Mechanistic insights into hydride transfer for catalytic hydrogenation of CO2 with cobalt complexes

2014 ◽  
Vol 43 (31) ◽  
pp. 11803-11806 ◽  
Author(s):  
N. Kumar ◽  
D. M. Camaioni ◽  
M. Dupuis ◽  
S. Raugei ◽  
A. M. Appel
Keyword(s):  
Catalytic Hydrogenation ◽  
Hydride Transfer ◽  
Cobalt Complexes ◽  
Reductive Elimination ◽  
Hydrogenation Of Co2 ◽  
Hydrogenation Of Co

The catalytic hydrogenation of CO2 to formate by Co(dmpe)2H can proceed via direct hydride transfer or via CO2 coordination to Co followed by reductive elimination of formate.

Catalytic hydrogenation of CO2 at a structurally rigidified cobalt center

2020 ◽  
Vol 7 (9) ◽  
pp. 1845-1850
Author(s):  
Jonghoon Choi ◽  
Yunho Lee
Keyword(s):  
Catalytic Hydrogenation ◽  
Catalytic Performance ◽  
Hydrogenation Of Co2 ◽  
Hydrogenation Of Co ◽  
Cobalt Center

Catalytic hydrogenation of CO2 occurs at a cobalt center supported by a rigidified PNP ligand revealing higher catalytic performance.

Recent developments in the catalytic hydrogenation of CO2 to formic acid/formate using heterogeneous catalysts

2016 ◽  
Vol 3 (7) ◽  
pp. 882-895 ◽  
Author(s):  
Gunniya Hariyanandam Gunasekar ◽  
Kwangho Park ◽  
Kwang-Deog Jung ◽  
Sungho Yoon
Keyword(s):  
Formic Acid ◽  
Catalytic Hydrogenation ◽  
Heterogeneous Catalysts ◽  
Hydrogenation Of Co2 ◽  
Recent Developments ◽  
Recent Trends ◽  
Heterogeneous Hydrogenation ◽  
Hydrogenation Of Co

This review highlights the recent trends in the heterogeneous hydrogenation of CO2 to formic acid/formate.

scholarly journals Hydrogenation of CO2 to formic acid with iridiumIII(bisMETAMORPhos)(hydride): the role of a dormant fac-IrIII(trihydride) and an active trans-IrIII(dihydride) species

2016 ◽  
Vol 6 (2) ◽  
pp. 404-408 ◽  
Author(s):  
S. Oldenhof ◽  
J. I. van der Vlugt ◽  
J. N. H. Reek
Keyword(s):  
Formic Acid ◽  
Catalytic Hydrogenation ◽  
Hydrogenation Of Co2 ◽  
Hydrogenation Of Co

Catalytic hydrogenation of CO2 to formate with an IrIII(METAMORPhos) complex in the presence of DBU requires a trans-dihydride for catalytic turnover, with an off-cycle trihydride as the dormant species.

New Ru(ii) N′NN′-type pincer complexes: synthesis, characterization and the catalytic hydrogenation of CO2 or bicarbonates to formate salts

2017 ◽  
Vol 41 (8) ◽  
pp. 3055-3060 ◽  
Author(s):  
Zengjin Dai ◽  
Qi Luo ◽  
Hengjiang Cong ◽  
Jing Zhang ◽  
Tianyou Peng
Keyword(s):  
Catalytic Hydrogenation ◽  
Catalytic Efficiency ◽  
Homogeneous System ◽  
Pincer Complexes ◽  
Hydrogenation Of Co2 ◽  
Hydrogenation Of Co

A new homogeneous system based on new Ru(ii)-N′NN′ pincer complexes has been successfully applied to the hydrogenation of CO2 to the formate, and complex 4 exhibits the best catalytic efficiency.

Continuous-flow formic acid production from the hydrogenation of CO2 without any base

2021 ◽  
Vol 23 (5) ◽  
pp. 1978-1982
Author(s):  
Zhaofu Zhang ◽  
Shuaishuai Liu ◽  
Minqiang Hou ◽  
Guangying Yang ◽  
Buxing Han
Keyword(s):  
Formic Acid ◽  
Continuous Flow ◽  
Acid Production ◽  
Hydrogenation Of Co2 ◽  
Hydrogenation Of Co

Continuous-flow formic acid production from the hydrogenation of CO2 without any base, and the concentration of formic acid by electrodialysis was tested both offline and online.

scholarly journals A brief review on the reaction mechanisms of CO2 hydrogenation into methanol

2020 ◽  
Vol 3 (2) ◽  
pp. 33-40
Author(s):  
Jawed Qaderi
Keyword(s):  
Catalytic Hydrogenation ◽  
Density Functional ◽  
Heterogeneous Catalysts ◽  
Catalytic Reduction ◽  
Kinetic Monte Carlo ◽  
Low Cost ◽  
Hydrogenation Of Co2 ◽  
Fuel Prices ◽  
Metal Metal ◽  
Reduction Of Co2

The catalytic reduction of CO2 to methanol is an appealing option to reduce greenhouse gas concentration as well as renewable energy production. In addition, the exhaustion of fossil fuel, increase in earth temperature and sharp increases in fuel prices are the main driving factor for exploring the synthesis of methanol by hydrogenating CO2. Many studies on the catalytic hydrogenation of CO2 to methanol were published in the literature over the last few decades. Many of the studies have presented different catalysts having high stability, higher performance, low cost, and are immediately required to promote conversion. Understanding the mechanisms involved in the conversion of CO2 is essential as the first step towards creating these catalysts. This review briefly summarizes recent theoretical developments in mechanistic studies focused on using density functional theory, kinetic Monte Carlo simulations, and microkinetics modeling. Based on these simulation techniques on different transition metals, metal/metal oxide, and other heterogeneous catalysts surfaces, mainly, three important mechanisms that have been recommended are the formate (HCOO), reverse water–gas shift (RWGS), and trans-COOH mechanisms. Recent experimental and theoretical efforts appear to demonstrate that the formate route in which the main intermediate species is H2CO* in the reaction route, is more favorable in catalytic hydrogenation of CO2 to chemical fuels in various temperature and pressure conditions.

scholarly journals Liquid phase hydrogenation of CO2 to formate using palladium and ruthenium nanoparticles supported on molybdenum carbide

2019 ◽  
Vol 43 (35) ◽  
pp. 13985-13997 ◽  
Author(s):  
Claire E. Mitchell ◽  
Umberto Terranova ◽  
Ihfaf Alshibane ◽  
David J. Morgan ◽  
Thomas E. Davies ◽  
...  
Keyword(s):  
Liquid Phase ◽  
Palladium Nanoparticles ◽  
Molybdenum Carbide ◽  
Active Catalyst ◽  
Ruthenium Nanoparticles ◽  
Reaction Conditions ◽  
Hydrogenation Of Co2 ◽  
Liquid Phase Hydrogenation ◽  
Hydrogenation Of Co

We report the development of palladium nanoparticles supported on Mo2C as an active catalyst for the liquid-phase hydrogenation of CO2 to formate under mild reaction conditions (100 °C and 2.0 MPa of a 1 : 1 CO2 : H2 mixture).

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