scholarly journals Solvent-free aerobic oxidation of alcohols using supported gold palladium nanoalloys prepared by a modified impregnation method

2014 ◽  
Vol 4 (9) ◽  
pp. 3120-3128 ◽  
Author(s):  
Moataz Morad ◽  
Meenakshisundaram Sankar ◽  
Enhong Cao ◽  
Ewa Nowicka ◽  
Thomas E. Davies ◽  
...  

The synthesis of stable, supported, bimetallic nanoalloys with controlled size, morphology and composition for selective alcohol oxidation.

RSC Advances ◽  
2016 ◽  
Vol 6 (51) ◽  
pp. 45330-45342 ◽  
Author(s):  
Chiranjit Santra ◽  
Aline Auroux ◽  
Biswajit Chowdhury

Gold nanoparticles supported on Bi–CeO2 with four different bismuth loadings (2 to 8 mol%) were prepared to determine the role of oxide vacancies in doped ceria in the benzyl alcohol oxidation reaction.


ChemCatChem ◽  
2015 ◽  
Vol 7 (24) ◽  
pp. 4131-4136 ◽  
Author(s):  
Yong-Ming Lu ◽  
Hai-Zhou Zhu ◽  
Jian-Wei Liu ◽  
Shu-Hong Yu

2021 ◽  
Vol 43 (2) ◽  
pp. 193-193
Author(s):  
Taiping Gao Taiping Gao ◽  
Xiaolin Ma Xiaolin Ma ◽  
Xin Li Xin Li ◽  
Qiang Xu and Yubao Wang Qiang Xu and Yubao Wang

The first mesoporous silica nanoparticles (MSNs) supported atomically precise palladium nanoclusters catalyzed alcohol oxidation reactions in water have been achieved. The catalysts was synthesized with simple impregnation method and well characterized by TEM, FT-IR, XPS anddiffuse reflectance optical spectrum and the results proved that the Pd nanoclustersimmobilized into the pores of MSNs.The as-prepared catalyst show excellent activity for the alcohol oxidation reactions with high yield under extremely mild aqueous conditions utilizes 1 atmosphere of molecular oxygen as sole oxidant. The features of clean system, gram-scale oxidation and easy recovery catalyst make this method cost effectively and environmentally benign.


RSC Advances ◽  
2016 ◽  
Vol 6 (74) ◽  
pp. 70424-70432 ◽  
Author(s):  
Ran Ji ◽  
Shangru Zhai ◽  
Wei Zheng ◽  
Zuoyi Xiao ◽  
Qingda An ◽  
...  

Towards the aerobic oxidation of alcohols, palladium nanoparticle immobilized mesoporous catalysts have been extensively investigated; however, the preparation of efficient catalytic materials without using complexing moieties remains a challenge.


2016 ◽  
Vol 6 (12) ◽  
pp. 4090-4104 ◽  
Author(s):  
Shuai Wang ◽  
Shuangtao Yin ◽  
Gaowen Chen ◽  
Lun Li ◽  
Hui Zhang

Nearly atomic precise Au25/NixAl-LDH catalysts obtained via adsorption of Au25Capt18 onto predispersed NixAl-LDH following proper calcination show extraordinary alcohol oxidation property due to ultrafine Au cluster, ordered LDH layer and strong Au25–LDH synergy.


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