A New Method for the Preparation of Alkyl Aryl Sulfides from Alcohols via Alkoxydiphenylphosphines by Oxidation?Reduction Condensation.

ChemInform ◽  
2005 ◽  
Vol 36 (19) ◽  
Author(s):  
Teruaki Mukaiyama ◽  
Kazuhiro Ikegai
Keyword(s):  
New Method ◽  
Alkyl Aryl ◽  
Oxidation Reduction ◽  
Aryl Sulfides

A Novel Method for the Direct Synthesis of Symmetrical and Unsymmetrical Sulfides and Disulfides from Aryl Halides and Ethyl Potassium Xanthogenate

Synlett ◽  
2018 ◽  
Vol 29 (07) ◽  
pp. 986-992 ◽  
Author(s):  
M. Soleiman-Beigi ◽  
Z. Arzehgar
Keyword(s):  
Direct Synthesis ◽  
Aryl Halides ◽  
New Method ◽  
Alkyl Aryl ◽  
Novel Method ◽  
Aryl Sulfides ◽  
Bunte Salts

An efficient and new method for the synthesis of disulfides and sulfides via the reaction of aryl halides with ethyl potassium xanthogenate in the presence of MOF-199 is described. O-Ethyl-S-aryl ­carbonodithioate has a key role as an intermediate in this procedure; it was converted into symmetrical diaryl disulfides in DMF. Additionally, this could be applied to the synthesis of unsymmetrical aryl alkyl(aryl′) disulfides by the reaction with S-alkyl(aryl) sulfurothioates (Bunte salts) as well as unsymmetrical aryl alkyl(aryl′) sulfides in DMSO.

Palladium-catalyzed thiolation of alkanes and ethers with arylsulfonyl hydrazides

2014 ◽  
Vol 50 (62) ◽  
pp. 8578-8581 ◽  
Author(s):  
Sheng-rong Guo ◽  
Wei-ming He ◽  
Jian-nan Xiang ◽  
Yan-qin Yuan
Keyword(s):  
New Method ◽  
Alkyl Aryl ◽  
Palladium Catalyzed ◽  
Aryl Sulfides

A new method for the preparation of alkyl aryl sulfides through direct oxidative thiolation of alkanes or ethers with arylsulfonyl hydrazides using DTBP as an oxidant catalyzed by Pd(OAc)2 has been reported. The C–H bonds in various alkanes or ethers were successfully converted into C–S bonds with moderate to good yields.

scholarly journals A New Method for the Synthesis of Alkyl Aryl Sulfides

1966 ◽  
Vol 39 (2) ◽  
pp. 411-411 ◽  
Author(s):  
Hiroshi Yoshida ◽  
Saburo Inokawa ◽  
Tsuyoshi Ogata
Keyword(s):  
New Method ◽  
Alkyl Aryl ◽  
Aryl Sulfides
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