The coordination core of Ag(i) N-heterocyclic carbene (NHC) complexes with anticancer properties as revealed by synchrotron radiation X-ray absorption spectroscopy

2014 ◽  
Vol 29 (3) ◽  
pp. 491-497 ◽  
Author(s):  
Marco Giorgetti ◽  
Giuliana Aquilanti ◽  
Maura Pellei ◽  
Valentina Gandin
2019 ◽  
Vol 91 ◽  
pp. 401-407 ◽  
Author(s):  
Simone S. Melo ◽  
Adriano B. Andrade ◽  
Giordano F.C. Bispo ◽  
Jessica C. Carvalho ◽  
Zélia S. Macedo ◽  
...  

2018 ◽  
Vol 2018 ◽  
pp. 1-11 ◽  
Author(s):  
Yingda Qian ◽  
Yuanlan Liang ◽  
Xuguang Luo ◽  
Kaiyan He ◽  
Wenhong Sun ◽  
...  

A series of ultrathin InSb films grown on GaAs by low-pressure metalorganic chemical vapor deposition with different V/III ratios were investigated thoroughly using spectroscopic ellipsometry (SE), X-ray diffraction, and synchrotron radiation X-ray absorption spectroscopy. The results predicted that InSb films on GaAs grown under too high or too low V/III ratios are with poor quality, while those grown with proper V/III ratios of 4.20–4.78 possess the high crystalline quality. The temperature-dependent SE (20–300°C) and simulation showed smooth variations of SE spectra, optical constants (n, k, e1, and ε2), and critical energy points (E1, E1+Δ1, E′0, E2, and E′1) for InSb film when temperature increased from 20°C to 250°C, while at 300°C, large changes appeared. Our study revealed the oxidation of about two atomic layers and the formation of an indium-oxide (InO) layer of ∼5.4 nm. This indicates the high temperature limitation for the use of InSb/GaAs materials, up to 250°C.


Hyomen Kagaku ◽  
1995 ◽  
Vol 16 (7) ◽  
pp. 428-433
Author(s):  
Fumitaka ESAKA ◽  
Hiromichi SHIMADA ◽  
Motoyasu IMAMURA ◽  
Nobuyuki MATSUBAYASHI ◽  
Toshio SATO ◽  
...  

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