Two novel lead(ii) carboxyphosphonates with a layered and a 3D framework structure: syntheses, crystal structures, reversible dehydration/hydration, and luminescence properties

2013 ◽  
Vol 42 (22) ◽  
pp. 8009 ◽  
Author(s):  
Wei Chu ◽  
Zhen-Gang Sun ◽  
Cheng-Qi Jiao ◽  
Yan-Yu Zhu ◽  
Shou-Hui Sun ◽  
...  
RSC Advances ◽  
2015 ◽  
Vol 5 (96) ◽  
pp. 79041-79049 ◽  
Author(s):  
Chao Ma ◽  
Cheng-Qi Jiao ◽  
Zhen-Gang Sun ◽  
Yan-Yu Zhu ◽  
Xiao-Wen Zhang ◽  
...  

Two novel cadmium(ii) carboxyphosphonates with 3D framework structure have been synthesized under hydrothermal conditions. The luminescence properties and molecular recognition properties of the compounds have been investigated.


2009 ◽  
Vol 33 (1) ◽  
pp. 119-124 ◽  
Author(s):  
Yanyu Zhu ◽  
Zhengang Sun ◽  
Yan Zhao ◽  
Jing Zhang ◽  
Xin Lu ◽  
...  

2010 ◽  
Vol 34 (11) ◽  
pp. 2429 ◽  
Author(s):  
Na Zhang ◽  
Zhengang Sun ◽  
Yanyu Zhu ◽  
Jing Zhang ◽  
Lei Liu ◽  
...  

2018 ◽  
Vol 42 (8) ◽  
pp. 424-427 ◽  
Author(s):  
Junfeng Li ◽  
Xiudian Xu ◽  
Lei Zhou ◽  
Zeyu Zhou ◽  
Lizhuang Chen ◽  
...  

The luminescent complexes [Cd(BIMP)2(NDC)2]n and [Zn(BIMP)2(NDC)]n (where (3-BIMP) = 3-(1H-benzoimidazol-2-yl)pyridin-2(1H)-one and NDC = 2,6-naphthalenedicarboxylic acid) have been synthesised under hydrothermal conditions and their crystal structures determined. [Cd(BIMP)2(NDC)2]n exhibited a 1D → 2D → 3D framework structure and [Zn(BIMP)2(NDC)]n has a 3D porous structure. Under the same excitation energy (λex = 389 nm), [Zn(BIMP)2(NDC)]n showed a stronger fluorescence emission than the free 3-BIMP ligand, the NDC ligand and [Cd(BIMP)2(NDC)2]n.


RSC Advances ◽  
2014 ◽  
Vol 4 (91) ◽  
pp. 49892-49899 ◽  
Author(s):  
Hui Luo ◽  
Yan-Yu Zhu ◽  
Zhen-Gang Sun ◽  
Cheng-Qi Jiao ◽  
Guang-Ning Zhang ◽  
...  

Two new 3D nickel(ii) carboxyphosphonates 1 and 2 were synthesized under hydrothermal conditions. The surface photovoltage and luminescent properties were studied.


2010 ◽  
Vol 10 (1) ◽  
pp. 406-413 ◽  
Author(s):  
Lei Liu ◽  
Zhen-Gang Sun ◽  
Na Zhang ◽  
Yan-Yu Zhu ◽  
Yan Zhao ◽  
...  

2021 ◽  
Vol 236 (1-2) ◽  
pp. 11-21
Author(s):  
Evgeny V. Nazarchuk ◽  
Oleg I. Siidra ◽  
Dmitry O. Charkin ◽  
Stepan N. Kalmykov ◽  
Elena L. Kotova

Abstract Three new rubidium polychromates, Rb2[(UO2)(Cr2O7)(NO3)2] (1), γ-Rb2Cr3O10 (2) and δ-Rb2Cr3O10 (3) were prepared by combination of hydrothermal treatment at 220 °C and evaporation of aqueous solutions under ambient conditions. Compound 1 is monoclinic, P 2 1 / c $P{2}_{1}/c$ , a = 13.6542(19), b = 19.698(3), c = 11.6984(17) Å, β = 114.326(2)°, V = 2867.0(7) Å3, R 1 = 0.040; 2 is hexagonal, P 6 3 / m $P{6}_{3}/m$ , a = 11.991(2), c = 12.828(3) Å, γ = 120°, V = 1597.3(5) Å3, R 1 = 0.031; 3 is monoclinic, P 2 1 / n $P{2}_{1}/n$ , a = 7.446(3), b = 18.194(6), c = 7.848(3) Å, β = 99.953(9)°, V = 1047.3(7) Å3, R 1 = 0.037. In the crystal structure of 1, UO8 bipyramids and NO3 groups share edges to form [(UO2)(NO3)2] species which share common corners with dichromate Cr2O7 groups producing novel type of uranyl dichromate chains [(UO2)(Cr2O7)(NO3)2]2−. In the structures of new Rb2Cr3O10 polymorphs, CrO4 tetrahedra share vertices to form Cr3O10 2− species. The trichromate groups are aligned along the 63 screw axis forming channels running in the ab plane in the structure of 2. The Rb cations reside between the channels and in their centers completing the structure. The trichromate anions are linked by the Rb+ cations into a 3D framework in the structure of 3. Effect of solution acidity on the crystallization of polychromates in uranyl-bearing systems is discussed.


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