp. 3752 ◽  
Author(s):  
Lin Wang ◽  
Zhi-Gang Ma ◽  
Xiao-Jing Wei ◽  
Qing-Yuan Meng ◽  
Deng-Tao Yang ◽  
...  
Keyword(s):  
Visible Light ◽  
Reaction Rate ◽  
Aerobic Oxidation ◽  
Visible Light Driven

Visible-Light-Driven Organic Photochemical Reactions in the Absence of External Photocatalysts

Synthesis ◽  
2019 ◽  
Vol 51 (16) ◽  
pp. 3021-3054 ◽  
Author(s):  
Yi Wei ◽  
Quan-Quan Zhou ◽  
Fen Tan ◽  
Liang-Qiu Lu ◽  
Wen-Jing Xiao
Keyword(s):  
Visible Light ◽  
Transition Metal Complexes ◽  
Organic Dyes ◽  
Photochemical Reactions ◽  
Reaction Intermediates ◽  
Organic Transformations ◽  
Reaction Conditions ◽  
Inorganic Semiconductors ◽  
Visible Light Driven ◽  
Representative Work

Visible-light-driven organic photochemical reactions have attracted substantial attention from the synthetic community. Typically, catalytic quantities of photosensitizers, such as transition metal complexes, organic dyes, or inorganic semiconductors, are necessary to absorb visible light and trigger subsequent organic transformations. Recently, in contrast to these photocatalytic processes, a variety of photocatalyst-free organic photochemical transformations have been exploited for the efficient formation of carbon–carbon and carbon–heteroatom bonds. In addition to not requiring additional photocatalysts, they employ low-energy visible light irradiation, have mild reaction conditions, and enable broad substrate diversity and functional group tolerance. This review will focus on a summary of representative work in this field in terms of different photoexcitation modes.1 Introduction2 Visible Light Photoexcitation of a Single Substrate3 Visible Light Photoexcitation of Reaction Intermediates4 Visible Light Photoexcitation of EDA Complexes between Substrates5 Visible Light Photoexcitation of EDA Complexes between Substrates and Reaction Intermediates6 Visible Light Photoexcitation of Products7 Conclusion and Outlook

Click-based conjugated microporous polymers as efficient heterogeneous photocatalysts for organic transformations

2022 ◽  
Author(s):  
Shaolin Gan ◽  
Yan Zeng ◽  
Jiaxin Liu ◽  
Junqi Nie ◽  
Cuifen Lu ◽  
...  
Keyword(s):  
Visible Light ◽  
Porous Structure ◽  
Oxidative Coupling ◽  
Photoelectric Property ◽  
Synthetic Methods ◽  
Organic Transformations ◽  
Microporous Polymers ◽  
Visible Light Driven ◽  
Conjugated Microporous Polymers

Due to the tunable porous structure and photoelectric property, conjugated microporous polymers (CMPs) have provided a new platform for visible-light driven photocatalysis. Some synthetic methods like Sonogashira, Suzuki, oxidative coupling...

Visible light-catalytic dehydrogenation of benzylic alcohols to carbonyl compounds by using an eosin Y and nickel–thiolate complex dual catalyst system

2019 ◽  
Vol 21 (6) ◽  
pp. 1401-1405 ◽  
Author(s):  
Xiu-Jie Yang ◽  
Yi-Wen Zheng ◽  
Li-Qiang Zheng ◽  
Li-Zhu Wu ◽  
Chen-Ho Tung ◽  
...  
Keyword(s):  
Visible Light ◽  
Carbonyl Compounds ◽  
Catalyst System ◽  
Environmentally Benign ◽  
Eosin Y ◽  
Catalytic Dehydrogenation ◽  
Benzylic Alcohols ◽  
System P ◽  
Visible Light Driven

A simple and environmentally benign visible-light-driven dehydrogenation of benzylic alcohols with H2 as the only byproduct is achieved by using an eosin Y and nickel–thiolate complex dual catalyst system.

scholarly journals Facile one-step solvothermal synthesis of active carbon/BiOI microspheres with enhanced visible light-driven photocatalytic activity in the reduction of Cr(vi)

RSC Advances ◽  
2018 ◽  
Vol 8 (14) ◽  
pp. 7518-7522 ◽  
Author(s):  
YuanYou Wang ◽  
SuoJin Chen ◽  
DangQin Jin ◽  
AiQin Gong ◽  
XueJiao Xu ◽  
...  
Keyword(s):  
Photocatalytic Activity ◽  
Visible Light ◽  
Active Carbon ◽  
Solvothermal Synthesis ◽  
Polluted Water ◽  
Visible Light Photocatalyst ◽  
Visible Light Driven ◽  
One Step

Active carbon/BiOI microspheres have promising applications as an efficient visible-light photocatalyst for the treatment of Cr(vi)-polluted water.

scholarly journals Amino-Functionalized Zirconium and Cerium MOFs: Catalysts for Visible Light Induced Aerobic Oxidation of Benzylic Alcohols and Microwaves assisted N-Alkylation of Amines

2021 ◽  
pp. 118287
Author(s):  
Antonio Valverde-González ◽  
Mercedes Pintado-Sierra ◽  
Antonia Rasero-Almansa ◽  
Félix Sánchez ◽  
Marta Iglesias
Keyword(s):  
Visible Light ◽  
Aerobic Oxidation ◽  
Benzylic Alcohols
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