On the Importance of the Metastable Liquid State and Glass Transition Phenomenon to Transport and Structure Studies in Ionic Liquids. I. Transport Properties1

1966 ◽  
Vol 70 (9) ◽  
pp. 2793-2803 ◽  
Author(s):  
C. Austen Angell
Keyword(s):  
Ionic Liquids ◽  
Glass Transition ◽  
Liquid State ◽  
Metastable Liquid ◽  
Transition Phenomenon

Ion specific, odd–even glass transition temperatures and conductivities in precise network polymerized ionic liquids

2019 ◽  
Vol 4 (2) ◽  
pp. 332-341 ◽  
Author(s):  
Chengtian Shen ◽  
Qiujie Zhao ◽  
Christopher M. Evans
Keyword(s):  
Ionic Liquids ◽  
Glass Transition ◽  
Network Architectures ◽  
Transition Temperatures ◽  
Glass Transition Temperatures

Network architectures reveal odd–even effects in existing PIL systems.

scholarly journals Effects of substituent branching and chirality on the physical properties of ionic liquids based on cationic ruthenium sandwich complexes

2016 ◽  
Vol 18 (15) ◽  
pp. 10041-10048 ◽  
Author(s):  
Tomomi Higashi ◽  
Takahiro Ueda ◽  
Tomoyuki Mochida
Keyword(s):  
Ionic Liquids ◽  
Physical Properties ◽  
Liquid State ◽  
Sandwich Complexes

Organometallic ionic liquids with less symmetrical substituents tend to maintain the liquid state due to suppression of crystallization.

scholarly journals The Fields of Crystal Engineering and Ionic Liquids Are Actually Quite Similar

2010 ◽  
Vol 63 (4) ◽  
pp. 533 ◽  
Author(s):  
Robin D. Rogers
Keyword(s):  
Ionic Liquids ◽  
Solid State ◽  
Crystal Engineering ◽  
Liquid State ◽  
Crystalline Solid

The fields of Crystal Engineering, the study and engineering of the crystalline solid state of materials, and Ionic Liquids, the study and engineering of the liquid state of salts that typically melt below 100, would seem at first glance polar opposites, but are they?

Dynamics of Compressed and Stretched Liquid SiO2, and the Glass Transition

1985 ◽  
Vol 63 ◽  
Author(s):  
C. A. Angell ◽  
P. A. Cheeseman ◽  
C. C. Phifer
Keyword(s):  
Glass Transition ◽  
Configuration Space ◽  
Negative Pressure ◽  
Liquid State ◽  
Ion Dynamics ◽  
System Configuration ◽  
Density Maximum ◽  
Pressure Regime ◽  
Dynamics Simulations

ABSTRACTIon dynamics simulations are presented to model the system SiO2 over wide ranges of temperature and density as it passes from liquid into glassy states. Essential features of the diffusive mechanism by means of which the system configuration space is explored are examined in relation to density and structure. The presence of a water-like density maximum in the liquid state of this system is established by using the negative pressure regime to stretch the system and thereby sharpen the phenomenon.

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