DABCO-catalyzed ring opening of activated cyclopropanes and recyclization leading to γ-lactams with an all-carbon quaternary center

2014 ◽  
Vol 50 (72) ◽  
pp. 10491-10494 ◽  
Author(s):  
Shaoxia Lin ◽  
Ling Li ◽  
Fushun Liang ◽  
Qun Liu

A novel and efficient method for the construction of γ-lactams with an all-carbon quaternary center is developed via a DABCO-catalyzed reaction of EWG-activated cyclopropanecarboxamides and electron-deficient alkenes.

2008 ◽  
Vol 2008 (4) ◽  
pp. 220-221 ◽  
Author(s):  
Dadkhoda Ghazanfari ◽  
Mohammed M. Hashemi ◽  
Mohammad Mehdi Mottaghi ◽  
Mohammad Mehdi Foroughi

2019 ◽  
Vol 10 (25) ◽  
pp. 6350-6353 ◽  
Author(s):  
Quan Gong ◽  
Jialin Wen ◽  
Xumu Zhang

We herein report an efficient method to synthesize cyclic hydroxy ketones with a chiral quaternary center.


2020 ◽  
Vol 18 (19) ◽  
pp. 3734-3739 ◽  
Author(s):  
Xiaobao Zeng ◽  
Xin Wang ◽  
Yanan Zhang ◽  
Li Zhu ◽  
Yu Zhao

A simple and efficient method for the radical ring-opening reaction of cyclopropanols with sulfonyl oxime ethers catalyzed by AgNO3 is developed, affording γ-keto oxime ethers in moderate to good yields.


2007 ◽  
Vol 264 (1-2) ◽  
pp. 162-169 ◽  
Author(s):  
Rukhsana Ilyas Kureshy ◽  
Surendra Singh ◽  
Noor-ul Hasan Khan ◽  
Sayed Hasan Razi Abdi ◽  
Eringathodi Suresh ◽  
...  

2001 ◽  
Vol 25 (2) ◽  
pp. 221-222 ◽  
Author(s):  
L. Rajender Reddy ◽  
M. Arjun Reddy ◽  
N. Bhanumathi ◽  
K. Rama Rao

SynOpen ◽  
2017 ◽  
Vol 01 (01) ◽  
pp. 0015-0023 ◽  
Author(s):  
Nirnita Ghosal ◽  
Sachinta Mahato ◽  
Rana Chatterjee ◽  
Sougata Santra ◽  
Grigory Zyryanov ◽  
...  

We have developed a new synthetic method for the synthesis of aziridines using Chloramine-T as an effective reagent in the presence of NH2OH·HCl and NaIO4. We found that the same combination of NH2OH·HCl and NaIO4 is also very effective for nucleophilic ring opening of aziridines.


2011 ◽  
Vol 339 (1-2) ◽  
pp. 32-36 ◽  
Author(s):  
Ervin Kovács ◽  
Angelika Thurner ◽  
Ferenc Farkas ◽  
Ferenc Faigl ◽  
László Hegedűs

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