Syntheses, crystal structures, MMCT and magnetic properties of four one-dimensional cyanide-bridged complexes comprised of MII–CN–FeIII (M = Fe, Ru, Os)

2014 ◽  
Vol 43 (46) ◽  
pp. 17453-17462 ◽  
Author(s):  
Yong Wang ◽  
Xiao Ma ◽  
Shengmin Hu ◽  
Yuehong Wen ◽  
Zhenzhen Xue ◽  
...  

Four 1D cyanide-bridged complexes [cis-MII(L)2(CN)2FeIII(salen)](PF6) (3–6) have been synthesized, of which 3 and 4 are Class II mixed-valence complexes.

Polyhedron ◽  
2014 ◽  
Vol 79 ◽  
pp. 129-137 ◽  
Author(s):  
Danica Čechová ◽  
Alena Martišková ◽  
Zdeňka Padělková ◽  
Lukáš Gal’a ◽  
L’ubor Dlháň ◽  
...  

Polyhedron ◽  
2008 ◽  
Vol 27 (2) ◽  
pp. 574-582 ◽  
Author(s):  
Cristian D. Ene ◽  
Floriana Tuna ◽  
Oscar Fabelo ◽  
Catalina Ruiz-Pérez ◽  
Augustin M. Madalan ◽  
...  

RSC Advances ◽  
2020 ◽  
Vol 10 (19) ◽  
pp. 11365-11370
Author(s):  
Ye-Min Han ◽  
Ning-Fang Li ◽  
Yan-Zhao Yu ◽  
Jia-Peng Cao ◽  
Mu-Xiu Yang ◽  
...  

Two heterometallic cluster {Ln8Cr4} were constructed from two classical “drum-like” {Ln4Cr2} building units associated by organic ligands HIN, displaying 1D wave chain structure. The MCE values for {Gd8Cr4} at 3 K and 7 T is 23.40 J kg−1 K−1.


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