Dye-sensitized solar cell from polyaniline–ZnS nanotubes and its characterization through impedance spectroscopy

2014 ◽  
Vol 16 (37) ◽  
pp. 20079-20088 ◽  
Author(s):  
Arnab Shit ◽  
Shreyam Chatterjee ◽  
Arun K. Nandi

DSSC fabricated with polyaniline–ZnS nanotubes exhibits reversible turn “on” and “off” capability with an efficiency of 3.4%, as shown by a Nyquist plot, characterizing different transport processes.

2016 ◽  
Vol 4 (2) ◽  
pp. 272-285 ◽  
Author(s):  
Pousali Chal ◽  
Arnab Shit ◽  
Arun K. Nandi

Nanotubular polyaniline/N,N-di((S)-1-carboxylethyl)-3,4 : 9,10 perylenetetracarboxyldiimide hybrids with characteristics of H-type aggregates and secondary de-doping yield photocurrent with photoconversion efficiency of 2.88%.


2015 ◽  
Vol 1131 ◽  
pp. 169-174
Author(s):  
Prathan Prachopchok ◽  
Chanchana Thanachayanon ◽  
Tanakorn Osotchan

Impedance spectroscopy (IS) is a useful technique to investigate the detail of charge transfer in dye sensitized solar cell (DSSC) especially for individual part of cell component. The charge transport in electrolyte, platinum and TiO2 electrodes can be separately examined by varying the frequency range of IS. In this work, the TiO2 electrode was modified by various nanostructures and the equivalence circuit parameters extracted from the measured IS were correlated to the power conversion efficiency of fabricated solar cells, in order to describe the origin of decreasing and increasing of the DSSC efficiency. The TiO2 electrode was prepared at different conditions of mixing with inorganic nanoparticle of CdS, CdSe and nanostructure of C60 at various concentration. Normally, the DSSC with unmodified TiO2 electrode shows the efficiency about 7.12% at AM 1.5. The dramatically dropping of efficiency was occurred in the cell with very small amount of nanoparticle added in TiO2 electrode. For most of the cases, the efficiency tended to become increase as increasing the amount of nanoparticle in the TiO2 electrode. In some structures, the efficiency can become higher than that of the unmodified TiO2 cell. However the large amount of nanoparticle in TiO2 electrode leaded to decreasing of cell efficiency in all fabricated types of TiO2 nanostructure. These efficiency variations were related to the resistance and capacitance values extracted from IS measurement in the frequency range of TiO2 response. It was found that the extracted value of cell resistance played the important role on the efficiency variation and the capacitance value can be used to describe the life-time of charge carrier in the cells.Keywords: Impedance spectroscopy, dye sensitized solar cell.


2016 ◽  
Vol 18 (46) ◽  
pp. 31732-31743 ◽  
Author(s):  
Arnab Shit ◽  
Pousali Chal ◽  
Arun K. Nandi

The hybrid DSSC of a PANI–CdS composite with nanotubular morphology exhibits a maximum PCE of 3.96% showing the highest lifetime of 1.34 ms of photo-injected electrons.


Sign in / Sign up

Export Citation Format

Share Document