Carbene complexes of phosphorus(v) fluorides substituted with perfluoroalkyl-groups synthesized by oxidative addition. Cleavage of the complexes reveals a new synthetic protocol for ionic liquids

2014 ◽  
Vol 43 (7) ◽  
pp. 2979-2987 ◽  
Author(s):  
Tobias Böttcher ◽  
Simon Steinhauer ◽  
Nadine Allefeld ◽  
Berthold Hoge ◽  
Beate Neumann ◽  
...  
Keyword(s):  
Ionic Liquids ◽  
Oxidative Addition ◽  
Carbene Complexes

scholarly journals Reactivity of cationic gold(I) carbene complexes toward oxidative addition of bromine

2012 ◽  
Vol 391 ◽  
pp. 141-149 ◽  
Author(s):  
Luciano Canovese ◽  
Fabiano Visentin ◽  
Carlo Levi ◽  
Claudio Santo
Keyword(s):  
Oxidative Addition ◽  
Carbene Complexes ◽  
Cationic Gold

Facile Oxidative Addition of Organic Halides to Heteroleptic and Homoleptic Pd0-N-Heterocyclic Carbene Complexes

2011 ◽  
Vol 2011 (11) ◽  
pp. 1750-1761 ◽  
Author(s):  
Jung-Hyun Lee ◽  
Hyeong-Tak Jeon ◽  
Yong-Joo Kim ◽  
Kyung-Eun Lee ◽  
Young Ok Jang ◽  
...  
Keyword(s):  
Oxidative Addition ◽  
Carbene Complexes ◽  
Organic Halides

Carbene Complexes of Phosphorus(V) Fluorides by Oxidative Addition of 2,2-Difluorobis(dialkylamines) to Phosphorus(III) Halides

2011 ◽  
Vol 31 (4) ◽  
pp. 1278-1280 ◽  
Author(s):  
Tobias Böttcher ◽  
Oleg Shyshkov ◽  
Matthias Bremer ◽  
Bassem S. Bassil ◽  
Gerd-Volker Röschenthaler
Keyword(s):  
Oxidative Addition ◽  
Carbene Complexes

Bis-carbene complexes from oxidative addition of imidazolium C–H bonds to palladium(0)

2002 ◽  
pp. 2163-2167 ◽  
Author(s):  
Stephan Gründemann ◽  
Martin Albrecht ◽  
Anes Kovacevic ◽  
Jack W. Faller ◽  
Robert H. Crabtree
Keyword(s):  
Oxidative Addition ◽  
Carbene Complexes

Kinetic study of the oxidative addition of methyl iodide to Vaska’s complex in ionic liquids

2005 ◽  
Vol 690 (15) ◽  
pp. 3522-3528 ◽  
Author(s):  
Steven J. P’Pool ◽  
Marc A. Klingshirn ◽  
Robin D. Rogers ◽  
Kevin H. Shaughnessy
Keyword(s):  
Ionic Liquids ◽  
Kinetic Study ◽  
Methyl Iodide ◽  
Oxidative Addition ◽  
Vaska's Complex

N,N'-Di(alkyloxy)imidazolium Salts: New Patent-free Ionic Liquids and NHC Precatalysts

2007 ◽  
Vol 62 (3) ◽  
pp. 295-308 ◽  
Author(s):  
Gerhard Laus ◽  
Alexander Schwärzler ◽  
Philipp Schuster ◽  
Gino Bentivoglio ◽  
Michael Hummel ◽  
...  
Keyword(s):  
Ionic Liquids ◽  
Solid State ◽  
Crystal Structures ◽  
Imidazole Ring ◽  
X Ray Diffraction ◽  
Ring Plane ◽  
Carbene Complexes ◽  
X Ray ◽  
Imidazolium Cations ◽  
Hydrophobic Ionic Liquids

1-Hydroxyimidazole-3-oxides (2-H, 2-Me) were alkylated with (RO)2SO2 (R =Me, Et) to give the new 1,3-di(alkyloxy)imidazolium cations which were isolated as hexafluorophosphates. Ion metathesis yielded new hydrophobic ionic liquids (bis(trifluoromethanesulfonyl)imides, tris(pentafluoroethyl) trifluorophosphates). Bromination afforded 2-bromo derivatives which were converted to Ni and Pd N-heterocyclic carbene complexes by oxidative insertion. Fifteen crystal structures were determined by X-ray diffraction. The N-alkyloxy groups are twisted out of the imidazole ring plane and adopt either syn or anti conformations in the solid state.

Nickel(II) Pincer Carbene Complexes: Oxidative Addition of an Aryl C–H Bond to Form a Ni(II) Hydride

2014 ◽  
Vol 34 (2) ◽  
pp. 399-407 ◽  
Author(s):  
Ellen M. Matson ◽  
Gabriel Espinosa Martinez ◽  
Abdulrahman D. Ibrahim ◽  
Bailey J. Jackson ◽  
Jeffrey A. Bertke ◽  
...  
Keyword(s):  
Oxidative Addition ◽  
Carbene Complexes
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