Well-defined graft copolymers of tert-butyldimethylsilyl methacrylate and poly(dimethylsiloxane) macromonomers synthesized by RAFT polymerization

2013 ◽  
Vol 4 (11) ◽  
pp. 3282 ◽  
Author(s):  
Marlène Lejars ◽  
André Margaillan ◽  
Christine Bressy
Keyword(s):  
Raft Polymerization ◽  
Graft Copolymers

Cellulose graft copolymers toward strong thermoplastic elastomers via RAFT polymerization

2019 ◽  
Vol 480 ◽  
pp. 162-171 ◽  
Author(s):  
Feng Jiang ◽  
Chenqian Pan ◽  
Yaqiong Zhang ◽  
Yanxiong Fang
Keyword(s):  
Raft Polymerization ◽  
Graft Copolymers ◽  
Thermoplastic Elastomers

Temperature Responsive Cellulose-graft-Copolymers via Cellulose Functionalization in an Ionic Liquid and RAFT Polymerization

2014 ◽  
Vol 15 (7) ◽  
pp. 2563-2572 ◽  
Author(s):  
Andrea Hufendiek ◽  
Vanessa Trouillet ◽  
Michael A. R. Meier ◽  
Christopher Barner-Kowollik
Keyword(s):  
Ionic Liquid ◽  
Raft Polymerization ◽  
Graft Copolymers ◽  
Temperature Responsive

PHEA-g-PDMAEA well-defined graft copolymers: SET-LRP synthesis, self-catalyzed hydrolysis, and quaternization

2016 ◽  
Vol 7 (45) ◽  
pp. 6973-6979 ◽  
Author(s):  
Fangxu Sun ◽  
Chun Feng ◽  
Haoyu Liu ◽  
Xiaoyu Huang
Keyword(s):  
Raft Polymerization ◽  
Graft Copolymers ◽  
Side Chains ◽  
Grafting From

This article reports the synthesis of well-defined graft copolymers containing a PHEA backbone and degradable PDMAEA side chains, by the combination of RAFT polymerization, SET-LRP, and the grafting-from strategy.

Synthesis and properties of organic/inorganic hybrid branched-graft copolymers and their application to solid-state electrolytes for high-temperature lithium-ion batteries

2014 ◽  
Vol 5 (10) ◽  
pp. 3432-3442 ◽  
Author(s):  
Jimin Shim ◽  
Dong-Gyun Kim ◽  
Jin Hong Lee ◽  
Ji Hoon Baik ◽  
Jong-Chan Lee
Keyword(s):  
High Temperature ◽  
Solid State ◽  
Lithium Ion Batteries ◽  
Solid Polymer Electrolyte ◽  
Raft Polymerization ◽  
Graft Copolymers ◽  
Lithium Ion ◽  
Solid Polymer ◽  
Inorganic Hybrid ◽  
Branched Graft

A series of organic/inorganic hybrid branched-graft copolymers (BCPs) were synthesized via RAFT polymerization for application to solid polymer electrolyte materials in high-temperature lithium-ion batteries.

scholarly journals First double hydrophilic graft copolymer bearing a poly(2-hydroxylethyl acrylate) backbone synthesized by sequential RAFT polymerization and SET-LRP

2016 ◽  
Vol 7 (18) ◽  
pp. 3156-3164 ◽  
Author(s):  
Yinan Cui ◽  
Xiuyu Jiang ◽  
Chun Feng ◽  
Guangxin Gu ◽  
Jie Xu ◽  
...  
Keyword(s):  
Graft Copolymer ◽  
Raft Polymerization ◽  
Graft Copolymers ◽  
Grafting From

This article reports the first synthesis of well-defined double hydrophilic graft copolymers with a PHEA backbone, by the combination of RAFT polymerization, SET-LRP, and a grafting-from strategy.

Synthesis and characterization of poly(vinyl chloride-graft-2-vinylpyridine) graft copolymers using a novel macroinitiator by reversible addition-fragmentation chain transfer polymerization

e-Polymers ◽  
2014 ◽  
Vol 14 (1) ◽  
pp. 27-34 ◽  
Author(s):  
Temel Öztürk ◽  
Melahat Göktaş ◽  
Bedrettin Savaş ◽  
Mustafa Işıklar ◽  
Mehmet Nuri Atalar ◽  
...  
Keyword(s):  
Vinyl Chloride ◽  
Chain Transfer ◽  
Raft Polymerization ◽  
Graft Copolymers ◽  
Monomer Concentration ◽  
Polymerization Reaction ◽  
Scanning Calorimetry ◽  
H Nmr ◽  
Poly Vinyl Chloride ◽  
Reversible Addition

AbstractSynthesis of poly(vinyl chloride-graft-2-vinylpyridine) graft copolymers was carried out by reversible addition-fragmentation chain transfer (RAFT) polymerization of 2-vinylpyridine using a novel macroinitiator (RAFT macroinitiator). For this purpose, RAFT macroinitiator was obtained from the potassium salt of ethyl xanthogenate and poly(vinyl chloride) (PVC). Then the graft copolymers were synthesized by using RAFT macroinitiator and 2-vinylpyridine. The principal parameters such as monomer concentration, initiator concentration, and polymerization time that affect the polymerization reaction were studied. The effect of the reaction conditions on the heterogeneity index and molecular weight was also investigated. The block lengths of the graft copolymers were calculated by using 1H nuclear magnetic resonance (1H NMR) spectra. The block lengths of the copolymers could be adjusted by varying the monomer and initiator concentrations. The characterizations of the samples were carried out by using 1H NMR, Fourier-transform infrared spectroscopy, gel-permeation chromatography, thermogravimetric analysis, differential scanning calorimetry, and fractional precipitation (γ value) techniques. RAFT polymerization is used to control the polymerization of 2-vinylpyridine over a broad range of molecular weights.

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