Li+ solvation in glyme–Li salt solvate ionic liquids

2015 ◽  
Vol 17 (12) ◽  
pp. 8248-8257 ◽  
Author(s):  
Kazuhide Ueno ◽  
Ryoichi Tatara ◽  
Seiji Tsuzuki ◽  
Soshi Saito ◽  
Hiroyuki Doi ◽  
...  
Keyword(s):  
Ionic Liquids ◽  
Crown Ether ◽  
Raman Spectra ◽  
Liquid State ◽  
Electrode Potentials

Raman spectra and electrode potentials corroborated that glyme–Li salt solvate ionic liquids consist of crown-ether like complex cations and counter anions with a few uncoordinated glyme molecules in the liquid state.

ChemInform Abstract: Crown Ether Complex Cation Ionic Liquids: Preparation and Applications in Organic Reactions.

ChemInform ◽  
2011 ◽  
Vol 42 (50) ◽  
pp. no-no
Author(s):  
Yingying Song ◽  
Huanwang Jing ◽  
Bo Li ◽  
Dongsheng Bai
Keyword(s):  
Ionic Liquids ◽  
Crown Ether ◽  
Complex Cation ◽  
Organic Reactions ◽  
Crown Ether Complex ◽  
Ether Complex

Application of Laser-Excited Raman Spectroscopy to Organic Chemistry. II. Conformers of Some Isochromans

1970 ◽  
Vol 24 (1) ◽  
pp. 42-43 ◽  
Author(s):  
Stanley K. Freeman
Keyword(s):  
Organic Chemistry ◽  
Raman Spectroscopy ◽  
Oxygen Atom ◽  
Aromatic Ring ◽  
Raman Spectra ◽  
Liquid State ◽  
Methyl Group ◽  
Methyl Analog

Raman spectra of 4-methyl isochroman and its aromatic ring substituted derivatives indicate the presence of two conformers in the liquid state and only one in the solid, while the 1- and 3-methyl analog assume one conformation only in both states. The presence of a methyl group adjacent to the ring oxygen atom sterically prevents adoption of one of the two possible conformations due to 1,3-interaction. No such restriction is imposed on the 4-methyl compounds.

The effect of ionic liquids as co-extractant with crown ether for the extraction of lithium in dichloromethane-water system

2019 ◽  
Vol 285 ◽  
pp. 75-83 ◽  
Author(s):  
Wenbo Zhu ◽  
Yongzhong Jia ◽  
Quanyou Zhang ◽  
Jinhe Sun ◽  
Yan Jing ◽  
...  
Keyword(s):  
Ionic Liquids ◽  
Crown Ether ◽  
Water System

scholarly journals Effects of substituent branching and chirality on the physical properties of ionic liquids based on cationic ruthenium sandwich complexes

2016 ◽  
Vol 18 (15) ◽  
pp. 10041-10048 ◽  
Author(s):  
Tomomi Higashi ◽  
Takahiro Ueda ◽  
Tomoyuki Mochida
Keyword(s):  
Ionic Liquids ◽  
Physical Properties ◽  
Liquid State ◽  
Sandwich Complexes

Organometallic ionic liquids with less symmetrical substituents tend to maintain the liquid state due to suppression of crystallization.

Raman spectra of ionic liquids: Interpretation via computer simulation

2004 ◽  
Vol 120 (14) ◽  
pp. 6609-6620 ◽  
Author(s):  
Paul A. Madden ◽  
Mark Wilson ◽  
Francis Hutchinson
Keyword(s):  
Computer Simulation ◽  
Ionic Liquids ◽  
Raman Spectra
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