CNTs/LiV3O8/Y2O3 Composites with Enhanced Electrochemical Performances as Cathode Materials for Rechargeable Solid-State Lithium Metal Batteries

2021 ◽  
Vol 13 (7) ◽  
pp. 8219-8228
Author(s):  
Yuqiang Pi ◽  
Zhiwei Gan ◽  
Mengyu Yan ◽  
Zheng Li ◽  
Yushan Ruan ◽  
...  
Keyword(s):  
Solid State ◽  
Cathode Materials ◽  
Electrochemical Performances ◽  
Lithium Metal ◽  
Lithium Metal Batteries

Flame-retardant single-ion conducting polymer electrolytes based on anion acceptors for high-safety lithium metal batteries

2021 ◽  
Author(s):  
Kuirong Deng ◽  
Tianyu Guan ◽  
Fuhui Liang ◽  
Xiaoqiong Zheng ◽  
Qingguang Zeng ◽  
...  
Keyword(s):  
Solid State ◽  
Flame Retardant ◽  
Conducting Polymer ◽  
Polymer Electrolytes ◽  
Lithium Metal ◽  
Lithium Metal Batteries ◽  
Lithium Metal Anodes ◽  
Ion Conducting ◽  
Ion Conducting Polymer ◽  
Metal Anodes

Solid-state lithium metal batteries (LMBs) assembled with polymer electrolytes (PEs) and lithium metal anodes are promising batteries owing to their enhanced safeties and ultrahigh theoretical energy densities. Nevertheless, polymer electrolytes...

Double-Layered Multifunctional Composite Electrolytes for High-Voltage Solid-State Lithium-Metal Batteries

2021 ◽  
Vol 13 (10) ◽  
pp. 11958-11967
Author(s):  
Zhongran Yao ◽  
Kongjun Zhu ◽  
Xia Li ◽  
Jie Zhang ◽  
Jun Li ◽  
...  
Keyword(s):  
Solid State ◽  
High Voltage ◽  
Lithium Metal ◽  
Composite Electrolytes ◽  
Lithium Metal Batteries

3D glass fiber cloth reinforced polymer electrolyte for solid-state lithium metal batteries

2020 ◽  
pp. 118940
Author(s):  
Zheng Zhang ◽  
Ying Huang ◽  
Heng Gao ◽  
Chao Li ◽  
Jiaxin Huang ◽  
...  
Keyword(s):  
Solid State ◽  
Glass Fiber ◽  
Polymer Electrolyte ◽  
Lithium Metal ◽  
Lithium Metal Batteries ◽  
Reinforced Polymer

scholarly journals Unique Carbonate-Based Single Ion Conducting Block Copolymers Enabling High-Voltage, All-Solid-State Lithium Metal Batteries

2021 ◽  
Author(s):  
Gabriele Lingua ◽  
Patrick Grysan ◽  
Petr S. Vlasov ◽  
Pierre Verge ◽  
Alexander S. Shaplov ◽  
...  
Keyword(s):  
Solid State ◽  
Block Copolymers ◽  
High Voltage ◽  
Lithium Metal ◽  
Lithium Metal Batteries ◽  
Ion Conducting

scholarly journals HKUST-1@IL-Li Solid-state Electrolyte with 3D Ionic Channels and Enhanced Fast Li+ Transport for Lithium Metal Batteries at High Temperature

Nanomaterials ◽  
2021 ◽  
Vol 11 (3) ◽  
pp. 736
Author(s):  
Man Li ◽  
Tao Chen ◽  
Seunghyun Song ◽  
Yang Li ◽  
Joonho Bae
Keyword(s):  
High Temperature ◽  
Solid State ◽  
Solid Electrolyte ◽  
Metal Organic Framework ◽  
Ionic Channels ◽  
Transference Numbers ◽  
Lithium Metal ◽  
Lithium Metal Batteries ◽  
Metal Organic ◽  
Organic Framework

The challenge of safety problems in lithium batteries caused by conventional electrolytes at high temperatures is addressed in this study. A novel solid electrolyte (HKUST-1@IL-Li) was fabricated by immobilizing ionic liquid ([EMIM][TFSI]) in the nanopores of a HKUST-1 metal–organic framework. 3D angstrom-level ionic channels of the metal–organic framework (MOF) host were used to restrict electrolyte anions and acted as “highways” for fast Li+ transport. In addition, lower interfacial resistance between HKUST-1@IL-Li and electrodes was achieved by a wetted contact through open tunnels at the atomic scale. Excellent high thermal stability up to 300 °C and electrochemical properties are observed, including ionic conductivities and Li+ transference numbers of 0.68 × 10-4 S·cm-1 and 0.46, respectively, at 25 °C, and 6.85 × 10-4 S·cm-1 and 0.68, respectively, at 100 °C. A stable Li metal plating/stripping process was observed at 100 °C, suggesting an effectively suppressed growth of Li dendrites. The as-fabricated LiFePO4/HKUST-1@IL-Li/Li solid-state battery exhibits remarkable performance at high temperature with an initial discharge capacity of 144 mAh g-1 at 0.5 C and a high capacity retention of 92% after 100 cycles. Thus, the solid electrolyte in this study demonstrates promising applicability in lithium metal batteries with high performance under extreme thermal environmental conditions.

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