Low temperature oxidation of methanol to methyl formate over Pd nanoparticles supported on γ-Fe2O3

2014 ◽  
Vol 4 (3) ◽  
pp. 738 ◽  
Author(s):  
R. Wojcieszak ◽  
M. N. Ghazzal ◽  
E. M. Gaigneaux ◽  
P. Ruiz
Keyword(s):  
Low Temperature ◽  
Methyl Formate ◽  
Pd Nanoparticles ◽  
Low Temperature Oxidation ◽  
Temperature Oxidation ◽  
Oxidation Of Methanol

scholarly journals Low-Temperature Oxidation of Methanol to Formaldehyde on a Model Single-Atom Catalyst: Pd Atoms on Fe3O4(001)

ACS Catalysis ◽  
2019 ◽  
Vol 9 (12) ◽  
pp. 10977-10982 ◽  
Author(s):  
Matthew D. Marcinkowski ◽  
Simuck F. Yuk ◽  
Nassar Doudin ◽  
R. Scott Smith ◽  
Manh-Thuong Nguyen ◽  
...  
Keyword(s):  
Low Temperature ◽  
Single Atom ◽  
Low Temperature Oxidation ◽  
Temperature Oxidation ◽  
Oxidation Of Methanol

scholarly journals Atomic‐Scale Insights into the Low‐Temperature Oxidation of Methanol over a Single‐Atom Pt 1 ‐Co 3 O 4 Catalyst

2019 ◽  
Vol 29 (31) ◽  
pp. 1902041 ◽  
Author(s):  
Zeyu Jiang ◽  
Xiangbo Feng ◽  
Jianlin Deng ◽  
Chi He ◽  
Mark Douthwaite ◽  
...  
Keyword(s):  
Low Temperature ◽  
Atomic Scale ◽  
Single Atom ◽  
Low Temperature Oxidation ◽  
Temperature Oxidation ◽  
Oxidation Of Methanol

Oxidation of methanol to methyl formate over supported Pd nanoparticles: insights into the reaction mechanism at low temperature

2014 ◽  
Vol 4 (9) ◽  
pp. 3298-3305 ◽  
Author(s):  
R. Wojcieszak ◽  
A. Karelovic ◽  
E. M. Gaigneaux ◽  
P. Ruiz
Keyword(s):  
Reaction Mechanism ◽  
Low Temperature ◽  
Methyl Formate ◽  
Pd Nanoparticles ◽  
Dissociative Adsorption ◽  
Reaction Step ◽  
Oxidation Of Methanol ◽  
Methoxy Groups ◽  
Supported Pd

The mechanism of methyl formate formation at low temperature was studied using DRIFT-operando. The first reaction step would be the formation of methoxy groups by dissociative adsorption of methanol and then transformation into formaldehyde. The final step would be the condensation of the formaldehyde species with gaseous methanol.

Low-Temperature Oxidation of Methyl Formate on Au(332)

2021 ◽  
Author(s):  
Christoph D. Feldt ◽  
Jian L. Low ◽  
Paul A. Albrecht ◽  
Keyun Tang ◽  
Wiebke Riedel ◽  
...  
Keyword(s):  
Low Temperature ◽  
Methyl Formate ◽  
Low Temperature Oxidation ◽  
Temperature Oxidation
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