Palladium(ii)-1-phenylthio-2-arylchalcogenoethane complexes: palladium phosphide nano-peanut and ribbon formation controlled by chalcogen and Suzuki coupling activation

2015 ◽  
Vol 44 (14) ◽  
pp. 6600-6612 ◽  
Author(s):  
Gyandshwar Kumar Rao ◽  
Arun Kumar ◽  
Fariha Saleem ◽  
Mahabir P. Singh ◽  
Satyendra Kumar ◽  
...  

Suzuki coupling (cocktail pathway) by complexes of S/Se-ligand/PdP2 NPs prepared from Pd-complexes in TOP (temperature ≥ 280 °C) is efficient.

2008 ◽  
Vol 59 (7) ◽  
Author(s):  
Maria Maganu ◽  
Filip Chiraleu ◽  
Constantin Draghici ◽  
Gheorghe Mihai

The previous data obtained by 1H-NMR spectroscopy established the existence of an asymmetry of the bond between Pd and p-allylic groups, even in the p-allyl-Pd complexes dimers which are considered usually symmetric dimers. The asymmetry of the bond depends by the substitutes of the allylic group. Other analytical methods were investigated for additional proof of the obtained results. Thus, this paper discusses how this asymmetry would be reflected in the infrared spectra and in the reaction of the complexes with carbon monoxide.


2001 ◽  
Vol 4 (6) ◽  
pp. 521-524 ◽  
Author(s):  
J. Tois ◽  
R. Franzen ◽  
O. Aitio ◽  
I. Laakso ◽  
J. Huuskonen ◽  
...  
Keyword(s):  

Author(s):  
Hirokazu Seto ◽  
Takumi Tono ◽  
Akiko Nagaoka ◽  
Mai Yamamoto ◽  
Yumiko Hirohashi ◽  
...  

Poly(vinylbiphenyl)s bearing glycoside ligands at the side chains were prepared using the Suzuku coupling reaction. Effects of glycoside reactant concentration, halide species, glycoside species, and catalyst species on the incorporation...


2021 ◽  
pp. 153147
Author(s):  
Samson Lai ◽  
Noah Takaesu ◽  
Wen Xuan Lin ◽  
David M. Perrin

2021 ◽  
Author(s):  
Hajime Kameo ◽  
Akihiro Mushiake ◽  
Tomohito Isasa ◽  
Hiroyuki Matsuzaka ◽  
Didier Bourissou

Pd/Ni → Ge–F interactions supported by phosphine-chelation were found to trigger dual activation of Ge–F bonds under mild conditions.


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