scholarly journals Low-Temperature Oxidation of Methanol to Formaldehyde on a Model Single-Atom Catalyst: Pd Atoms on Fe3O4(001)

ACS Catalysis ◽  
2019 ◽  
Vol 9 (12) ◽  
pp. 10977-10982 ◽  
Author(s):  
Matthew D. Marcinkowski ◽  
Simuck F. Yuk ◽  
Nassar Doudin ◽  
R. Scott Smith ◽  
Manh-Thuong Nguyen ◽  
...  
Keyword(s):  
Low Temperature ◽  
Single Atom ◽  
Low Temperature Oxidation ◽  
Temperature Oxidation ◽  
Oxidation Of Methanol

scholarly journals Atomic‐Scale Insights into the Low‐Temperature Oxidation of Methanol over a Single‐Atom Pt 1 ‐Co 3 O 4 Catalyst

2019 ◽  
Vol 29 (31) ◽  
pp. 1902041 ◽  
Author(s):  
Zeyu Jiang ◽  
Xiangbo Feng ◽  
Jianlin Deng ◽  
Chi He ◽  
Mark Douthwaite ◽  
...  
Keyword(s):  
Low Temperature ◽  
Atomic Scale ◽  
Single Atom ◽  
Low Temperature Oxidation ◽  
Temperature Oxidation ◽  
Oxidation Of Methanol

scholarly journals Influence of Co-Precipitation Agent on the Structure, Texture and Catalytic Activity of Au-CeO2 Catalysts in Low-Temperature Oxidation of Benzyl Alcohol

Catalysts ◽  
2021 ◽  
Vol 11 (5) ◽  
pp. 641
Author(s):  
Lukasz Wolski ◽  
Grzegorz Nowaczyk ◽  
Stefan Jurga ◽  
Maria Ziolek
Keyword(s):  
Gold Nanoparticles ◽  
Catalytic Activity ◽  
Low Temperature ◽  
Benzyl Alcohol ◽  
Low Temperature Oxidation ◽  
Temperature Oxidation ◽  
Oxidation Of Benzyl Alcohol ◽  
Key Factor ◽  
Au Particle Size ◽  
Co Precipitation

The aim of the study was to establish the influence of a co-precipitation agent (i.e., NaOH–immediate precipitation; hexamethylenetetramine/urea–gradual precipitation and growth of nanostructures) on the properties and catalytic activity of as-synthesized Au-CeO2 nanocomposites. All catalysts were fully characterized with the use of XRD, nitrogen physisorption, ICP-OES, SEM, HR-TEM, UV-vis, XPS, and tested in low-temperature oxidation of benzyl alcohol as a model oxidation reaction. The results obtained in this study indicated that the type of co-precipitation agent has a significant impact on the growth of gold species. Immediate co-precipitation of Au-CeO2 nanostructures with the use of NaOH allowed obtainment of considerably smaller and more homogeneous in size gold nanoparticles than those formed by gradual co-precipitation and growth of Au-CeO2 nanostructures in the presence of hexamethylenetetramine or urea. In the catalytic tests, it was established that the key factor promoting high activity in low-temperature oxidation of benzyl alcohol was size of gold nanoparticles. The highest conversion of the alcohol was observed for the catalyst containing the smallest Au particle size (i.e., Au-CeO2 nanocomposite prepared with the use of NaOH as a co-precipitation agent).

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