ChemInform Abstract: Biphasic Copper-Catalyzed C-H Bond Activation of Arylalkanes to Ketones with tert-Butyl Hydroperoxide in Water at Room Temperature.

ChemInform ◽  
2016 ◽  
Vol 47 (44) ◽  
Author(s):  
Md. Munkir Hossain ◽  
Shin-Guang Shyu
Keyword(s):  
Room Temperature ◽  
Bond Activation ◽  
Butyl Hydroperoxide ◽  
Tert Butyl ◽  
Tert Butyl Hydroperoxide

Efficient and selective copper-catalyzed organic solvent-free and biphasic oxidation of aromatic gem-disubstituted alkenes to carbonyl compounds by tert-butyl hydroperoxide at room temperature

2014 ◽  
Vol 16 (6) ◽  
pp. 3013-3017 ◽  
Author(s):  
Md. Munkir Hossain ◽  
Wei-Kai Huang ◽  
Hung-Jie Chen ◽  
Pei-Han Wang ◽  
Shin-Guang Shyu
Keyword(s):  
Organic Solvent ◽  
Carbonyl Compounds ◽  
Room Temperature ◽  
Oxidative Cleavage ◽  
Solvent Free ◽  
Butyl Hydroperoxide ◽  
Tert Butyl ◽  
Tert Butyl Hydroperoxide

Biphasic Cu(ii) catalyzed selective oxidative cleavage of aromatic gem-disubstituted alkenes to carbonyl compounds using tert-butyl hydroperoxide at room temperature.

tert-Butyl hydroperoxide (TBHP)-mediated oxidative self-coupling of amines to imines over a α-MnO2 catalyst

2014 ◽  
Vol 16 (5) ◽  
pp. 2523-2527 ◽  
Author(s):  
Zhe Zhang ◽  
Feng Wang ◽  
Min Wang ◽  
Shutao Xu ◽  
Haijun Chen ◽  
...  
Keyword(s):  
Room Temperature ◽  
Direct Synthesis ◽  
Aliphatic Amines ◽  
Butyl Hydroperoxide ◽  
Tert Butyl ◽  
Tert Butyl Hydroperoxide ◽  
Aromatic And Aliphatic Amines

A methodology for the direct synthesis of imines from amines via a facile α-MnO2 catalyzed-procedure at room temperature with TBHP as an oxidant was described. The catalysis is suitability for 13 aromatic and aliphatic amines, and it is heterogeneous, recyclable and reusable.

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