Design and development of POCN-pincer palladium catalysts for C–H bond arylation of azoles with aryl iodides

2014 ◽  
Vol 43 (42) ◽  
pp. 16084-16096 ◽  
Author(s):  
Shrikant M. Khake ◽  
Vineeta Soni ◽  
Rajesh G. Gonnade ◽  
Benudhar Punji
Keyword(s):  
Palladium Catalysts ◽  
Palladium Complexes ◽  
Design And Development ◽  
Direct Arylation ◽  
Bond Functionalization ◽  
Highly Active ◽  
Aryl Iodides

Well-defined highly active pincer-ligated palladium complexes have been developed for the direct arylation of heteroarenes through C–H bond functionalization using aryl iodides as electrophiles with impressive reactivity.

From recovered metal waste to high-performance palladium catalysts

2017 ◽  
Vol 19 (24) ◽  
pp. 5846-5853 ◽  
Author(s):  
Khairil A. Jantan ◽  
Chuek Yee Kwok ◽  
Kuang Wen Chan ◽  
Luciano Marchiò ◽  
Andrew J. P. White ◽  
...  
Keyword(s):  
Palladium Catalysts ◽  
High Performance ◽  
Palladium Complexes ◽  
Catalytic Converters ◽  
Highly Active ◽  
Metal Waste

Molecular palladium complexes, recovered selectively from used catalytic converters, can be directly valorised as highly-active catalysts for C–H oxidative functionalisation.

Direct arylation of imidazo[2,1-b]thiazoles and thiazoles with aryl iodides via CuCl2/PPh3-catalyzed C-H bond functionalization

2015 ◽  
Vol 29 (3) ◽  
pp. 165-169 ◽  
Author(s):  
Yuchang Ma ◽  
Min Na ◽  
Yanfang Gu ◽  
Guoli Huang ◽  
Xia Li ◽  
...  
Keyword(s):  
Direct Arylation ◽  
Bond Functionalization ◽  
Aryl Iodides

ChemInform Abstract: Direct Arylation of Imidazo[2,1-b]thiazoles and Thiazoles with Aryl Iodides via CuCl2/PPh3-Catalyzed C-H Bond Functionalization.

ChemInform ◽  
2015 ◽  
Vol 46 (28) ◽  
pp. no-no
Author(s):  
Yuchang Ma ◽  
Min Na ◽  
Yanfang Gu ◽  
Guoli Huang ◽  
Xia Li ◽  
...  
Keyword(s):  
Direct Arylation ◽  
Bond Functionalization ◽  
Aryl Iodides

ChemInform Abstract: Direct Arylation of Imidazo[1,2-a]pyridine at C-3 with Aryl Iodides, Bromides, and Triflates via Copper(I)-Catalyzed C-H Bond Functionalization.

ChemInform ◽  
2012 ◽  
Vol 43 (31) ◽  
pp. no-no
Author(s):  
Hua Cao ◽  
Haiying Zhan ◽  
Yuanguang Lin ◽  
Xiulian Lin ◽  
Zuodong Du ◽  
...  
Keyword(s):  
Direct Arylation ◽  
Bond Functionalization ◽  
Aryl Iodides

Direct Arylation of Imidazo[1,2-a]pyridine at C-3 with Aryl Iodides, Bromides, and Triflates via Copper(I)-Catalyzed C–H Bond Functionalization

2012 ◽  
Vol 14 (7) ◽  
pp. 1688-1691 ◽  
Author(s):  
Hua Cao ◽  
Haiying Zhan ◽  
Yuanguang Lin ◽  
Xiulian Lin ◽  
Zuodong Du ◽  
...  
Keyword(s):  
Direct Arylation ◽  
Bond Functionalization ◽  
Aryl Iodides

scholarly journals N-Heterocyclic carbene–palladium catalysts for the direct arylation of pyrrole derivatives with aryl chlorides

2013 ◽  
Vol 9 ◽  
pp. 303-312 ◽  
Author(s):  
Ismail Özdemir ◽  
Nevin Gürbüz ◽  
Nazan Kaloğlu ◽  
Öznur Doğan ◽  
Murat Kaloğlu ◽  
...  
Keyword(s):  
Palladium Catalysts ◽  
Palladium Complexes ◽  
Direct Arylation ◽  
Pyrrole Derivatives ◽  
Aryl Chlorides ◽  
Palladium Catalyzed

New Pd–NHC complexes have been synthesized and employed for palladium-catalyzed direct arylation of pyrrole derivatives by using electron-deficient aryl chlorides as coupling partners. The desired coupling products were obtained in moderate to good yields by using 1 mol % of these air-stable palladium complexes. This is an advantage compared to the procedures employing air-sensitive phosphines, which have been previously shown to promote the coupling of aryl chlorides with heteroarenes.

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