Rational design of cyanide-bridged heterometallic M(I)–Mn(II) (M = Ag, Au) one-dimensional chain complexes: synthesis, crystal structures and magnetic properties

CrystEngComm ◽  
2009 ◽  
Vol 11 (11) ◽  
pp. 2447 ◽  
Author(s):  
Daopeng Zhang ◽  
Hailong Wang ◽  
Laijin Tian ◽  
Jianzhuang Jiang ◽  
Zhong-Hai Ni
2021 ◽  
Vol 7 (7) ◽  
pp. 105
Author(s):  
Min Zeng ◽  
Xi Chen ◽  
Hui-Zhong Kou

Two carboxylate-bridged one-dimensional chain complexes, {[MnII(MeOH)2][FeIII(L)2]2}n (1) and {[MnII(DMF)2][MnIII(L)2]2·DMF}n (2) [H2L = ((2-carboxyphenyl)azo)-benzaldoxime], containing a low-spin [FeIII(L)2]− or [MnIII(L)2]− unit were synthesized. Magnetic measurements show that the adjacent high-spin MnII and low-spin MIII ions display weak antiferromagnetic coupling via the syn–anti carboxyl bridges, with J = −0.066(2) cm−1 for complex 1 and J = −0.274(2) cm−1 for complex 2.


2009 ◽  
Vol 48 (12) ◽  
pp. 5488-5496 ◽  
Author(s):  
Daopeng Zhang ◽  
Hailong Wang ◽  
Yuting Chen ◽  
Zhong-Hai Ni ◽  
Laijin Tian ◽  
...  

2014 ◽  
Vol 43 (3) ◽  
pp. 945-949 ◽  
Author(s):  
Daopeng Zhang ◽  
Yongzhong Bian ◽  
Jie Qin ◽  
Ping Wang ◽  
Xia Chen

Two cyanide-bridged enantiopure one-dimensional single chain complexes have been synthesized and structurally characterized. Systematically magnetic investigations show the antiferromagnetic coupling between the Mn(iii)–Fe(iii) centers and the metamagnetic behavior at about 5.0 K.


2011 ◽  
Vol 989 (1-3) ◽  
pp. 60-69 ◽  
Author(s):  
Moha Outirite ◽  
Bouchaib Mernari ◽  
Fouad Bentiss ◽  
Frederic Capet ◽  
Michel Lagrenée

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