[Mn2Ga4Sn4S20]8− T3 supertetrahedral nanocluster directed by a series of transition metal complexes

2015 ◽  
Vol 44 (5) ◽  
pp. 2416-2424 ◽  
Author(s):  
Cheng-Yang Yue ◽  
Xiao-Wu Lei ◽  
Li-Juan Feng ◽  
Chen Wang ◽  
Ya-Ping Gong ◽  
...  
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Nonlinear Optical ◽  
Second Order ◽  
Luminescence Properties ◽  
Thermal Stabilities ◽  
Tin Sulfides

Three new manganese gallium tin sulfides based on T3 supertetrahedral nanocluster of [Mn2Ga4Sn4S20]8− have been solvothermally synthesized and structurally characterized. The photocatalytic, second-order nonlinear optical and luminescence properties, as well as thermal stabilities of the title compounds were also studied.

scholarly journals Second-Order Nonlinear Optical Property for Transition Metal Complexes with Bis(imino)pyridine

2011 ◽  
Vol 27 (10) ◽  
pp. 2297-2302
Author(s):  
SUN Jian ◽  
◽  
SUN Xiu-Xin ◽  
SUN Shi-Ling ◽  
QIU Yong-Qing ◽  
...  
Keyword(s):  
Optical Property ◽  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Nonlinear Optical ◽  
Nonlinear Optical Property ◽  
Second Order

Nonlinear optical studies on transition metal complexes of o-aminobenzenethiol

1991 ◽  
Vol 179 (1-2) ◽  
pp. 79-84 ◽  
Author(s):  
Z.H. Kafafi ◽  
J.R. Lindle ◽  
C.S. Weisbecker ◽  
F.J. Bartoli ◽  
J.S. Shirk ◽  
...  
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Nonlinear Optical ◽  
Optical Studies

Third- and Fifth-Order Optical Properties of Transition Metal Complexes of Benzenedithiol at 1.064 μm

1992 ◽  
Vol 247 ◽  
Author(s):  
J. R. Lindle ◽  
C. S. Weisbecker ◽  
F. J. Bartoli ◽  
R. G. S. Pong ◽  
Z. H. Kafafi
Keyword(s):  
Optical Properties ◽  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Nd:Yag Laser ◽  
Nonlinear Optical ◽  
Four Wave Mixing ◽  
Wave Mixing ◽  
Time Resolved ◽  
Fifth Order

ABSTRACTTime-resolved degenerate four-wave-mixing studies have been conducted on solutions of transition-metal complexes of benzenedithiol using a 35 ps Nd:YAG laser operating at 1.064 μm. The nonlinear optical properties of the first-row Co(d7), Ni(d8), and Cu(d9) and the d8 group Ni and P t transition metal complexes are discussed.

Three transition metal complexes with uncoordinated carboxyl groups: synthesis, structures, and luminescence properties

2014 ◽  
Vol 39 (5) ◽  
pp. 559-566 ◽  
Author(s):  
Sen Su ◽  
Mei-ling Cheng ◽  
Yanqiu Ren ◽  
Changwei Zhai ◽  
Feng Tao ◽  
...  
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Luminescence Properties ◽  
Carboxyl Groups

scholarly journals Preparation and Characterisation of the Cyano-Bridged Transition Metal Complexes Using N,N-Diethyl Thiourea as a Ligand

2021 ◽  
Vol 75 ◽  
Author(s):  
Dursun Karaağaç
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Nickel Atom ◽  
Zinc Atom ◽  
Planar Geometry ◽  
Thermal Stabilities ◽  
Air Atmosphere ◽  
Square Planar ◽  
Cyano Groups

ABSTRACT New cyano bridged transition metal complexes, [Cu(detu)4Ni(CN)4]-2H2O (1) and [Zn(H2O)(detu)Ni(CN)4]-2H2O (2) (detu = N, N' diethyl thiourea) have been synthesised in powder form. Their structures were illuminated by using spectroscopic, thermal and elemental analysis techniques. The nickel atom exhibits square planar geometry in these complexes by coordinating with the cyano group's nitrogen atoms. The copper atom of 1 is six coordinated with two bridging cyano groups and four detu ligands. In contrast, the zinc atom of 2 is six coordinated with four bridging cyano groups, one detu ligand and one aqua ligand. In addition, the structure of 2 is formed from polymeric layers of |Zn-Ni(CN)41 „ with the detu and aqua ligands bonded to the zinc atom. Thermal stabilities and decomposition products of 1 and 2 were examined in the static air atmosphere between 30 and 900 °C. Keywords: btetracyanonickelate(II) complex, N,N'-diethyl thiourea, cyano-bridged complex, vibration spectra, thermal analysis.

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