Two novel derivatives of ammonia borane for hydrogen storage: synthesis, structure, and hydrogen desorption investigation

2013 ◽  
Vol 1 (39) ◽  
pp. 12263 ◽  
Author(s):  
Leigang Li ◽  
Qinfen Gu ◽  
Ziwei Tang ◽  
Xiaowei Chen ◽  
Yingbin Tan ◽  
...  
Keyword(s):  
Hydrogen Storage ◽  
Ammonia Borane ◽  
Hydrogen Desorption ◽  
Derivatives Of

Computational study of methyl derivatives of ammonia borane for hydrogen storage

2008 ◽  
Vol 10 (40) ◽  
pp. 6104 ◽  
Author(s):  
Cheng-Hua Sun ◽  
Xiang-Dong Yao ◽  
Ai-Jun Du ◽  
L. Li ◽  
Sean Smith ◽  
...  
Keyword(s):  
Hydrogen Storage ◽  
Computational Study ◽  
Ammonia Borane ◽  
Methyl Derivatives ◽  
Derivatives Of

Hydrogen-mediated affinity of ions found in compressed potassium amidoborane, K[NH2BH3]

CrystEngComm ◽  
2014 ◽  
Vol 16 (45) ◽  
pp. 10367-10370 ◽  
Author(s):  
Ewelina Magos-Palasyuk ◽  
Taras Palasyuk ◽  
Patryk Zaleski-Ejgierd ◽  
Karol Fijalkowski
Keyword(s):  
Hydrogen Storage ◽  
Theoretical Investigation ◽  
Ammonia Borane ◽  
Hydrogen Storage Material ◽  
Storage Material ◽  
Bonding Properties ◽  
Derivatives Of

The paper reports on the experimental and theoretical investigation of bonding properties of potassium amidoborane, (K[NH2BH3]), which is one of the most promising compounds for hydrogen storage material among metallated derivatives of ammonia borane (NH3BH3).

Preparation and Hydrogen Storage Kinetics of Nanocrystalline and Amorphous Mg20Ni8M2 (M=Cu, Co) Alloys

2012 ◽  
Vol 586 ◽  
pp. 50-57
Author(s):  
Yang Huan Zhang ◽  
Tai Yang ◽  
Hong Wei Shang ◽  
Guo Fang Zhang ◽  
Xia Li ◽  
...  
Keyword(s):  
Hydrogen Storage ◽  
Melt Spinning ◽  
Nanocrystalline Structure ◽  
Hydrogen Desorption ◽  
Amorphous Structure ◽  
Saturation Ratio ◽  
Cu Alloy ◽  
Nanocrystalline And Amorphous ◽  
Kinetics Of ◽  
Co Alloys

In order to obtain a nanocrystalline and amorphous structure, the Mg20Ni8M2 (M=Cu, Co) hydrogen storage alloys were fabricated by the melt spinning technology. The microstructures of the alloys were characterized by XRD, SEM and HRTEM. The effects of the melt spinning on the hydriding and dehydriding kinetics of the alloys were investigated. The results indicate that the as-spun (M=Cu) alloys hold an entire nanocrystalline structure even if the limited spinning rate is applied, while the as-spun (M=Co) alloys display a nanocrystalline and amorphous structure as the spinning rate grows to 30 m/s, suggesting that the substitution of Co for Ni facilitates the glass formation in the Mg2Ni-type alloy. The melt spinning remarkably improves the gaseous hydriding and dehydriding kinetics of the alloys. As the spinning rate grows from 0 (As-cast was defined as the spinning rate of 0 m/s) to 30 m/s, the hydrogen absorption saturation ratio ( ) is enhanced from 56.72% to 92.74% for the (M=Cu) alloy and from 80.43% to 94.38% for the (M=Co) alloy. The hydrogen desorption ratio ( ) is raised from14.89% to 40.37% for the (M=Cu) alloy and from 24.52% to 51.67% for the (M=Co) alloy.

Thermal Stability of Ammonia Borane: A Case Study for Exothermic Hydrogen Storage Materials

2010 ◽  
Vol 24 (4) ◽  
pp. 2596-2606 ◽  
Author(s):  
Scot D. Rassat ◽  
Christopher L. Aardahl ◽  
Tom Autrey ◽  
R. Scott Smith
Keyword(s):  
Thermal Stability ◽  
Hydrogen Storage ◽  
Ammonia Borane ◽  
Hydrogen Storage Materials ◽  
Storage Materials ◽  
Thermal Stability Of

Nano-Columnar Mg Thin Films Created by Plasma Sputter Deposition for Improved Hydrogen Kinetics and Storage Properties

2004 ◽  
Vol 837 ◽  
Author(s):  
M. W. Zandbergen ◽  
S. W. H. Eijt ◽  
W. J. Legerstee ◽  
H. Schut ◽  
V. L. Svetchnikov
Keyword(s):  
Thin Films ◽  
Hydrogen Storage ◽  
Hydrogen Permeation ◽  
Hydrogen Desorption ◽  
Sputter Deposition ◽  
Hydrogen Molecules ◽  
Concomitant Reduction ◽  
And Storage ◽  
Determining Factor ◽  
Storage Properties

ABSTRACTThe hydrogen storage properties of nanostructured Mg and MgH2 thin films were studied as created by Ar and Ar+H2 plasma sputter deposition. Columnar structures with typical widths of ∼120 nm are observed with their long columnar axis extending throughout the thickness of the films. Applying substrate bias voltages during deposition results in narrower columns. A concomitant reduction in hydrogen desorption temperature from 400 °C to 360 °C is observed. Capping the Mg films with a ∼100 nm thin Pd layer leads to significantly reduced hydrogen desorption temperatures of ∼200 °C induced by the catalytic activity of the Pd cap layer. Also, hydrogen permeation of the films is strongly improved. The rate-determining factor is found to be the dissociation of the hydrogen molecules. Optimum hydrogen loading conditions of the Pd/Mg films were obtained just above ∼200 °C at hydrogen pressures of 0.25–1.0 MPa, resulting in hydrogen storage capacities in the range of 4–7 wt%.

Polyacrylamide Blending with Ammonia Borane: A Polymer Supported Hydrogen Storage Composite

2011 ◽  
Vol 116 (1) ◽  
pp. 1544-1549 ◽  
Author(s):  
S. F. Li ◽  
Z. W. Tang ◽  
Y. B. Tan ◽  
X. B. Yu
Keyword(s):  
Hydrogen Storage ◽  
Ammonia Borane ◽  
Polymer Supported

Defect-Rich Walnut-like Copper-Doped Ni(PO3)2 Catalyst towards Ammonia Borane Electrooxidation Reaction with High Performance

2022 ◽  
Author(s):  
Jia Yu ◽  
Haiyan Jing ◽  
Peng Zhao ◽  
Keren Lu ◽  
Juanjuan Song ◽  
...  
Keyword(s):  
Free Energy ◽  
Fuel Cells ◽  
Hydrogen Storage ◽  
High Performance ◽  
Ammonia Borane ◽  
Energy Material

Ammonia borane (NH3BH3, AB), a carbon-free-energy material has attracted enormous attention not only as the hydrogen storage source but also as the anodic fuel for direct AB fuel cells (DABFCs)....

The hydrolysis of ammonia borane catalyzed by NiCoP/OPC-300 nanocatalysts: high selectivity and efficiency, and mechanism

2019 ◽  
Vol 21 (4) ◽  
pp. 850-860 ◽  
Author(s):  
Xiaopeng Qu ◽  
Rui Jiang ◽  
Qian Li ◽  
Fanan Zeng ◽  
Xue Zheng ◽  
...  
Keyword(s):  
Hydrogen Storage ◽  
High Selectivity ◽  
Clean Energy ◽  
Ammonia Borane ◽  
Hydrogen Storage Materials ◽  
Storage Materials ◽  
Highly Efficient ◽  
Energy Economy ◽  
Chemical Hydrogen Storage ◽  
Hydrolysis Of

The development of highly efficient and cheap catalysts for the release of hydrogen from chemical hydrogen-storage materials is indispensable for the coming clean energy economy.

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