Palladium-catalyzed thiolation of alkanes and ethers with arylsulfonyl hydrazides

2014 ◽  
Vol 50 (62) ◽  
pp. 8578-8581 ◽  
Author(s):  
Sheng-rong Guo ◽  
Wei-ming He ◽  
Jian-nan Xiang ◽  
Yan-qin Yuan
Keyword(s):  
New Method ◽  
Alkyl Aryl ◽  
Palladium Catalyzed ◽  
Aryl Sulfides

A new method for the preparation of alkyl aryl sulfides through direct oxidative thiolation of alkanes or ethers with arylsulfonyl hydrazides using DTBP as an oxidant catalyzed by Pd(OAc)2 has been reported. The C–H bonds in various alkanes or ethers were successfully converted into C–S bonds with moderate to good yields.

A Novel Method for the Direct Synthesis of Symmetrical and Unsymmetrical Sulfides and Disulfides from Aryl Halides and Ethyl Potassium Xanthogenate

Synlett ◽  
2018 ◽  
Vol 29 (07) ◽  
pp. 986-992 ◽  
Author(s):  
M. Soleiman-Beigi ◽  
Z. Arzehgar
Keyword(s):  
Direct Synthesis ◽  
Aryl Halides ◽  
New Method ◽  
Alkyl Aryl ◽  
Novel Method ◽  
Aryl Sulfides ◽  
Bunte Salts

An efficient and new method for the synthesis of disulfides and sulfides via the reaction of aryl halides with ethyl potassium xanthogenate in the presence of MOF-199 is described. O-Ethyl-S-aryl ­carbonodithioate has a key role as an intermediate in this procedure; it was converted into symmetrical diaryl disulfides in DMF. Additionally, this could be applied to the synthesis of unsymmetrical aryl alkyl(aryl′) disulfides by the reaction with S-alkyl(aryl) sulfurothioates (Bunte salts) as well as unsymmetrical aryl alkyl(aryl′) sulfides in DMSO.

scholarly journals A New Method for the Synthesis of Alkyl Aryl Sulfides

1966 ◽  
Vol 39 (2) ◽  
pp. 411-411 ◽  
Author(s):  
Hiroshi Yoshida ◽  
Saburo Inokawa ◽  
Tsuyoshi Ogata
Keyword(s):  
New Method ◽  
Alkyl Aryl ◽  
Aryl Sulfides

ChemInform Abstract: Palladium-Catalyzed Amination of Aryl Sulfides with Aliphatic Amines.

ChemInform ◽  
2015 ◽  
Vol 46 (33) ◽  
pp. no-no
Author(s):  
Ke Gao ◽  
Hideki Yorimitsu ◽  
Atsuhiro Osuka
Keyword(s):  
Aliphatic Amines ◽  
Palladium Catalyzed ◽  
Aryl Sulfides

A New Method To Generate Arene-Terminated Si(111) and Ge(111) Surfaces via a Palladium-Catalyzed Arylation Reaction

2012 ◽  
Vol 134 (50) ◽  
pp. 20433-20439 ◽  
Author(s):  
Yoshinori Yamanoi ◽  
Junya Sendo ◽  
Tetsuhiro Kobayashi ◽  
Hiroaki Maeda ◽  
Yusuke Yabusaki ◽  
...  
Keyword(s):  
New Method ◽  
Palladium Catalyzed

A Facile One-Pot Synthesis of Alkyl Aryl Sulfides from Aryl Bromides

2004 ◽  
Vol 69 (9) ◽  
pp. 3236-3239 ◽  
Author(s):  
Jungyeob Ham ◽  
Inho Yang ◽  
Heonjoong Kang
Keyword(s):  
One Pot ◽  
Alkyl Aryl ◽  
One Pot Synthesis ◽  
Aryl Bromides ◽  
Aryl Sulfides

Palladium-catalyzed selective hydrogenolysis of N-alkyl(aryl)-substituted γ-keto amides as an approach to γ-lactams or linear amides

2015 ◽  
Vol 64 (5) ◽  
pp. 1065-1068
Author(s):  
O. V. Turova ◽  
V. G. Berezhnaya ◽  
E. V. Starodubtseva ◽  
M. G. Vinogradov
Keyword(s):  
Alkyl Aryl ◽  
Selective Hydrogenolysis ◽  
Palladium Catalyzed
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