Modified secondary lithium metal batteries with the polyaniline–carbon nanotube composite buffer layer

2015 ◽  
Vol 51 (2) ◽  
pp. 322-325 ◽  
Author(s):  
Ding Zhang ◽  
Yanli Yin ◽  
Changhong Liu ◽  
Shoushan Fan
Keyword(s):  
Carbon Nanotube ◽  
Buffer Layer ◽  
Electrochemical Performances ◽  
Lithium Metal ◽  
Lithium Metal Batteries ◽  
Secondary Battery ◽  
Carbon Nanotube Composite

A PANI–CNT-film modified Li metal battery results in a new secondary battery with notably improved electrochemical performances and safe reliability.

From −20 °C to 150 °C: a lithium secondary battery with a wide temperature window obtained via manipulated competitive decomposition in electrolyte solution

2021 ◽  
Vol 9 (14) ◽  
pp. 9307-9318
Author(s):  
Tianle Zheng ◽  
Jianwei Xiong ◽  
Bingying Zhu ◽  
Xiaotang Shi ◽  
Ya-Jun Cheng ◽  
...  
Keyword(s):  
Electrolyte Solution ◽  
Wide Temperature Range ◽  
Decomposition Process ◽  
Lithium Metal ◽  
Lithium Secondary Battery ◽  
Temperature Range ◽  
Lithium Metal Batteries ◽  
Secondary Battery ◽  
Temperature Window

A competitive decomposition process is manipulated with ADN in an electrolyte solution containing EC, LiTFSI, and LiODFB via a solvation mechanism, which endows lithium metal batteries work over a wide temperature range between −20 °C and 150 °C.

scholarly journals Favorable Lithium Nucleation on Lithiophilic Framework Porphyrin for Dendrite-Free Lithium Metal Anodes

Research ◽  
2019 ◽  
Vol 2019 ◽  
pp. 1-11 ◽  
Author(s):  
Bo-Quan Li ◽  
Xiao-Ru Chen ◽  
Xiang Chen ◽  
Chang-Xin Zhao ◽  
Rui Zhang ◽  
...  
Keyword(s):  
Coulombic Efficiency ◽  
Dendrite Growth ◽  
Homogeneous Distribution ◽  
Electrochemical Performances ◽  
Lithium Metal ◽  
Lithium Metal Batteries ◽  
Host Materials ◽  
Lithium Metal Anodes ◽  
Excellent Stability ◽  
Metal Anodes

Lithium metal constitutes promising anode materials but suffers from dendrite growth. Lithiophilic host materials are highly considered for achieving uniform lithium deposition. Precise construction of lithiophilic sites with desired structure and homogeneous distribution significantly promotes the lithiophilicity of lithium hosts but remains a great challenge. In this contribution, a framework porphyrin (POF) material with precisely constructed lithiophilic sites in regard to chemical structure and geometric position is employed as the lithium host to address the above issues for dendrite-free lithium metal anodes. The extraordinary lithiophilicity of POF even beyond lithium nuclei validated by DFT simulations and lithium nucleation overpotentials affords a novel mechanism of favorable lithium nucleation to facilitate uniform nucleation and inhibit dendrite growth. Consequently, POF-based anodes demonstrate superior electrochemical performances with high Coulombic efficiency over 98%, reduced average voltage hysteresis, and excellent stability for 300 cycles at 1.0 mA cm−2, 1.0 mAh cm−2 superior to both Cu and graphene anodes. The favorable lithium nucleation mechanism on POF materials inspires further investigation of lithiophilic electrochemistry and development of lithium metal batteries.

Polypropylene Carbonate-Based Adaptive Buffer Layer for Stable Interfaces of Solid Polymer Lithium Metal Batteries

2019 ◽  
Vol 11 (31) ◽  
pp. 27906-27912 ◽  
Author(s):  
Haochen Yang ◽  
Yamin Zhang ◽  
Michael J. Tennenbaum ◽  
Zachary Althouse ◽  
Yao Ma ◽  
...  
Keyword(s):  
Buffer Layer ◽  
Solid Polymer ◽  
Lithium Metal ◽  
Lithium Metal Batteries

A single-ion conducting and shear-thinning polymer electrolyte based on ionic liquid-decorated PMMA nanoparticles for lithium-metal batteries

2016 ◽  
Vol 4 (47) ◽  
pp. 18543-18550 ◽  
Author(s):  
Yang Li ◽  
Ka Wai Wong ◽  
Qianqian Dou ◽  
Ka Ming Ng
Keyword(s):  
Ionic Liquid ◽  
Polymer Electrolyte ◽  
Conducting Polymer ◽  
Shear Thinning ◽  
Electrochemical Performances ◽  
Lithium Metal ◽  
Lithium Metal Batteries ◽  
Ion Conducting ◽  
Ion Conducting Polymer

A single-ion conducting polymer electrolyte based on ionic liquid-decorated PMMA nanoparticles exhibits excellent electrochemical performances.

A Dendrite‐Free Lithium/Carbon Nanotube Hybrid for Lithium‐Metal Batteries

2020 ◽  
pp. 2006702
Author(s):  
Zhi Yong Wang ◽  
Zhong Xu Lu ◽  
Wei Guo ◽  
Qin Luo ◽  
Yan Hong Yin ◽  
...  
Keyword(s):  
Carbon Nanotube ◽  
Lithium Metal ◽  
Lithium Metal Batteries
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