Solar thermal catalytic reforming of natural gas: a review on chemistry, catalysis and system design

2015 ◽  
Vol 5 (4) ◽  
pp. 1991-2016 ◽  
Author(s):  
David S. A. Simakov ◽  
Mark M. Wright ◽  
Shakeel Ahmed ◽  
Esmail M. A. Mokheimer ◽  
Yuriy Román-Leshkov
Keyword(s):  
Natural Gas ◽  
System Design ◽  
Fossil Fuels ◽  
Solar Thermal ◽  
Catalytic Reforming

Solar thermal catalytic reforming of natural gas is a promising route to increase the efficiency of fossil fuels utilization.

Energy, Environment, and Economical Advantages of Solar Thermal Cracking of Natural Gas

2012 ◽  
Author(s):  
Nesrin Ozalp
Keyword(s):  
Natural Gas ◽  
Carbon Black ◽  
Fossil Fuels ◽  
Petroleum Industry ◽  
World Market ◽  
Point Of View ◽  
Solar Thermal ◽  
Gas Combustion ◽  
Economic Point ◽  
Energy Environment

Among all fossil fuels, natural gas is probably the most attractive one because of its higher heating value, and approximately 97% methane content, which creates less hazardous emissions during power generation. Considering these important facts and the demand for natural gas in the world market, it would be unlikely to think of converting natural gas. However, if we want to utilize our planet’s limited natural gas resources better, then we need to explore alternative ways. A way to achieve that goal is direct cracking of natural gas via solar thermal processing. This paper describes advantages of solar cracking of natural gas from energy, environment and economic point of view. Results show that products of natural gas decomposition contain 8% more energy per mole compared to natural gas itself, while the decomposition process does not emit any hazardous emissions to the environment. As for the economics, once the decomposition products of natural gas, namely hydrogen and carbon black, are sold separately, it is possible to make up to three times more revenue than the selling of natural gas. The products of natural gas decomposition have a very wide use in chemical and petroleum industries. For example, hydrogen is a crucial commodity to refine crude oil, while carbon black is the fundamental component in car tire, battery, conveyer belt, and printer ink manufacturing industries. Currently, petroleum industry produces hydrogen via steam reforming of methane and the chemical industry produces carbon black from coal or natural gas combustion in furnace, which are both highly toxic and global warming emissive processes. With solar cracking of natural gas, these two important commodities can be produced without any emissions to the environment.

Evaluasi Prediksi Higher Heating Value (HHV) Biomassa Berdasarkan Analisis Proksimat

2020 ◽  
Vol 4 (1) ◽  
pp. 1-7
Author(s):  
Made Dirgantara ◽  
Karelius Karelius ◽  
Marselin Devi Ariyanti, Sry Ayu K. Tamba
Keyword(s):  
Renewable Energy ◽  
Natural Gas ◽  
Key Words ◽  
Critical Analysis ◽  
Fossil Fuels ◽  
Calorific Value ◽  
Proximate Analysis ◽  
Heating Value ◽  
Bomb Calorimeter ◽  
Hhv Prediction

Abstrak – Biomassa merupakan salah satu energi terbarukan yang sangat mudah ditemui, ramah lingkungan dan cukup ekonomis. Keberadaan biomassa dapat dimaanfaatkan sebagai pengganti bahan bakar fosil, baik itu minyak bumi, gas alam maupun batu bara. Analisi diperlukan sebagai dasar biomassa sebagai energi seperti proksimat dan kalor. Analisis terpenting untuk menilai biomassa sebagai bahan bakar adalah nilai kalori atau higher heating value (HHV). HHV secara eksperimen diukur menggunakan bomb calorimeter, namun pengukuran ini kurang efektif, karena memerlukan waktu serta biaya yang tinggi. Penelitian mengenai prediksi HHV berdasarkan analisis proksimat telah dilakukan sehingga dapat mempermudah dan menghemat biaya yang diperlukan peneliti. Dalam makalah ini dibahas evaluasi persamaan untuk memprediksi HHV berdasarkan analisis proksimat pada biomassa berdasarkan data dari penelitian sebelumnya. Prediksi nilai HHV menggunakan lima persamaan yang dievaluasi dengan 25 data proksimat biomassa dari penelitian sebelumnya, kemudian dibandingkan berdasarkan nilai error untuk mendapatkan prediksi terbaik. Hasil analisis menunjukan, persamaan A terbaik di 7 biomassa, B di 6 biomassa, C di 6 biomassa, D di 5 biomassa dan E di 1 biomassa.Kata kunci: bahan bakar, biomassa, higher heating value, nilai error, proksimat  Abstract – Biomass is a renewable energy that is very easy to find, environmentally friendly, and quite economical. The existence of biomass can be used as a substitute for fossil fuels, both oil, natural gas, and coal. Analyzes are needed as a basis for biomass as energy such as proximate and heat. The most critical analysis to assess biomass as fuel is the calorific value or higher heating value (HHV). HHV is experimentally measured using a bomb calorimeter, but this measurement is less effective because it requires time and high costs. Research on the prediction of HHV based on proximate analysis has been carried out so that it can simplify and save costs needed by researchers. In this paper, the evaluation of equations is discussed to predict HHV based on proximate analysis on biomass-based on data from previous studies. HHV prediction values using five equations were evaluated with 25 proximate biomass data from previous studies, then compared based on error value to get the best predictions. The analysis shows that Equation A predicts best in 7 biomass, B in 6 biomass, C in 6 biomass, D in 5 biomass, and E in 1 biomass. Key words: fuel, biomass, higher heating value, error value, proximate 

scholarly journals Emissions Effects of Energy Storage for Frequency Regulation: Comparing Battery and Flywheel Storage to Natural Gas

Energies ◽  
2021 ◽  
Vol 14 (3) ◽  
pp. 549
Author(s):  
Eric Pareis ◽  
Eric Hittinger
Keyword(s):  
Energy Storage ◽  
Natural Gas ◽  
Fossil Fuels ◽  
Storage Systems ◽  
Storage System ◽  
The United States ◽  
Frequency Regulation ◽  
So2 Emissions ◽  
Gas Generation ◽  
Electrical Generation

With an increase in renewable energy generation in the United States, there is a growing need for more frequency regulation to ensure the stability of the electric grid. Fast ramping natural gas plants are often used for frequency regulation, but this creates emissions associated with the burning of fossil fuels. Energy storage systems (ESSs), such as batteries and flywheels, provide an alternative frequency regulation service. However, the efficiency losses of charging and discharging a storage system cause additional electrical generation requirements and associated emissions. There is not a good understanding of these indirect emissions from charging and discharging ESSs in the literature, with most sources stating that ESSs for frequency regulation have lower emissions, without quantification of these emissions. We created a model to estimate three types of emissions (CO2, NOX, and SO2) from ESSs providing frequency regulation, and compare them to emissions from a natural gas plant providing the same service. When the natural gas plant is credited for the generated electricity, storage systems have 33% to 68% lower CO2 emissions than the gas turbine, depending on the US eGRID subregion, but higher NOX and SO2 emissions. However, different plausible assumptions about the framing of the analysis can make ESSs a worse choice so the true difference depends on the nature of the substitution between storage and natural gas generation.

Accelerating oil and gas investment and reserves by design

2018 ◽  
Vol 58 (2) ◽  
pp. 557
Author(s):  
Barry A. Goldstein
Keyword(s):  
Natural Gas ◽  
Fossil Fuels ◽  
Oil And Gas ◽  
South Australia ◽  
Land Access ◽  
Oil And Gas Exploration ◽  
Oil And Gas Producers ◽  
Crude Oil Prices ◽  
Exploration And Production ◽  
Oil And Gas Operations

Facts are stubborn things; and whatever may be our wishes, our inclinations, or the dictates of our passion, they cannot alter the state of facts and evidence (Adams 1770). Some people unfamiliar with upstream petroleum operations, some enterprises keen to sustain uncontested land use, and some people against the use of fossil fuels have and will voice opposition to land access for oil and gas exploration and production. Social and economic concerns have also arisen with Australian domestic gas prices tending towards parity with netbacks from liquefied natural gas (LNG) exports. No doubt, natural gas, LNG and crude-oil prices will vary with local-to-international supply-side and demand-side competition. Hence, well run Australian oil and gas producers deploy stress-tested exploration, delineation and development budgets. With these challenges in mind, successive governments in South Australia have implemented leading-practice legislation, regulation, policies and programs to simultaneously gain and sustain trust with the public and investors with regard to land access for trustworthy oil and gas operations. South Australia’s most recent initiatives to foster reserve growth through welcomed investment in responsible oil and gas operations include the following: a Roundtable for Oil and Gas; evergreen answers to frequently asked questions, grouped retention licences that accelerate investment in the best of play trends; the Plan for ACcelerating Exploration (PACE) Gas Program; and the Oil and Gas Royalty Return Program. Intended and actual outcomes from these initiatives are addressed in this extended abstract.

scholarly journals Solar Integrated Anaerobic Digester: Energy Savings and Economics

Energies ◽  
2020 ◽  
Vol 13 (17) ◽  
pp. 4292
Author(s):  
Lidia Lombardi ◽  
Barbara Mendecka ◽  
Simone Fabrizi
Keyword(s):  
Anaerobic Digestion ◽  
Natural Gas ◽  
Economic Analysis ◽  
Thermal Energy ◽  
Economic Feasibility ◽  
Solar Thermal ◽  
Base Case ◽  
Economic Sustainability ◽  
Solar Thermal Energy ◽  
Solar Integration

Industrial anaerobic digestion requires low temperature thermal energy to heat the feedstock and maintain temperature conditions inside the reactor. In some cases, the thermal requirements are satisfied by burning part of the produced biogas in devoted boilers. However, part of the biogas can be saved by integrating thermal solar energy into the anaerobic digestion plant. We study the possibility of integrating solar thermal energy in biowaste mesophilic/thermophilic anaerobic digestion, with the aim of reducing the amount of biogas burnt for internal heating and increasing the amount of biogas, further upgraded to biomethane and injected into the natural gas grid. With respect to previously available studies that evaluated the possibility of integrating solar thermal energy in anaerobic digestion, we introduce the topic of economic sustainability by performing a preliminary and simplified economic analysis of the solar system, based only on the additional costs/revenues. The case of Italian economic incentives for biomethane injection into the natural gas grid—that are particularly favourable—is considered as reference case. The amount of saved biogas/biomethane, on an annual basis, is about 4–55% of the heat required by the gas boiler in the base case, without solar integration, depending on the different considered variables (mesophilic/thermophilic, solar field area, storage time, latitude, type of collector). Results of the economic analysis show that the economic sustainability can be reached only for some of the analysed conditions, using the less expensive collector, even if its efficiency allows lower biomethane savings. Future reduction of solar collector costs might improve the economic feasibility. However, when the payback time is calculated, excluding the Italian incentives and considering selling the biomethane at the natural gas price, its value is always higher than 10 years. Therefore, incentives mechanism is of great importance to support the economic sustainability of solar integration in biowaste anaerobic digestion producing biomethane.

scholarly journals Advances in Underground Energy Storage for Renewable Energy Sources

2021 ◽  
Vol 11 (11) ◽  
pp. 5142
Author(s):  
Javier Menéndez ◽  
Jorge Loredo
Keyword(s):  
European Union ◽  
Renewable Energy ◽  
Energy Storage ◽  
Natural Gas ◽  
Greenhouse Gas ◽  
Fossil Fuels ◽  
Renewable Energy Sources ◽  
Energy Sources ◽  
The European Union ◽  
Coal Fuel

The use of fossil fuels (coal, fuel, and natural gas) to generate electricity has been reduced in the European Union during the last few years, involving a significant decrease in greenhouse gas emissions [...]

PRODUCTION OF DOMESTIC HOT WATER IN A SUSTAINABLE WAY BY USING A COMBINED SOLAR - TLUD SYSTEM

2020 ◽  
Author(s):  
Radu Radoi ◽  
Ioan Pavel ◽  
Corneliu Cristescu ◽  
Liliana Dumitrescu
Keyword(s):  
Climate Change ◽  
Fossil Fuels ◽  
Heat Waves ◽  
Hot Water ◽  
Experimental Results ◽  
Solar Thermal ◽  
Extreme Weather Events ◽  
Automation System ◽  
Low Carbon ◽  
Domestic Hot Water

Fossil fuels are an exhaustible resource on Earth, and their use pollutes the environment massively. The population of the planet has grown a lot, and for the production of domestic hot water, to ensure a decent standard of living, it is necessary to consume increasing quantities of fossil fuels. The very high level of greenhouse gases released into the atmosphere leads to an increase in average of annual temperature and climate change. Climate change is manifested by the melting of the ice caps, which has the consequence of increasing the level of the seas and oceans. Climate change also leads to extreme weather events such as floods, heat waves or the appearance of arid areas. Risks to human health have increased through deaths caused by heat or by changing the way some diseases are spread. Risks also exist for flora and wildlife due to rapid climate change.Many species of animals migrate, and other species of animals and plants are likely to disappear. Climate change also leads to costs for society and the economy due to damage to property and infrastructure, which have been more than 90 billion euros in the last 30 years, just because of the floods. In order to reduce the effects of environmental pollution, ecological energy production solutions need to be expanded. The article presents the creation of an experimental stand of a Solar - TLUD stove combined system for the production of domestic hot water in a sustainable way. TLUD is the acronym for "Top-Lit UpDraft". The advantage of the combined heat system is that it can provide thermal energy both during the day and at night. If the atmospheric conditions are unfavorable (clouds, fog) and do not allow the water to be heated only with the solar panel, TLUD gas stove can be used to supplement the energy. The TLUD stove has low Carbon Monoxide (CO) and Particulate Matter (PM) emissions. After gasification, about 10% of the carbon contained in the biomass is thermally stabilized and can be used as a "biochar" in agriculture or it can be burnt completely, resulting in very little ash. The stand is composed of a solar thermal panel, a TLUD stove, a boiler for hot water storage and an automation system with circulation pumps and temperature sensors. To record the experimental results, a data acquisition board was used, with which data were recorded from a series of temperature and flow transducers located in the installation. Experimental results include diagrams for temperature variation, available energy and heat accumulated in the boiler. Keywords: combined thermal system, TLUD stove, domestic hot water, solar thermal panel, data aquisition system

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