tert-Butyl hydroperoxide (TBHP)-mediated oxidative self-coupling of amines to imines over a α-MnO2 catalyst

2014 ◽  
Vol 16 (5) ◽  
pp. 2523-2527 ◽  
Author(s):  
Zhe Zhang ◽  
Feng Wang ◽  
Min Wang ◽  
Shutao Xu ◽  
Haijun Chen ◽  
...  
Keyword(s):  
Room Temperature ◽  
Direct Synthesis ◽  
Aliphatic Amines ◽  
Butyl Hydroperoxide ◽  
Tert Butyl ◽  
Tert Butyl Hydroperoxide ◽  
Aromatic And Aliphatic Amines

A methodology for the direct synthesis of imines from amines via a facile α-MnO2 catalyzed-procedure at room temperature with TBHP as an oxidant was described. The catalysis is suitability for 13 aromatic and aliphatic amines, and it is heterogeneous, recyclable and reusable.

Efficient and selective copper-catalyzed organic solvent-free and biphasic oxidation of aromatic gem-disubstituted alkenes to carbonyl compounds by tert-butyl hydroperoxide at room temperature

2014 ◽  
Vol 16 (6) ◽  
pp. 3013-3017 ◽  
Author(s):  
Md. Munkir Hossain ◽  
Wei-Kai Huang ◽  
Hung-Jie Chen ◽  
Pei-Han Wang ◽  
Shin-Guang Shyu
Keyword(s):  
Organic Solvent ◽  
Carbonyl Compounds ◽  
Room Temperature ◽  
Oxidative Cleavage ◽  
Solvent Free ◽  
Butyl Hydroperoxide ◽  
Tert Butyl ◽  
Tert Butyl Hydroperoxide

Biphasic Cu(ii) catalyzed selective oxidative cleavage of aromatic gem-disubstituted alkenes to carbonyl compounds using tert-butyl hydroperoxide at room temperature.

Sign in / Sign up

Export Citation Format

Share Document