Bond Dissociation Free Energies of the H-A Bonds in HA2- Dianions

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Yongyu Zhao ◽  
Frederick G. Bordwell
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Neucírio Ricardo de Azevedo ◽  
Pedro Henrique Ferri ◽  
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The structurally characterized [MnIII(OMe)(dpaq)]+ complex is the first example of a stable MnIII–OMe complex that can activate substrate O–H bonds with bond dissociation free energies up to 78.5 kcal mol−1 in acetonitrile.


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