scholarly journals The impact of ionic liquid fluorinated moieties on their thermophysical properties and aqueous phase behaviour

2014 ◽  
Vol 16 (39) ◽  
pp. 21340-21348 ◽  
Author(s):  
Catarina M. S. S. Neves ◽  
Kiki A. Kurnia ◽  
Karina Shimizu ◽  
Isabel M. Marrucho ◽  
Luís Paulo N. Rebelo ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Ionic Liquids ◽  
Aqueous Phase ◽  
Thermophysical Properties ◽  
Phase Behaviour ◽  
Alkyl Chains ◽  
The Impact

The presence of fluorinated alkyl chains in ionic liquids is quite relevant regarding their thermophysical properties and aqueous phase behaviour.

scholarly journals Controlled Nanostructuration of Cobalt Oxyhydroxide Electrode Material for Hybrid Supercapacitors

Materials ◽  
2021 ◽  
Vol 14 (9) ◽  
pp. 2325
Author(s):  
Ronan Invernizzi ◽  
Liliane Guerlou-Demourgues ◽  
François Weill ◽  
Alexia Lemoine ◽  
Marie-Anne Dourges ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Ionic Liquids ◽  
Energy Storage ◽  
Specific Surface ◽  
Electrode Materials ◽  
Specific Capacity ◽  
Hybrid Supercapacitors ◽  
Cobalt Oxyhydroxide ◽  
Precipitation Medium ◽  
The Impact

Nanostructuration is one of the most promising strategies to develop performant electrode materials for energy storage devices, such as hybrid supercapacitors. In this work, we studied the influence of precipitation medium and the use of a series of 1-alkyl-3-methylimidazolium bromide ionic liquids for the nanostructuration of β(III) cobalt oxyhydroxides. Then, the effect of the nanostructuration and the impact of the different ionic liquids used during synthesis were investigated in terms of energy storage performances. First, we demonstrated that forward precipitation, in a cobalt-rich medium, leads to smaller particles with higher specific surface areas (SSA) and an enhanced mesoporosity. Introduction of ionic liquids (ILs) in the precipitation medium further strongly increased the specific surface area and the mesoporosity to achieve well-nanostructured materials with a very high SSA of 265 m2/g and porosity of 0.43 cm3/g. Additionally, we showed that ILs used as surfactant and template also functionalize the nanomaterial surface, leading to a beneficial synergy between the highly ionic conductive IL and the cobalt oxyhydroxide, which lowers the resistance charge transfer and improves the specific capacity. The nature of the ionic liquid had an important influence on the final electrochemical properties and the best performances were reached with the ionic liquid containing the longest alkyl chain.

scholarly journals Ionic liquids and deep eutectic solvents for the recovery of phenolic compounds: effect of ionic liquids structure and process parameters

RSC Advances ◽  
2021 ◽  
Vol 11 (20) ◽  
pp. 12398-12422
Author(s):  
Amir Sada Khan ◽  
Taleb H. Ibrahim ◽  
Nabil Abdel Jabbar ◽  
Mustafa I. Khamis ◽  
Paul Nancarrow ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Ionic Liquids ◽  
Phenolic Compounds ◽  
Liquid Phase ◽  
Aqueous Phase ◽  
Process Parameters ◽  
Deep Eutectic Solvents

Extraction of phenol from aqueous phase to ionic liquid phase.

scholarly journals Amphiphilic ionic liquid induced fusion of phospholipid liposomes

2020 ◽  
Vol 22 (43) ◽  
pp. 25255-25263
Author(s):  
Sandeep Kumar ◽  
Navleen Kaur ◽  
Venus Singh Mithu
Keyword(s):  
Ionic Liquid ◽  
Ionic Liquids ◽  
Structural Integrity ◽  
Unilamellar Vesicles ◽  
Phospholipid Liposomes ◽  
Large Unilamellar Vesicles ◽  
The Impact

The impact of increasing concentration of imidazolium-based ionic liquids ([CnMIM]+[Br]−) on the structural integrity of large unilamellar vesicles (LUVs) made of pure phosphatidylcholine (PC) and phosphatidylglycerol (PG) lipids.

Molecular dynamics study of mesophase transitions upon annealing of imidazolium-based ionic liquids with long-alkyl chains

2018 ◽  
Vol 20 (15) ◽  
pp. 9796-9805 ◽  
Author(s):  
Hailong Peng ◽  
Momoji Kubo ◽  
Hayato Shiba
Keyword(s):  
Molecular Dynamics ◽  
Ionic Liquid ◽  
Ionic Liquids ◽  
Alkyl Chains ◽  
Different Temperatures ◽  
Long Time

The isotropic to mesophase transition upon the long-time annealing of a 1-dodecyl-3-methylimidazolium hexafluorophosphate ionic liquid at different temperatures is illustrated.

Role of Cation in Enhancing the Conversion of the Alzheimer’s Peptide into Amyloid Fibrils Using Protic Ionic Liquids

2012 ◽  
Vol 65 (11) ◽  
pp. 1502 ◽  
Author(s):  
Natalie Debeljuh ◽  
Swapna Varghese ◽  
Colin J. Barrow ◽  
Nolene Byrne
Keyword(s):  
Ionic Liquid ◽  
Ionic Liquids ◽  
Primary Amine ◽  
Amyloid Fibrils ◽  
Tertiary Amines ◽  
Protic Ionic Liquids ◽  
Protic Ionic Liquid ◽  
The Difference ◽  
The Impact

We report on the impact of changes in the protic ionic liquid (pIL) cation on the fibrilisation kinetics and the conversion of the Aβ 16–22 from monomers to amyloid fibrils. When we compare the use of primary, secondary, and tertiary amines we find that the primary amine results in the greatest conversion into amyloid fibrils. We show that the pIL is directly interacting with the peptide and this likely drives the difference in conversion and kinetics observed.

scholarly journals Thermal stability of imidazolium-based ionic liquids

2016 ◽  
Vol 4 (1) ◽  
pp. 51-64 ◽  
Author(s):  
Léa Chancelier ◽  
Olivier Boyron ◽  
Thibaut Gutel ◽  
Catherine Santini
Keyword(s):  
Thermal Stability ◽  
Ionic Liquids ◽  
Hydrogen Bonds ◽  
Alkyl Chain ◽  
Alkyl Chain Length ◽  
Van Der Waals Interactions ◽  
Alkyl Chains ◽  
Coulombic Interactions ◽  
The Impact ◽  
Thermal Stability Of

This work highlights the factors tuning the thermal stability of imidazolium-based ionic liquids (IL) associated to bis(trifluoromethanesulfonyl)imide anion [NTf2]. The decomposition temperatures (Td) were evaluated by thermogravimetric analyses (TGA) with optimized parameters to obtain reproducible Td. The impact of the alkyl chain length and of the presence of functional groups and unsaturations on Td were evaluated. The thermal behaviour was governed by Van der Waals interactions between alkyl chains, and by inter and intra coulombic interactions such as hydrogen bonds.

Natural Convection in Rectangular Cavity With Nanoparticle Enhanced Ionic Liquids (NEILs)

2012 ◽  
Author(s):  
Titan C. Paul ◽  
A. K. M. M. Morshed ◽  
Elise B. Fox ◽  
Ann E. Visser ◽  
Nicholas J. Bridges ◽  
...  
Keyword(s):  
Heat Transfer ◽  
Thermal Conductivity ◽  
Heat Capacity ◽  
Ionic Liquid ◽  
Ionic Liquids ◽  
Natural Convection ◽  
Thermophysical Properties ◽  
Convection Heat Transfer ◽  
Natural Convection Heat Transfer ◽  
Convection Heat

A systematic natural convection heat transfer experiment has been carried out of nanoparticle enhanced ionic liquids (NEILs) in rectangular enclosures (lengthxwidthxheight, 50×50×50mm and 50×50×75mm) heated from below condition. In the present experiment NEIL was made of N-butyl-N-methylpyrrolidinium bis{(trifluoromethyl)sulfonyl} imide, ([C4mpyrr][NTf2]) ionic liquid with 0.5% (weight%) Al2O3 nanoparticles. In addition to characterize the natural convection behavior of NEIL, thermophysical properties such as thermal conductivity, heat capacity, and viscosity were also measured. The result shows that the thermal conductivity of NEIL enhanced ∼3% from the base ionic liquid (IL), heat capacity enhanced ∼12% over the measured temperature range. The natural convection experimental result shows consistent for two different enclosures based on the degrading natural convection heat transfer rate over the measured Rayleigh number range. Possible reasons of the degradation of natural convection heat transfer may be the relative change of the thermophysical properties of NEIL compare to the base ionic liquid.

An Efficient, Eco-Friendly, One-Pot Protocol for the Synthesis of 2-Oxazolines Promoted by Ionic Liquid/Indium Chloride

2006 ◽  
Vol 59 (7) ◽  
pp. 463 ◽  
Author(s):  
R. Kamakshi ◽  
Boreddy S. R. Reddy
Keyword(s):  
Ionic Liquid ◽  
Ionic Liquids ◽  
Lewis Acid ◽  
Acid Catalysts ◽  
Lewis Acid Catalysts ◽  
One Pot ◽  
Indium Chloride ◽  
Ambient Temperatures ◽  
Alkyl Chains ◽  
Liquid Indium

2-Oxazolines have been synthesized using a solventless ionic liquid melt in good yields at ambient temperatures. The efficiency of various Lewis acid catalysts for the same reaction has been compared. The effectiveness of different alkyl chains in the ionic liquids for the synthesis of oxazolines has been studied and a butylmethylimidazolinium chloride/indium chloride melt has been found to be the best media for promoting the reaction.

scholarly journals Is a medium-range order pre-peak possible for ionic liquids without an aliphatic chain?

RSC Advances ◽  
2015 ◽  
Vol 5 (63) ◽  
pp. 50938-50941 ◽  
Author(s):  
Marco Campetella ◽  
Serena De Santis ◽  
Ruggero Caminiti ◽  
Paolo Ballirano ◽  
Claudia Sadun ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Ionic Liquids ◽  
Range Order ◽  
Aliphatic Chain ◽  
Medium Range Order ◽  
X Ray ◽  
Alkyl Chains ◽  
X Ray Scattering ◽  
Medium Range ◽  
Ray Scattering

The pre-peak in the X-ray scattering patterns of ionic liquids is not always due to alkyl chains. In choline–proline (a bio-compatible ionic liquid), it is due to second-shell cation–cation distances.

scholarly journals Liquid-liquid solvent extraction of rare earths: a crystallographic analysis.

2014 ◽  
Vol 70 (a1) ◽  
pp. C1006-C1006
Author(s):  
Jeroen Jacobs ◽  
Koen Binnemans ◽  
Luc Van Meervelt
Keyword(s):  
Crystal Structure ◽  
Ionic Liquid ◽  
Ionic Liquids ◽  
Rare Earth ◽  
Solvent Extraction ◽  
Aqueous Phase ◽  
Rare Earths ◽  
Structural Information ◽  
Side Chain ◽  
Anionic Complex

Liquid-liquid solvent extraction has become the primary research topic for separating mixtures of rare-earths. [1] Current research on this topic focuses on extraction processes involving ionic liquids as basic extracting agents. In the aqueous phase, the rare-earth is coordinated by the anionic entities of the ionic liquid, forming an anionic complex. The large organic cation of the ionic liquid neutralizes the complex (ion-pair complex) and migrates the entity to an organic phase. The choice of these agents is solely based on the calculation of thermodynamical extraction parameters, whilst structural information about these compounds is rare or even non-existent. Our research focuses on obtaining structural information via crystallography on the above-mentioned molecules and relating the interactions between anion and cation to the stability of the complexes. A difference in stability between the anionic complex and cation can give a different extractability. Different rare-earth chloride salts were dissolved in an aqueous phase, containing ionic liquids with β-diketonate anions and 1-alkyl-3-methylimidazolium cations. After the extraction, crystals of the formed compounds are grown from the organic phase and measured. Current results show us that an intermolecular non-classical C-H ... O hydrogen bond is persistent across the different molecules, whilst small interactions between the cation side chain and halogens on the β-diketonate add extra stability to the crystal structure. Structures formed with 2-thenolytrifluoroactylacetonate anions have no intention to form side chain interactions, leaving the alkyl chain of the 1-alkyl-3-methylimidazolium in a void, whilst structures formed with hexafluoroacetylactonate have strong side chain interactions, which leads to a better packing. The different solubility of both compounds can be related to the different interactions and stability in the crystal structure.

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