scholarly journals An experimental and theoretical study of the gas phase kinetics of atomic chlorine reactions with CH3NH2, (CH3)2NH, and (CH3)3N

2015 ◽  
Vol 17 (2) ◽  
pp. 911-917 ◽  
Author(s):  
J. M. Nicovich ◽  
S. Mazumder ◽  
P. L. Laine ◽  
P. H. Wine ◽  
Y. Tang ◽  
...  
Keyword(s):  
Gas Phase ◽  
Kinetic Data ◽  
Theoretical Study ◽  
Gas Phase Reactions ◽  
Chlorine Atoms ◽  
Gas Phase Kinetics ◽  
Kinetics Of ◽  
Atomic Chlorine

The first kinetic data for the gas phase reactions of amines with chlorine atoms.

Kinetics of the Gas-Phase Reactions of Chlorine Atoms with Naphthalene, Acenaphthene, and Acenaphthylene

2014 ◽  
Vol 118 (20) ◽  
pp. 3535-3540 ◽  
Author(s):  
Matthieu Riva ◽  
Robert M. Healy ◽  
Pierre-Marie Flaud ◽  
Emilie Perraudin ◽  
John C. Wenger ◽  
...  
Keyword(s):  
Gas Phase ◽  
Gas Phase Reactions ◽  
Chlorine Atoms ◽  
Kinetics Of

Numerical Simulation of Gas Phase Reaction Chemistry in Methane-Hydrogen Mixtures

2003 ◽  
Author(s):  
R. K. Garg ◽  
J. P. Gore ◽  
T. S. Fisher
Keyword(s):  
Gas Phase ◽  
Energy Deposition ◽  
Synthesis Process ◽  
Phase Reaction ◽  
Gas Phase Reactions ◽  
Gas Phase Kinetics ◽  
Hydrogen Mixtures ◽  
Kinetics Of ◽  
Energy Deposition Rate ◽  
Reactor Pressure

In the present work, gas-phase reactions between opposing streams of mixtures of hydrogen (H2) and methane (CH4) in the presence of volumetric energy input were simulated. The goal of the simulations is to estimate the concentrations of precursors responsible for the formation of carbon nanotubes (CNTs). These estimates are expected to help in understanding fundamental mechanisms of CNT formation and in controlling the synthesis process through parameters such as inlet composition and temperature, reactor pressure and absorbed energy. The simulation employs gas-phase kinetics of the GRI-2.11 mechanism with only reactions involving molecules that contain C and H atoms. The results indicate that the concentrations of H radicals, C2H2 and C atoms increase significantly with increases in volumetric energy deposition rate beyond a threshold.

Numerical Simulation of Hydrocarbon-Hydrogen Reaction Chemistry in a CVD Reactor

2003 ◽  
Author(s):  
R. K. Garg ◽  
J. P. Gore ◽  
T. S. Fisher
Keyword(s):  
Gas Phase ◽  
Energy Deposition ◽  
Chemical Vapor ◽  
Synthesis Process ◽  
Gas Phase Reactions ◽  
Gas Phase Kinetics ◽  
Hydrogen Mixtures ◽  
Kinetics Of ◽  
Energy Deposition Rate ◽  
Reactor Pressure

In the present work, gas-phase reactions for three different hydrocarbon-hydrogen mixtures (CH4+H2, C2H2+H2 and C2H4+H2) in the presence of volumetric energy input were simulated in a chemical vapor deposition (CVD) reactor. The goal of the simulations is to estimate the concentrations of species responsible for the formation of carbon nanotubes (CNTs). These estimates are expected to aid in understanding fundamental mechanisms of CNT formation and in controlling the synthesis process through process parameters such as inlet composition and temperature of the mixture, reactor pressure and microwave power. The simulation employs gas-phase kinetics of the GRI-2.11 mechanism with only reactions involving neutral molecules that contain C and H atoms. The results indicate that the concentrations of H radicals and C atoms increase with increases in energy deposition rate.

Kinetics of the gas phase reactions of chlorine atoms with a series of formates

2006 ◽  
Vol 432 (1-3) ◽  
pp. 57-61 ◽  
Author(s):  
T.J. Wallington ◽  
M.D. Hurley ◽  
A. Haryanto
Keyword(s):  
Gas Phase ◽  
Gas Phase Reactions ◽  
Chlorine Atoms ◽  
Kinetics Of

Thermodynamics and kinetics of initial gas phase reactions in chemical vapor deposition of titanium nitride. Theoretical study of TiCl4 ammonolysis

2001 ◽  
Vol 22 (13) ◽  
pp. 1366-1376 ◽  
Author(s):  
Stanislav Ya. Umanskii ◽  
Konstantin P. Novoselov ◽  
Airat Kh. Minushev ◽  
Magdalena Siodmiak ◽  
Gernot Frenking ◽  
...  
Keyword(s):  
Chemical Vapor Deposition ◽  
Titanium Nitride ◽  
Gas Phase ◽  
Vapor Deposition ◽  
Theoretical Study ◽  
Chemical Vapor ◽  
Gas Phase Reactions ◽  
Thermodynamics And Kinetics ◽  
Kinetics Of

A theoretical study on gas-phase reactions of acrylic acid with chlorine atoms: mechanism, kinetics, and insights

2020 ◽  
Vol 27 (13) ◽  
pp. 15772-15784 ◽  
Author(s):  
Jingyu Sun ◽  
Han Chu ◽  
Wenzhong Wu ◽  
Fang Chen ◽  
Yanan Sun ◽  
...  
Keyword(s):  
Acrylic Acid ◽  
Gas Phase ◽  
Theoretical Study ◽  
Gas Phase Reactions ◽  
Chlorine Atoms

Kinetics of the gas phase reactions of chlorine atoms and OH radicals with CF3CBrCH2 and CF3CF2CBrCH2

2009 ◽  
Vol 482 (1-3) ◽  
pp. 20-23 ◽  
Author(s):  
M.P. Sulbaek Andersen ◽  
M.D. Hurley ◽  
T.J. Wallington
Keyword(s):  
Gas Phase ◽  
Oh Radicals ◽  
Gas Phase Reactions ◽  
Chlorine Atoms ◽  
Kinetics Of

Kinetics of the gas phase reactions of chlorine atoms with a series of ketones

2006 ◽  
Vol 431 (4-6) ◽  
pp. 257-260 ◽  
Author(s):  
F. Taketani ◽  
Y. Matsumi ◽  
T.J. Wallington ◽  
M.D. Hurley
Keyword(s):  
Gas Phase ◽  
Gas Phase Reactions ◽  
Chlorine Atoms ◽  
Kinetics Of

scholarly journals Kinetics of the gas-phase reactions of chlorine atoms with CH2F2, CH3CCl3, and CF3CFH2over the temperature range 253-553 K

2009 ◽  
Vol 41 (6) ◽  
pp. 401-406 ◽  
Author(s):  
E. J. K. Nilsson ◽  
M. S. Johnson ◽  
O. J. Nielsen ◽  
E. W. Kaiser ◽  
T. J. Wallington
Keyword(s):  
Gas Phase ◽  
Gas Phase Reactions ◽  
Chlorine Atoms ◽  
Temperature Range ◽  
Kinetics Of
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