Hydrogen-mediated affinity of ions found in compressed potassium amidoborane, K[NH2BH3]

CrystEngComm ◽  
2014 ◽  
Vol 16 (45) ◽  
pp. 10367-10370 ◽  
Author(s):  
Ewelina Magos-Palasyuk ◽  
Taras Palasyuk ◽  
Patryk Zaleski-Ejgierd ◽  
Karol Fijalkowski
Keyword(s):  
Hydrogen Storage ◽  
Theoretical Investigation ◽  
Ammonia Borane ◽  
Hydrogen Storage Material ◽  
Storage Material ◽  
Bonding Properties ◽  
Derivatives Of

The paper reports on the experimental and theoretical investigation of bonding properties of potassium amidoborane, (K[NH2BH3]), which is one of the most promising compounds for hydrogen storage material among metallated derivatives of ammonia borane (NH3BH3).

Ammonia borane with polyvinylpyrrolidone as a hydrogen storage material: Comparison of different molecular weights

2017 ◽  
Vol 110 ◽  
pp. 394-400 ◽  
Author(s):  
Ramanjaneyulu Seemaladinne ◽  
Sahithya Pati ◽  
Krishna Kharel ◽  
Adarsh Bafana ◽  
Amal al-Wahish ◽  
...  
Keyword(s):  
Hydrogen Storage ◽  
Ammonia Borane ◽  
Hydrogen Storage Material ◽  
Storage Material ◽  
Molecular Weights

The Route to a Feasible Hydrogen-Storage Material: MOFs versus Ammonia Borane

2011 ◽  
Vol 17 (37) ◽  
pp. 10184-10207 ◽  
Author(s):  
Thomas Hügle ◽  
Monika Hartl ◽  
Dieter Lentz
Keyword(s):  
Hydrogen Storage ◽  
Ammonia Borane ◽  
Hydrogen Storage Material ◽  
Storage Material

Mechanistic insights into the thermal decomposition of ammonia borane, a material studied for chemical hydrogen storage

2021 ◽  
Vol 8 (7) ◽  
pp. 1900-1930
Author(s):  
Umit B. Demirci
Keyword(s):  
Thermal Decomposition ◽  
Hydrogen Storage ◽  
Ammonia Borane ◽  
Hydrogen Storage Material ◽  
Storage Material ◽  
Chemical Hydrogen Storage

We have now a better understanding of the mechanisms of thermal decomposition of ammonia borane, a widely studied hydrogen storage material.

ChemInform Abstract: Ammonia Borane Destabilized by Lithium Hydride: An Advanced On-Board Hydrogen Storage Material.

ChemInform ◽  
2008 ◽  
Vol 39 (44) ◽  
Author(s):  
Xiangdong Kang ◽  
Zhanzhao Fang ◽  
Lingyan Kong ◽  
Huiming Cheng ◽  
Xiangdong Yao ◽  
...  
Keyword(s):  
Hydrogen Storage ◽  
Ammonia Borane ◽  
Lithium Hydride ◽  
Hydrogen Storage Material ◽  
Storage Material

scholarly journals Solid-State High-Resolution1H-NMR Study for Ammonia Borane of Hydrogen Storage Material

2010 ◽  
Vol 14 (1) ◽  
pp. 38-44 ◽  
Author(s):  
J.H. Han ◽  
Cheol-Eui Lee ◽  
Se-Hun Kim ◽  
Chang-Sam Kim ◽  
Doug-Young Han
Keyword(s):  
Solid State ◽  
Hydrogen Storage ◽  
Ammonia Borane ◽  
Hydrogen Storage Material ◽  
Storage Material ◽  
Nmr Study

scholarly journals Catalytic Hydrolysis of Ammonia Borane by Cobalt Nickel Nanoparticles Supported on Reduced Graphene Oxide for Hydrogen Generation

2014 ◽  
Vol 2014 ◽  
pp. 1-9 ◽  
Author(s):  
Yuwen Yang ◽  
Fei Zhang ◽  
Hualan Wang ◽  
Qilu Yao ◽  
Xiangshu Chen ◽  
...  
Keyword(s):  
Graphene Oxide ◽  
Catalytic Activity ◽  
Hydrogen Storage ◽  
Reduced Graphene Oxide ◽  
Ammonia Borane ◽  
Reducing Agent ◽  
Hydrogen Storage Material ◽  
Storage Material ◽  
Reduced Graphene ◽  
Total Turnover

Well dispersed magnetically recyclable bimetallic CoNi nanoparticles (NPs) supported on the reduced graphene oxide (RGO) were synthesized by one-step in situ coreduction of aqueous solution of cobalt(II) chloride, nickel (II) chloride, and graphite oxide (GO) with ammonia borane (AB) as the reducing agent under ambient condition. The CoNi/RGO NPs exhibits excellent catalytic activity with a total turnover frequency (TOF) value of 19.54 mol H2 mol catalyst−1 min−1and a low activation energy value of 39.89 kJ mol−1at room temperature. Additionally, the RGO supported CoNi NPs exhibit much higher catalytic activity than the monometallic and RGO-free CoNi counterparts. Moreover, the as-prepared catalysts exert satisfying durable stability and magnetically recyclability for the hydrolytic dehydrogenation of AB, which make the practical reusing application of the catalysts more convenient. The usage of the low-cost, easy-getting catalyst to realize the production of hydrogen under mild condition gives more confidence for the application of ammonia borane as a hydrogen storage material. Hence, this general method indicates that AB can be used as both a potential hydrogen storage material and an efficient reducing agent, and can be easily extended to facile preparation of other RGO-based metallic systems.

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