Metal–organic frameworks: versatile heterogeneous catalysts for efficient catalytic organic transformations

2015 ◽  
Vol 44 (19) ◽  
pp. 6804-6849 ◽  
Author(s):  
Adeel H. Chughtai ◽  
Nazir Ahmad ◽  
Hussein A. Younus ◽  
A. Laypkov ◽  
Francis Verpoort
Keyword(s):  
Heterogeneous Catalysts ◽  
Metal Organic Frameworks ◽  
Organic Reactions ◽  
Organic Transformations ◽  
Catalytic Materials ◽  
Metal Organic

Novel catalytic materials are highly demanded to perform a variety of catalytic organic reactions.

Metal–organic frameworks as catalytic selectivity regulators for organic transformations

2021 ◽  
Author(s):  
Jun Guo ◽  
Yutian Qin ◽  
Yanfei Zhu ◽  
Xiaofei Zhang ◽  
Chang Long ◽  
...  
Keyword(s):  
Heterogeneous Catalysts ◽  
Metal Organic Frameworks ◽  
Research Topic ◽  
Organic Transformations ◽  
Catalytic Selectivity ◽  
Challenging Research ◽  
Metal Organic

Selective organic transformations using metal–organic frameworks (MOFs) and MOF-based heterogeneous catalysts have been an intriguing but challenging research topic in both the chemistry and materials communities.

scholarly journals Metal–Organic Frameworks (MOFs) and Covalent Organic Frameworks (COFs) Applied to Photocatalytic Organic Transformations

Catalysts ◽  
2020 ◽  
Vol 10 (7) ◽  
pp. 720
Author(s):  
Alberto López-Magano ◽  
Alicia Jiménez-Almarza ◽  
Jose Alemán ◽  
Rubén Mas-Ballesté
Keyword(s):  
Organic Molecules ◽  
Metal Organic Frameworks ◽  
Organic Reactions ◽  
Covalent Organic Frameworks ◽  
Organic Transformations ◽  
Molecular Systems ◽  
Metal Organic ◽  
General Aspects ◽  
Good Number ◽  
Comprehensive Discussion

Among the different alternatives for catalysis using metal–organic frameworks (MOFs) or covalent organic frameworks (COFs), photocatalysis has remarkably evolved during the last decade. Photocatalytic reticular materials allowed recyclability and easy separation of catalyst from the product, also reaching the activity and selectivity commonly observed for molecular systems. Recently, photocatalytic MOFs and COFs have been applied to synthetic applications in order to obtain organic molecules of different complexity. However, although a good number of works have been devoted to this issue, an updated comprehensive revision on this field is still needed. The aim of this review was to fill this gap covering the following three general aspects: (1) common strategies on the design of reticular photocatalytic materials, (2) a comprehensive discussion of the photocatalytic organic reactions achieved by the use of COFs and MOFs, and (3) some critical considerations highlighting directions that should be considered in order to make advances in the study of photocatalytic COFs and MOFs.

scholarly journals Magnetic Metal Organic Framework Composites: Structurally Advanced Catalytic Materials for Organic Transformations

2021 ◽  
Author(s):  
Sneha Yadav ◽  
Ranjana Dixit ◽  
Shivani Sharma ◽  
Sriparna Dutta ◽  
Kanika Solanki ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
Organic Transformations ◽  
Modern Material ◽  
Catalytic Materials ◽  
Material Chemistry ◽  
Frontiers Of Science ◽  
Magnetic Metal ◽  
Metal Organic ◽  
Organic Framework

Since past two decades, metal organic frameworks (MOFs) are a rising star in modern material chemistry and engineering that have contributed immensely to advance the frontiers of science. Amalgamation of...

Delineating similarities and dissimilarities in the use of metal organic frameworks and zeolites as heterogeneous catalysts for organic reactions

2011 ◽  
Vol 40 (24) ◽  
pp. 6344 ◽  
Author(s):  
Amarajothi Dhakshinamoorthy ◽  
Mercedes Alvaro ◽  
Avelino Corma ◽  
Hermenegildo Garcia
Keyword(s):  
Heterogeneous Catalysts ◽  
Metal Organic Frameworks ◽  
Organic Reactions ◽  
Metal Organic

scholarly journals A Review on Metal-Organic Frameworks as Congenial Heterogeneous Catalysts for Potential Organic Transformations

2021 ◽  
Vol 9 ◽  
Author(s):  
Kranthi Kumar Gangu ◽  
Sreekantha B. Jonnalagadda
Keyword(s):  
Active Sites ◽  
Heterogeneous Catalysts ◽  
Metal Organic Frameworks ◽  
Value Added ◽  
Biological Molecules ◽  
Full Potential ◽  
Organic Transformations ◽  
Solid Catalysts ◽  
Metal Organic ◽  
Catalytic Active Sites

Metal-organic frameworks (MOFs) have emerged as versatile candidates of interest in heterogeneous catalysis. Recent research and developments with MOFs positively endorse their role as catalysts in generating invaluable organic compounds. To harness the full potential of MOFs in value-added organic transformation, a comprehensive look at how these materials are likely to involve in the catalytic processes is essential. Mainstays of MOFs such as metal nodes, linkers, encapsulation materials, and enveloped structures tend to produce capable catalytic active sites that offer solutions to reduce human efforts in developing new organic reactions. The main advantages of choosing MOFs as reusable catalysts are the flexible and robust skeleton, regular porosity, high pore volume, and accessible synthesis accompanied with cost-effectiveness. As hosts for active metals, sole MOFs, modified MOFs, and MOFs have made remarkable advances as solid catalysts. The extensive exploration of the MOFs possibly led to their fast adoption in fabricating new biological molecules such as pyridines, quinolines, quinazolinones, imines, and their derivatives. This review covers the varied MOFs and their catalytic properties in facilitating the selective formation of the product organic moieties and interprets MOF’s property responsible for their elegant performance.

ChemInform Abstract: Metal-Organic Frameworks: Versatile Heterogeneous Catalysts for Efficient Catalytic Organic Transformations

ChemInform ◽  
2015 ◽  
Vol 46 (46) ◽  
pp. no-no
Author(s):  
Adeel H. Chughtai ◽  
Nazir Ahmad ◽  
Hussein A. Younus ◽  
A. Laypkov ◽  
Francis Verpoort
Keyword(s):  
Heterogeneous Catalysts ◽  
Metal Organic Frameworks ◽  
Organic Transformations ◽  
Metal Organic

An Overview of Metal-organic Frameworks-based Acid/Base Catalysts for Biofuel Synthesis

2020 ◽  
Vol 24 (16) ◽  
pp. 1876-1891
Author(s):  
Qiuyun Zhang ◽  
Yutao Zhang ◽  
Jingsong Cheng ◽  
Hu Li ◽  
Peihua Ma
Keyword(s):  
Alternative Fuels ◽  
Heterogeneous Catalysts ◽  
Supported Catalysts ◽  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
Flexible Structures ◽  
Biodiesel Production ◽  
Biodiesel Synthesis ◽  
Metal Organic ◽  
Organic Framework

Biofuel synthesis is of great significance for producing alternative fuels. Among the developed catalytic materials, the metal-organic framework-based hybrids used as acidic, basic, or supported catalysts play major roles in the biodiesel production. This paper presents a timely and comprehensive review of recent developments on the design and preparation of metal-organic frameworks-based catalysts used for biodiesel synthesis from various oil feedstocks, including MILs-based catalysts, ZIFs-based catalysts, UiO-based catalysts, Cu-BTC-based catalysts, and MOFs-derived porous catalysts. Due to their unique and flexible structures, excellent thermal and hydrothermal stability, and tunable host-guest interactions, as compared with other heterogeneous catalysts, metal-organic framework-based catalysts have good opportunities for application in the production of biodiesel at industrial scale.

Selective Cyclohexene Oxidation to Allylic Compounds over Cu-triazole Framework via Homolytic Activation of Hydrogen Peroxide

2021 ◽  
Author(s):  
Panyapat Ponchai ◽  
Kanyaporn Adpakpang ◽  
Sareeya Bureekaew
Keyword(s):  
Hydrogen Peroxide ◽  
Heterogeneous Catalysts ◽  
Metal Organic Frameworks ◽  
Porous Structures ◽  
Cyclohexene Oxidation ◽  
Catalytic Sites ◽  
P Utilization ◽  
Metal Organic ◽  
Activation Of Hydrogen Peroxide

Utilization of metal-organic frameworks as heterogeneous catalysts is crucial owing to their abundant catalytic sites and well-defined porous structures. Highly robust [Cu3(trz)3(μ3-OH)(OH)2(H2O)4]∙2H2O (trz = 1,2,4-triazole) was employed as a catalyst...

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