Two three-dimensional cadmium(ii) coordination polymers based on 5-amino-tetrazolate and 1,2,4,5-benzenetetracarboxylate: the pH value controlled syntheses, crystal structures and luminescent properties

CrystEngComm ◽  
2014 ◽  
Vol 16 (21) ◽  
pp. 4633-4640 ◽  
Author(s):  
Di-Chang Zhong ◽  
Wen-Guan Lu ◽  
Ji-Hua Deng
Keyword(s):  
Crystal Structures ◽  
Coordination Polymers ◽  
Ph Value ◽  
Three Dimensional ◽  
Luminescent Properties ◽  
Ph Values

Two 3D cadmium(ii) coordination polymers have been prepared by controlling the pH values of the reaction mixture.

Three new three dimensional Zn(II)-benzenetetracarboxylate coordination polymers: Syntheses, crystal structures and luminescent properties

Polyhedron ◽  
2017 ◽  
Vol 123 ◽  
pp. 69-74 ◽  
Author(s):  
Yu-Hui Luo ◽  
Chuan-Zhou Tao ◽  
Dong-En Zhang ◽  
Juan-Juan Ma ◽  
Lin Liu ◽  
...  
Keyword(s):  
Crystal Structures ◽  
Coordination Polymers ◽  
Three Dimensional ◽  
Luminescent Properties

Coordination Polymers of Silver(I) with the Flexible Tritopic Ligand 1,3,5-Tri(4-cyanophenoxy)benzene: Guest Inclusion and Luminescent Properties

2013 ◽  
Vol 66 (4) ◽  
pp. 436 ◽  
Author(s):  
Sandipan Roy ◽  
Kumar Biradha
Keyword(s):  
Crystal Structures ◽  
Coordination Polymers ◽  
Three Dimensional ◽  
Luminescent Properties ◽  
Guest Molecules ◽  
Space Group ◽  
Centrosymmetric Space Group ◽  
Aromatic Guest

A new flexible tritopic ligand, 1,3,5-tri(4-cyanophenoxy)benzene (1), was synthesised by the reaction of phloroglucinol and para-fluorobenzonitrile. Compound 1 crystallises in the non-centrosymmetric space group Pna21. The reaction of ligand 1 with AgBF4 in the presence of different aromatic guest molecules was found to result in coordination polymers, namely, {[Ag3(1)2(BF4)3(H2O)2]·2C7H8·2CH2Cl2}n (2), {[Ag3(1)2(BF4)3(H2O)2]·2C6H6·2CH2Cl2}n (3). The crystal structures of 2 and 3 reveal that ligand 1 is linked by AgI ions into three-dimensional networks containing channels that are occupied by dichloromethane and aromatic guest molecules. The luminescent properties of crystalline 1 and 3 differ significantly.

Four d10Metal Coordination Polymers Containing Isomeric Thiodiphthalic Ligands:  Crystal Structures and Luminescent Properties

2007 ◽  
Vol 7 (7) ◽  
pp. 1277-1283 ◽  
Author(s):  
Yang Su ◽  
Shuangquan Zang ◽  
Yizhi Li ◽  
Huizhen Zhu ◽  
Qingjin Meng
Keyword(s):  
Crystal Structures ◽  
Coordination Polymers ◽  
Luminescent Properties
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