O–H bond oxidation by a monomeric MnIII–OMe complex

2015 ◽  
Vol 44 (7) ◽  
pp. 3295-3306 ◽  
Author(s):  
Gayan B. Wijeratne ◽  
Victor W. Day ◽  
Timothy A. Jackson
Keyword(s):  
Free Energies ◽  
Bond Dissociation

The structurally characterized [MnIII(OMe)(dpaq)]+ complex is the first example of a stable MnIII–OMe complex that can activate substrate O–H bonds with bond dissociation free energies up to 78.5 kcal mol−1 in acetonitrile.

scholarly journals O--H Bond Dissociation Free Energies of Hydroquinone and the Corresponding Radical Anion, Monoanion and Free Radical in Dimethyl Sulfoxide Solution.

1993 ◽  
Vol 47 ◽  
pp. 1144-1145 ◽  
Author(s):  
Vernon D. Parker ◽  
Jin-Pei Cheng ◽  
Kishan L. Handoo ◽  
Anne K. Jensen ◽  
Teddy K. Thorsen ◽  
...  
Keyword(s):  
Free Radical ◽  
Dimethyl Sulfoxide ◽  
Radical Anion ◽  
Free Energies ◽  
Bond Dissociation ◽  
Dimethyl Sulfoxide Solution

scholarly journals Substituent Effects on Homolytic Bond Dissociation Free Energies of Oxygen--Acetyl Bonds in Phenyl Acetates and Nitrogen--Acetyl Bonds in Acetanilides.

1996 ◽  
Vol 50 ◽  
pp. 1045-1049 ◽  
Author(s):  
Mogens L. Andersen ◽  
Tore Benneche ◽  
Kjell Undheim ◽  
Neucírio Ricardo de Azevedo ◽  
Pedro Henrique Ferri ◽  
...  
Keyword(s):  
Substituent Effects ◽  
Free Energies ◽  
Bond Dissociation

Bond Dissociation Free Energies of the H-A Bonds in HA2- Dianions

1995 ◽  
Vol 60 (13) ◽  
pp. 3932-3933 ◽  
Author(s):  
Yongyu Zhao ◽  
Frederick G. Bordwell
Keyword(s):  
Free Energies ◽  
Bond Dissociation
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