Novel triple-shape PCU/PPDO interpenetrating polymer networks constructed by self-complementary quadruple hydrogen bonding and covalent bonding

2014 ◽  
Vol 5 (7) ◽  
pp. 2231 ◽  
Author(s):  
Liping Xiao ◽  
Min Wei ◽  
Miqin Zhan ◽  
Jingjing Zhang ◽  
Hui Xie ◽  
...  
Keyword(s):  
Hydrogen Bonding ◽  
Polymer Networks ◽  
Covalent Bonding ◽  
Interpenetrating Polymer Networks ◽  
Quadruple Hydrogen Bonding

Interpenetrating polymer networks with controllable intermolecular hydrogen bonding

1990 ◽  
Vol 23 (1) ◽  
pp. 103-109 ◽  
Author(s):  
Ming Jiang ◽  
Hong Xiao ◽  
Xiaoling Jin ◽  
Tongyin Yu
Keyword(s):  
Hydrogen Bonding ◽  
Polymer Networks ◽  
Interpenetrating Polymer Networks ◽  
Intermolecular Hydrogen Bonding

scholarly journals The microscopic distribution of hydrophilic polymers in interpenetrating polymer networks (IPNs) of medical grade silicone

Polymer ◽  
2021 ◽  
Vol 224 ◽  
pp. 123671
Author(s):  
Gregory N. Smith ◽  
Erik Brok ◽  
Martin Schmiele ◽  
Kell Mortensen ◽  
Wim G. Bouwman ◽  
...  
Keyword(s):  
Polymer Networks ◽  
Interpenetrating Polymer Networks ◽  
Hydrophilic Polymers ◽  
Microscopic Distribution ◽  
Medical Grade

scholarly journals Quadruple Hydrogen Bond-Containing A-AB-A Triblock Copolymers: Probing the Influence of Hydrogen Bonding in the Central Block

Molecules ◽  
2021 ◽  
Vol 26 (15) ◽  
pp. 4705
Author(s):  
Boer Liu ◽  
Xi Chen ◽  
Glenn A. Spiering ◽  
Robert B. Moore ◽  
Timothy E. Long
Keyword(s):  
Hydrogen Bonding ◽  
Self Assembly ◽  
Microphase Separation ◽  
Triblock Copolymers ◽  
Random Copolymer ◽  
Thermomechanical Properties ◽  
Structure Property ◽  
Scanning Calorimetry ◽  
Central Block ◽  
Quadruple Hydrogen Bonding

This work reveals the influence of pendant hydrogen bonding strength and distribution on self-assembly and the resulting thermomechanical properties of A-AB-A triblock copolymers. Reversible addition-fragmentation chain transfer polymerization afforded a library of A-AB-A acrylic triblock copolymers, wherein the A unit contained cytosine acrylate (CyA) or post-functionalized ureido cytosine acrylate (UCyA) and the B unit consisted of n-butyl acrylate (nBA). Differential scanning calorimetry revealed two glass transition temperatures, suggesting microphase-separation in the A-AB-A triblock copolymers. Thermomechanical and morphological analysis revealed the effects of hydrogen bonding distribution and strength on the self-assembly and microphase-separated morphology. Dynamic mechanical analysis showed multiple tan delta (δ) transitions that correlated to chain relaxation and hydrogen bonding dissociation, further confirming the microphase-separated structure. In addition, UCyA triblock copolymers possessed an extended modulus plateau versus temperature compared to the CyA analogs due to the stronger association of quadruple hydrogen bonding. CyA triblock copolymers exhibited a cylindrical microphase-separated morphology according to small-angle X-ray scattering. In contrast, UCyA triblock copolymers lacked long-range ordering due to hydrogen bonding induced phase mixing. The incorporation of UCyA into the soft central block resulted in improved tensile strength, extensibility, and toughness compared to the AB random copolymer and A-B-A triblock copolymer comparisons. This study provides insight into the structure-property relationships of A-AB-A supramolecular triblock copolymers that result from tunable association strengths.

Use of Quadruple Hydrogen Bonding as the Switching Phase in Thermo- and Light-Responsive Shape Memory Hydrogel

2021 ◽  
Author(s):  
Yufang Song ◽  
Yiming Chen ◽  
Ran Chen ◽  
Hongji Zhang ◽  
Dongjian Shi ◽  
...  
Keyword(s):  
Hydrogen Bonding ◽  
Shape Memory ◽  
Quadruple Hydrogen Bonding

Organic-solvent-free electromembrane extraction based on semi-interpenetrating polymer networks

2021 ◽  
Author(s):  
Hang Mei ◽  
Huajing Liu ◽  
Qianqian Shang ◽  
Ying Dong ◽  
Stig Pedersen-Bjergaard ◽  
...  
Keyword(s):  
Organic Solvent ◽  
Polymer Networks ◽  
Interpenetrating Polymer Networks ◽  
Solvent Free ◽  
Electromembrane Extraction ◽  
Acidic Analytes

A versatile organic-solvent-free electromembrane extraction (EME) system, which could be successfully used for the extraction of both basic and acidic analytes, is proposed based on semi-interpenetrating polymer networks.

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